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E-grāmata: Anionic Polymerization: Principles, Practice, Strength, Consequences and Applications

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  • Formāts: PDF+DRM
  • Izdošanas datums: 01-Sep-2015
  • Izdevniecība: Springer Verlag, Japan
  • Valoda: eng
  • ISBN-13: 9784431541868
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  • Formāts: PDF+DRM
  • Izdošanas datums: 01-Sep-2015
  • Izdevniecība: Springer Verlag, Japan
  • Valoda: eng
  • ISBN-13: 9784431541868

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This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supramolecular assemblies have been created and widely studied and are considered nanodevices in the fields of nanoscience and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities , in research organizations, and in industry.

This book examines a wide range of topics on anionic polymerization, from basic principles to experimental techniques important for practice. Coverage includes recent advances and potential applications.
Part I Principles and Practice
Schlenk Techniques for Anionic Polymerization
3(16)
Kedar Ratkanthwar
Junpeng Zhao
Hefeng Zhang
Nikos Hadjichristidis
Jimmy W. Mays
High Vacuum Techniques for Anionic Polymerization
19(42)
Kedar Ratkanthwar
Nikos Hadjichristidis
Jimmy W. Mays
Nonpolar Monomers: Styrene and 1,3-Butadiene Derivatives
61(66)
Akira Hirao
Katsuhiko Takenaka
Anionic Polymerization of Polar Vinyl Monomers: Vinylpyridines, (Meth)acrylates, (Meth)acrylamides, (Meth)acrylonitrile, Phenyl Vinyl Sulfoxide, Benzofulvene, and Other Monomers
127(64)
Takashi Ishizone
Yuki Kosaka
Raita Goseki
Cyclic Monomers: Epoxides, Lactide, Lactones, Lactams, Cyclic Silicon-Containing Monomers, Cyclic Carbonates, and Others
191(116)
Stephane Carlotti
Frederic Peruch
Ring-Opening Polymerization of N-Carboxyanhydrides for Preparation of Polypeptides and Polypeptide-Based Hybrid Materials with Various Molecular Architectures
307(32)
David Pahovnik
Nikos Hadjichristidis
Living Anionic Polymerization of Isocyanates
339(48)
Chang-Geun Chae
Ho-Bin Seo
Jae-Suk Lee
Poly(ferrocenylsilanes) with Controlled Macromolecular Architecture by Anionic Polymerization: Applications in Patterning and Lithography
387(42)
Lionel Dos Ramos
Mark A. Hempenius
G. Julius Vancso
Polymerization Using Phosphazene Bases
429(22)
Junpeng Zhao
Nikos Hadjichristidis
Helmut Schlaad
Group Transfer Polymerization of Acrylic Monomers
451(44)
Yougen Chen
Keita Fuchise
Toshifumi Satoh
Toyoji Kakuchi
Surface-Initiated Anionic Polymerization from Nanomaterials
495(46)
Zhong Li
Durairaj Baskaran
Part II Strength: Precise Synthesis of Well-Defined Architectural Polymers
Block Copolymers by Anionic Polymerization: Recent Synthetic Routes and Developments
541(84)
Georgios Theodosopoulos
Marinos Pitsikalis
Graft and Comblike Polymers
625(34)
Andrew Goodwin
Nam-Goo Kang
Jimmy W. Mays
Star-Branched Polymers (Star Polymers)
659(60)
Akira Hirao
Mayumi Hayashi
Shotaro Ito
Raita Goseki
Tomoya Higashihara
Nikos Hadjichristidis
Synthesis of Dendrimer-Like Polymers
719(34)
Junpo He
Jia Li
Shaohui Yang
Complex Branched Polymers
753(52)
Georgios Theodosopoulos
Marinos Pitsikalis
Block Copolymers Containing Polythiophene Segments
805(38)
Tomoya Higashihara
Eisuke Goto
Mitsuru Ueda
Part III Consequences: Morphologies and Self-Assembled Hierarchical Structures
Block Copolymers and Miktoarm Star-Branched Polymers
843(18)
Hirokazu Hasegawa
Control of Surface Structure and Dynamics of Polymers Based on Precision Synthesis
861(20)
Tomoyasu Hirai
Yukari Oda
David P. Penaloza Jr.
Daisuke Kawaguchi
Keiji Tanaka
Block Copolymers as Antifouling and Fouling Resistant Coatings
881(44)
David Calabrese
Brandon Wenning
Christopher K. Ober
Micellar Structures from Anionically Synthesized Block Copolymers
925(50)
Jean-Francois Gohy
Part IV Applications
Block Polymers for Self-Assembling: Lithographic Materials
975(36)
Teruaki Hayakawa
Methacrylate-Based Polymers for Industrial Uses
1011(22)
Kenichi Hamada
Yoshihiro Morishita
Toyoaki Kurihara
Kazushige Ishiura
The Critical Role of Anionic Polymerization for Advances in the Physics of Polyolefins
1033(48)
David J. Lohse
Part V Future Remarks
Future Remarks
1081
Nikos Hadjichristidis
Akira Hirao
Professor Nikos Hadjichristidis Professor of Chemical Sciences Division of Chemical and Life Sciences & Engineering King Abdullah University of Science and Technology (KAUST) Kingdom of Saudi Arabia *Chemistry of Thermoplastic Elastomers Award of ACS, Rubber Division, USA, 2011 *Cooperative Award of ACS Division of Polymeric Materials: Science and Engineering, USA, 2010 *International Award of the Society of Polymer Science, Japan, 2007 Akira HIRAO, Ph.D. Professor of Organic and Polymeric Materials Tokyo Institute of Technology Japan *Japan Polymer Society Award (2010) *member of the Editorial Board of "Macromolecules", "Polymer Journal"