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E-grāmata: Applications of Metal-Organic Frameworks and Their Derived Materials [Wiley Online]

Edited by (Aligarh Muslim University, Aligarh, India), Edited by (National Center for Nanoscience and Technology (NCNST, Beijing)), Edited by , Edited by (King Abdulaziz University, Jeddah, Saudi Arabia)
  • Formāts: 496 pages
  • Izdošanas datums: 05-Jun-2020
  • Izdevniecība: Wiley-Scrivener
  • ISBN-10: 1119651077
  • ISBN-13: 9781119651079
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Applications of Metal-Organic Frameworks and Their Derived MaterialsPalielināt
  • Formāts: 496 pages
  • Izdošanas datums: 05-Jun-2020
  • Izdevniecība: Wiley-Scrivener
  • ISBN-10: 1119651077
  • ISBN-13: 9781119651079
Citas grāmatas par šo tēmu:
Wiley Online E-booksMore info about Wiley Online
Rokasgrāmatas mājas lapa: https://onlinelibrary.wiley.com/doi/book/10.1002/9781119651079
"Metal organic frameworks (MOFs) are porous crystalline polymers constructed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their highsurface area, controllable morphology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self sacrificing templates for synthesizing metal oxides, heteroatom doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down to earth applications in fields such as biomedical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strategies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must have for any library"--

Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community.

This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials.

Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.
Preface xiii
1 Application of MOFs and Their Derived Materials in Sensors 1(32)
Yong Wang
Chang Yin
Qianfen Zhuang
1.1 Introduction
1(2)
1.2 Application of MOFs and Their Derived Materials in Sensors
3(19)
1.2.1 Optical Sensor
3(10)
1.2.1.1 Colorimetric Sensor
3(4)
1.2.1.2 Fluorescence Sensor
7(4)
1.2.1.3 Chemiluminescent Sensor
11(2)
1.2.2 Electrochemical Sensor
13(6)
1.2.2.1 Amperometric Sensor
13(3)
1.2.2.2 Impedimetric, Electrochemiluminescence, and Photoelectrochemical Sensor
16(3)
1.2.3 Field-Effect Transistor Sensor
19(2)
1.2.4 Mass-Sensitive Sensor
21(1)
1.3 Conclusion
22(1)
Acknowledgments
23(1)
References
23(10)
2 Applications of Metal-Organic Frameworks (MOFs) and Their Derivatives in Piezo/Ferroelectrics 33(30)
H. Manjunatha
K. Chandra Babu Naidu
N. Suresh Kumar
Ramyakrishna Pothu
Rajender Boddula
2.1 Introduction
34(1)
2.1.1 Brief Introduction to Piezo/Ferroelectricity
34(1)
2.2 Fundamentals of Piezo/Ferroelectricity
34(6)
2.3 Metal-Organic Frameworks for Piezo/Ferroelectricity
40(1)
2.4 Ferro/Piezoelectric Behavior of Various MOFs
40(12)
2.5 Conclusion
52(1)
References
53(10)
3 Fabrication and Functionalization Strategies of MOFs and Their Derived Materials "MOF Architecture" 63(38)
Demet Ozer
3.1 Introduction
63(2)
3.2 Fabrication and Functionalization of MOFs
65(24)
3.2.1 Metal Nodes
65(3)
3.2.2 Organic Linkers
68(8)
3.2.3 Secondary Building Units
76(1)
3.2.4 Synthesis Methods
77(6)
3.2.4.1 Hydrothermal and Solvothermal Method
77(1)
3.2.4.2 Microwave Synthesis
78(2)
3.2.4.3 Electrochemical Method
80(1)
3.2.4.4 Mechanochemical Synthesis
81(1)
3.2.4.5 Sonochemical (Ultrasonic Assisted) Method
81(1)
3.2.4.6 Diffusion Method
82(1)
3.2.4.7 Template Method
82(1)
3.2.5 Synthesis Strategies
83(6)
3.3 MOF Derived Materials
89(1)
3.4 Conclusion
90(1)
References
90(11)
4 Application of MOFs and Their Derived Materials in Molecular Transport 101(8)
Arka Bagchi
Partha Saha
Arunima Biswas
S.K. Manirul Islam
4.1 Introduction
102(1)
4.2 MOFs as Nanocarriers for Membrane Transport
102(4)
4.2.1 MIL-89
103(1)
4.2.2 MIL-88A
103(1)
4.2.3 MIL-100
104(1)
4.2.4 MIL-101
104(1)
4.2.5 MIL-53
104(1)
4.2.6 ZIF-8
104(1)
4.2.7 Zn-TATAT
105(1)
4.2.8 BioMOF-1 (Zn)
105(1)
4.2.9 UiO (Zr)
105(1)
4.3 Conclusion
106(1)
References
106(3)
5 Role of MOFs as Electro/-Organic Catalysts 109(12)
Manorama Singh
Ankita Rai
Vijai K. Rai
Smita R. Bhardiya
Ambika Asati
5.1 What Is MOFs
109(2)
5.2 MOFs as Electrocatalyst in Sensing Applications
111(3)
5.3 MOFs as Organic Catalysts in Organic Transformations
114(1)
5.4 Conclusion and Future Prospects
115(1)
References
116(5)
6 Application of MOFs and Their Derived Materials in Batteries 121(56)
Rituraj Dutta
Ashok Kumar
6.1 Introduction
122(4)
6.2 Metal-Organic Frameworks
126(9)
6.2.1 Classification and Properties of Metal-Organic Frameworks
127(3)
6.2.2 Potential Applications of MOFs
130(3)
6.2.3 Synthesis of MOFs
133(2)
6.3 Polymer Electrolytes
135(7)
6.3.1 Historical Perspectives and Classification of Polymer Electrolytes
136(3)
6.3.2 MOF Based Polymer Electrolytes
139(3)
6.4 Ionic Liquids
142(5)
6.4.1 Properties of Ionic Liquids
143(2)
6.4.2 Ionic Liquid Incorporated MOF
145(2)
6.5 Ion Transport in Polymer Electrolytes
147(10)
6.5.1 General Description of Ionic Conductivity
147(1)
6.5.2 Models for Ionic Transport in Polymer Electrolytes
148(4)
6.5.3 Impedance Spectroscopy and Ionic Conductivity Measurements
152(3)
6.5.4 Concept of Mismatch and Relaxation
155(1)
6.5.5 Scaling of ac Conductivity
156(1)
6.6 IL Incorporated MOF Based Composite Polymer Electrolytes
157(9)
6.7 Conclusion and Perspectives
166(2)
References
168(9)
7 Fine Chemical Synthesis Using Metal-Organic Frameworks as Catalysts 177(16)
Aasif Helal
7.1 Introduction
177(2)
7.2 Oxidation Reaction
179(4)
7.2.1 Epoxidation
179(2)
7.2.2 Sulfoxidation
181(1)
7.2.3 Aerobic Oxidation of Alcohols
182(1)
7.3 1,3-Dipolar Cycloaddition Reaction
183(1)
7.4 Transesterification Reaction
183(1)
7.5 C-C Bond Formation Reactions
184(3)
7.5.1 Heck Reactions
184(2)
7.5.2 Sonogashira Coupling
186(1)
7.5.3 Suzuki Coupling
186(1)
7.6 Conclusion
187(1)
References
187(6)
8 Application of Metal Organic Framework and Derived Material in Hydrogenation Catalysis 193(26)
Tejaswini Sahoo
Jagannath Panda
Jnana Ranjan Sahu
Rojalin Sahu
8.1 Introduction
193(4)
8.1.1 The Active Centers in Parent MOF Materials
195(1)
8.1.2 The Active Centers in MOF Catalyst
195(1)
8.1.3 Metal Nodes
196(1)
8.2 Hydrogenation Reactions
197(13)
8.2.1 Hydrogenation of Alpha-Beta Unsaturated Aldehyde
197(1)
8.2.2 Hydrogenation of Cinnamaldehyde
198(1)
8.2.3 Hydrogenation of Nitroarene
199(2)
8.2.4 Hydrogenation of Nitro Compounds
201(1)
8.2.5 Hydrogenation of Benzene
202(3)
8.2.6 Hydrogenation of Quinoline
205(1)
8.2.7 Hydrogenation of Carbon Dioxide
206(1)
8.2.8 Hydrogenation of Aromatics
207(1)
8.2.9 Hydrogenation of Levulinic Acid
207(1)
8.2.10 Hydrogenation of Alkenes and Alkynes
208(2)
8.2.11 Hydrogenation of Phenol
210(1)
8.3 Conclusion
210(1)
References
211(8)
9 Application of MOFs and Their Derived Materials in Solid-Phase Extraction 219(44)
Adrian Gutierrez-Serpa
Ivan Taima-Mancera
Jorge Pasdn
Juan H. Ayala
Veronica Pino
9.1 Solid-Phase Extraction
220(5)
9.1.1 Materials in SPE
223(2)
9.2 MOFs and COFs in Miniaturized Solid-Phase Extraction (µSPE)
225(7)
9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-µSPE)
232(7)
9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-µSPE)
239(10)
9.5 Concluding Remarks
249(1)
Acknowledgments
249(1)
References
249(14)
10 Anticancer and Antimicrobial MOFs and Their Derived Materials 263(24)
Nasser Mohammed Hosny
10.1 Introduction
263(1)
10.2 Anticancer MOFs
264(8)
10.2.1 MOFs as Drug Carriers
264(5)
10.2.2 MOFs in Phototherapy
269(3)
10.3 Antibacterial MOFs
272(6)
10.4 Antifungal MOFs
278(2)
References
280(7)
11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Personal Care Products 287(26)
Jagannath Panda
Satya Narayan Sahu
Tejaswini Sahoo
Biswajit Mishra
Subrat Kumar Pattanayak
Rojalin Sahu
11.1 Introduction
288(2)
11.2 General Synthesis Routes
290(7)
11.2.1 Hydrothermal Synthesis
295(1)
11.2.2 Solvothermal Synthesis of MOFs
296(1)
11.2.3 Room Temperature Synthesis
296(1)
11.2.4 Microwave Assisted Synthesis
296(1)
11.2.5 Mechanochemical Synthesis
297(1)
11.2.6 Electrochemical Synthesis
297(1)
11.3 Postsynthetic Modification in MOF
297(1)
11.4 Computational Method
297(2)
11.5 Results and Discussion
299(4)
11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone)
299(4)
11.6 Conclusion
303(1)
References
304(9)
12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds 313(44)
Sheila Permatasari Santoso
Artik Elisa Angkawijaya
Vania Bundjaja
Felycia Edi Soetaredjo
Suryadi Ismadji
12.1 Introduction
314(1)
12.2 VOCs and Their Potential Hazards
315(5)
12.2.1 Other Sources of VOCs
319(1)
12.3 VOCs Removal Techniques
320(4)
12.4 Fabricated MOF for VOC Removal
324(14)
12.4.1 MIL Series MOFs
325(2)
12.4.2 Isoreticular MOFs
327(5)
12.4.2.1 Adsorption Comparison of the Isoreticular MOFs
330(2)
12.4.3 NENU Series MOFs
332(1)
12.4.4 MOF-5, Eu-MOF, and MOF-199
333(1)
12.4.5 Amine-Impregnated MIL-100
334(1)
12.4.6 Biodegradable MOFs MIL-88 Series
335(1)
12.4.7 Catalytic MOFs
335(1)
12.4.8 Photo-Degradating MOFs
336(1)
12.4.9 Some Other Studied MOFs
337(1)
12.5 MOF Composites
338(2)
12.5.1 MIL-101 Composite With Graphene Oxide
338(1)
12.5.2 MIL-101 Composite With Graphite Oxide
338(2)
12.6 Generalization Adsorptive Removal of VOCs by MOFs
340(1)
12.7 Simple Modeling the Adsorption
340(4)
12.7.1 Thermodynamic Parameters
340(1)
12.7.2 Dynamic Sorption Methods
341(3)
12.8 Factor Affecting VOCs Adsorption
344(5)
12.8.1 Breathing Phenomena
344(1)
12.8.2 Activation of MOFs
345(1)
12.8.3 Applied Pressure
346(1)
12.8.4 Relative Humidity
347(1)
12.8.5 Breakthrough Conditions
347(1)
12.8.6 Functional Group of MOFs
347(1)
12.8.7 Concentration, Molecular Size, and Type of VOCs
348(1)
12.9 Future Perspective
349(1)
References
350(7)
13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis 357(20)
Gopalram Keerthiga
Peramaiah Karthik
Bernaurdshaw Neppolian
List of Abbreviations
358(1)
13.1 Introduction
358(2)
13.2 Perspective Synthesis of MOF and Their Derived Materials
360(2)
13.3 MOF for Hydrogen Evolution Reaction
362(1)
13.4 MOF for Oxygen Evolution Reaction
363(2)
13.5 MOF for Oxygen Reduction Reaction
365(1)
13.6 MOF for CO2 Electrochemical Reduction Reaction
366(4)
13.6.1 Electrosynthesis of MOF for CO2 Reduction
366(1)
13.6.2 Composite Electrodes as MOF for CO2 Reduction
367(2)
13.6.3 Continuous Flow Reduction of CO2
369(1)
13.6.4 CO2 Electrochemical Reduction in Ionic Liquid
369(1)
13.7 MOF for Electrocatalytic Sensing
370(1)
13.8 Electrocatalytic Features of MOF
371(1)
13.9 Conclusion
372(1)
Acknowledgment
372(1)
References
372(5)
14 Applications of MOFs and Their Composite Materials in Light-Driven Redox Reactions 377(86)
Elizabeth Rojas-Garcia
Jose M. Barrera-Andrade
Elim Albiter
A. Marisela Maubert
Miguel A. Valenzuela
14.1 Introduction
378(9)
14.1.1 MOFs as Photocatalysts
381(1)
14.1.2 Charge Transfer Mechanisms
382(3)
14.1.3 Methods of Synthesis
385(2)
14.2 Pristine MOFs and Their Application in Photocatalysis
387(26)
14.2.1 Group 4 Metallic Clusters
387(6)
14.2.2 Groups 8, 9, and 10 Metallic Clusters
393(1)
14.2.3 Group 11 Metallic Clusters
393(10)
14.2.4 Group 12 Metallic Clusters
403(10)
14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis
413(8)
14.3.1 Ag-MOF Composites
415(2)
14.3.2 Au-MOF Composites
417(1)
14.3.3 Cu-MOF Composites
417(1)
14.3.4 Pd-MOF Composites
418(1)
14.3.5 Pt-MOF Composites
419(2)
14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis
421(21)
14.4.1 Ti02-MOF Composites
422(4)
14.4.2 Graphitic Carbon Nitride-MOF Composites
426(3)
14.4.3 Bismuth-Based Semiconductors
429(1)
14.4.4 Reduced Graphene Oxide-MOF Composites
430(6)
14.4.5 Silver-Based Semiconductors
436(2)
14.4.6 Other Semiconductors
438(4)
14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis
442(4)
14.5.1 Semiconductor-Semiconductor-MOF Composites
442(1)
14.5.2 Semiconductor-Metal-MOF Composites
443(3)
14.6 Conclusions
446(2)
References
448(15)
Index 463
Inamuddin, PhD, is an assistant professor at King Abdulaziz University, Jeddah, Saudi Arabia and is also an assistant professor in the Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India. He has published about 150 research articles in various international scientific journals, 18 book chapters, and 60 edited books with multiple well-known publishers.

Rajender Boddula, PhD, is currently working for the Chinese Academy of Sciences President's International Fellowship Initiative (CAS-PIFI) at the National Center for Nanoscience and Technology (NCNST, Beijing). He has numerous honors, book chapters, and academic papers to his credit and is an editorial board member and a referee for several reputed international peer-reviewed journals.

Mohd Imran Ahamed, PhD, received his PhD from Aligarh Muslim University, Aligarh, India in 2019. He has published several research and review articles in various international scientific journals, and his research work includes ion-exchange chromatography, wastewater treatment, and analysis, bending actuator and electrospinning.

Abdullah M. Asiri is the Head of the Chemistry Department at King Abdulaziz University and the founder and Director of the Center of Excellence for Advanced Materials Research (CEAMR). He is the Editor-in-Chief of the King Abdulaziz University Journal of Science. He has received numerous awards, and serves on the editorial boards of multiple scientific journals and is the Vice President of the Saudi Chemical Society (Western Province Branch). He holds multiple patents, has authored ten books, more than one thousand publications in international journals, and multiple book chapters.
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