Contributors |
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xi | |
Preface |
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xvii | |
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3 | (1) |
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4 | (2) |
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6 | (5) |
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11 | (6) |
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17 | (10) |
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27 | (1) |
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28 | (5) |
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33 | (4) |
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1.9 Conclusions and Perspectives |
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37 | (8) |
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38 | (1) |
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38 | (7) |
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2 Emerging Technologies for Biofuels Production |
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Ahmad Fadzil Ahmad Shuhaili |
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Haswin Kaur Gurdeep Singh |
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45 | (1) |
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2.2 Existing Liquid Biofuel Technologies |
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46 | (1) |
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2.3 Existing Gaseous Biofuel Technologies |
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46 | (3) |
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2.4 Emerging Liquid Biofuels Technologies |
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49 | (15) |
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2.5 Emerging Gaseous Biofuels Technologies |
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64 | (4) |
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2.6 Conclusions and Perspectives |
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68 | (9) |
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70 | (1) |
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71 | (6) |
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3 Systems Analysis Frameworks for Biorefineries |
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77 | (2) |
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3.2 Classification of Biorefineries |
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79 | (5) |
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3.3 Frameworks for Analysis of Biorefineries |
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84 | (4) |
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88 | (2) |
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3.5 Conclusions and Perspectives |
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90 | (5) |
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90 | (5) |
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II SUSTAINABILITY ASSESSMENT OF BIOFUELS |
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4 Economic Assessment of Biofuels |
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95 | (2) |
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97 | (11) |
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4.3 Results of Selected Studies |
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108 | (8) |
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4.4 Conclusions and Perspectives |
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116 | (7) |
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117 | (6) |
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5 Social Assessment of Biofuels |
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123 | (2) |
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125 | (4) |
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5.3 Applications to Biofuels |
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129 | (9) |
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5.4 Conclusion and Perspectives |
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138 | (3) |
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138 | (3) |
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6 Hotspot Environmental Assessment of Biofuels |
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Jegannathan Kenthorai Raman |
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141 | (1) |
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142 | (6) |
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6.3 Hotspots Environmental Assessment |
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148 | (10) |
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6.4 Conclusions and Perspectives |
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158 | (5) |
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159 | (4) |
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7 Wide Scope Environmental Assessment of Biofuels |
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Jegannathan Kenthorai Raman |
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163 | (1) |
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7.2 Methods, Tools, and Materials |
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164 | (4) |
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7.3 Selected Cases of Wide Scope Environmental Assessment of Biomass and Bioenergy |
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168 | (21) |
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7.4 Conclusions and Perspectives |
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189 | (8) |
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191 | (6) |
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8 Integrated Sustainability Assessment of Biofuels |
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197 | (2) |
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199 | (5) |
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8.3 Applications to Biofuels |
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204 | (8) |
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8.4 Conclusions and Perspectives |
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212 | (5) |
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212 | (5) |
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III THERMOCHEMICAL CONVERSION OF LIGNOCELLULOSIC BIOMASS TO BIOFUELS |
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217 | (1) |
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9.2 Components of Lignocellulosic Biomass |
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218 | (5) |
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223 | (2) |
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225 | (1) |
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9.5 Mechanism of Pyrolysis |
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226 | (4) |
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230 | (9) |
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9.7 Economic Analysis of the Pyrolysis Process |
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239 | (1) |
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9.8 Conclusions and Perspectives |
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240 | (5) |
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240 | (5) |
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10 Advanced Hydrothermal Liquefaction of Biomass for Bio-Oil Production |
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245 | (2) |
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10.2 Lignocellulosic and Aquatic Biomass as a Feedstock |
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247 | (1) |
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10.3 Decomposing Mechanism of Biomasses |
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247 | (1) |
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10.4 Hydrothermal Processes |
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248 | (1) |
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10.5 Advanced HTL Process Over the Decade |
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249 | (2) |
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10.6 HTL Process Parameters for Bio-Oil Production |
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251 | (8) |
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10.7 Batch to Continuous HTL Process |
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259 | (1) |
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10.8 Conclusions and Future Perspectives |
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260 | (7) |
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261 | (1) |
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262 | (5) |
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11 Combustion of Lignocellulosic Biomass |
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267 | (1) |
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268 | (2) |
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11.3 Chemistry of Biomass Combustion |
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270 | (2) |
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11.4 Combustion Parameters |
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272 | (2) |
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11.5 Types of Combustion Reactors |
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274 | (4) |
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11.6 Challenges and Research Possibilities |
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278 | (2) |
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11.7 Conclusions and Perspectives |
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280 | (5) |
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282 | (1) |
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282 | (3) |
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12 Gasification of Lignocellulosic Biomass |
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285 | (1) |
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12.2 Feedstock Preparation for Gasification |
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286 | (1) |
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12.3 Initial Steps in the Gasifier |
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287 | (1) |
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12.4 Gasification Reaction Chemistry |
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287 | (1) |
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288 | (4) |
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12.6 Catalytic Gasification |
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292 | (1) |
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12.7 Tar Cleaning and Conditioning |
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293 | (1) |
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12.8 Applications of Synthesis Gas |
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294 | (2) |
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12.9 Conclusion and Perspectives |
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296 | (5) |
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297 | (1) |
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297 | (4) |
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13 Syngas Fermentation Into Biofuels and Biochemicals |
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301 | (1) |
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13.2 Fundamental Aspects of Syngas Formation |
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302 | (4) |
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13.3 Microbiology of Syngas Fermentation |
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306 | (3) |
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13.4 Syngas Characteristics |
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309 | (1) |
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13.5 Developments in Syngas Fermentation for Biofuels and Biochemicals |
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310 | (3) |
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13.6 Factors Affecting Syngas Fermentation |
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313 | (9) |
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13.7 Modeling Syngas Fermentation Processes |
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322 | (1) |
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13.8 Conclusions and Future Perspectives |
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322 | (9) |
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323 | (1) |
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323 | (8) |
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IV BIOCHEMICAL AND BIOTECHNOLOGICAL CONVERSION OF LIGNOCELLULOSIC BIOMASS TO BIOFUELS---BIOETHANOL AND BIOBUTANOL |
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14 Lignocellulosic Bioethanol: Current Status and Future Perspectives |
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Luciana P.S. Vandenberghe |
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331 | (4) |
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14.2 First-Generation Fuel Ethanol Production: The Feedstock, the Process, and Its Constraints |
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335 | (2) |
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14.3 Second-Generation Ethanol Production |
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337 | (4) |
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14.4 Feasibility of Lignocellulosic Ethanol Production |
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341 | (7) |
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14.5 Conclusions and Perspectives |
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348 | (7) |
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350 | (5) |
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15 Biobutanol Production: Microbes, Feedstock, and Strategies |
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Lalitha Devi Gottumukkala |
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15.1 Introduction: Overview of Biobutanol |
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355 | (2) |
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15.2 Recent Advancements in Biobutanol Production |
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357 | (2) |
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359 | (6) |
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15.4 Process Developments |
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365 | (5) |
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15.5 Techno-Economic and Environment Assessment |
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370 | (1) |
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15.6 Conclusions and Perspectives |
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371 | (8) |
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372 | (7) |
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16 Pretreatment Technologies for Lignocellulosic Biomass Deconstruction Within a Biorefinery Perspective |
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M. Ballesteros M.J. Negro |
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379 | (2) |
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16.2 Recent Advances in Lignocellulose Pretreatment |
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381 | (8) |
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16.3 Challenges in Processing Pretreated Biomass |
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389 | (2) |
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16.4 The Role of Pretreatment in Lignocellulosic Biorefineries |
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391 | (2) |
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16.5 Conclusions and Perspectives |
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393 | (8) |
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394 | (1) |
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394 | (7) |
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17 Production of Celluloytic Enzymes for Lignocellulosic Biomass Hydrolysis |
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401 | (1) |
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17.2 Cellulase; Mode of Action |
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402 | (1) |
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17.3 Cellulase Systems and the Control of Cellulase Gene Expression |
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403 | (2) |
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405 | (2) |
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407 | (1) |
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17.6 Bioprocesses for Cellulase Production |
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407 | (5) |
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17.7 Applications of Cellulases |
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412 | (5) |
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17.8 Cellulase Market Scenario |
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417 | (2) |
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17.9 Engineered/Artificial Cellulases |
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419 | (2) |
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17.10 Potentials and Challenges |
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421 | (3) |
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17.11 Conclusions and Perspectives |
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424 | (3) |
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424 | (1) |
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424 | (3) |
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18 Hemicellulases for Lignocellulosics-Based Bioeconomy |
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427 | (1) |
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18.2 Complex Hemicellulosic Structure |
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427 | (1) |
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428 | (5) |
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18.4 Methods for Assay of Hemicellulases |
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433 | (1) |
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18.5 Functional Genomic Approach for Studying Cellulases and Hemicellulases |
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434 | (1) |
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435 | (1) |
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18.7 Applications of Hemicellulases |
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436 | (1) |
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18.8 Conclusions and Perspectives |
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437 | (10) |
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437 | (10) |
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19 Hydrolysis of Cellulosic and Hemicellulosic Biomass |
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447 | (1) |
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448 | (1) |
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19.3 Enzymatic Hydrolysis |
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449 | (5) |
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19.4 Factors Affecting Enzymatic Hydrolysis |
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454 | (2) |
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19.5 Recycling of Enzymes |
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456 | (1) |
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19.6 Methods for Improving Enzymatic Hydrolysis |
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457 | (1) |
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19.7 Kinetic Model for Enzymatic Hydrolysis of Lignocelluloses |
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457 | (1) |
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19.8 Conclusions and Perspectives |
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458 | (3) |
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458 | (1) |
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458 | (3) |
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20 Fermentation Inhibitors in Ethanol and Biogas Processes and Strategies to Counteract Their Effects |
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Adhitya Pitara Sanjaya Ria Millati |
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Keikhosro Karimi Mohammad J. Taherzadeh |
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461 | (1) |
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20.2 Inhibitors for Ethanol and Biogas Production |
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462 | (6) |
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20.3 Inhibitors From Metabolic Product |
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468 | (8) |
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20.4 Strategies for Minimizing the Effects of Inhibitors in Ethanol and Biogas Production |
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476 | (7) |
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20.5 Fermentation Strategy to Overcome Inhibitions |
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483 | (4) |
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20.6 Microorganisms or Microflora Adaptation |
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487 | (1) |
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20.7 Conclusions and Perspectives |
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488 | (15) |
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489 | (14) |
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21 Biodiesel Production: Status and Perspectives |
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503 | (1) |
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21.2 Global Situation of Biodiesel Production |
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504 | (2) |
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21.3 Technological Advance in Biodiesel Production |
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506 | (6) |
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21.4 Toward Efficient Utilization of Crude Glycerol |
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512 | (3) |
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21.5 Biodiesel Production: Strategy Forward |
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515 | (2) |
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21.6 Conclusions and Perspectives |
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517 | (6) |
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517 | (4) |
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521 | (2) |
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22 Biodiesel Production in Supercritical Fluids |
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523 | (2) |
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22.2 Supercritical Fluid Reaction |
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525 | (1) |
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22.3 Biodiesel Production in Noncatalytic Supercritical Fluid Reaction |
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526 | (11) |
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22.4 Conclusions and Perspectives |
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537 | (2) |
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537 | (1) |
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537 | (2) |
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23 Production of Biodiesel Using Palm Oil |
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Nur Azimah Jamalluddin Keat Teong Lee |
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539 | (2) |
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23.2 Production rate of Palm Oil and Palm Biodiesel |
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541 | (3) |
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23.3 Palm Biodiesel Conversion Technology |
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544 | (22) |
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23.4 Conclusion and Perspectives |
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566 | (9) |
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567 | (1) |
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567 | (8) |
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24 Biodiesel Production From Waste Oils |
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575 | (1) |
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24.2 Waste Oil and Its Pretreatment |
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576 | (1) |
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24.3 Technologies for BD Production From Waste Oils |
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577 | (11) |
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24.4 Downstream Processing of Crude BD Product |
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588 | (5) |
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24.5 Economic and Environmental Aspect of BD Production From Waste Oils |
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593 | (1) |
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24.6 Conclusions and Perspectives |
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594 | (7) |
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595 | (6) |
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25 Biodiesel From Microalgae |
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601 | (2) |
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25.2 Nature of Microalgal Lipids and Methods of Extraction |
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603 | (12) |
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25.3 Different Types of Biodiesel Synthesis Pathways |
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615 | (2) |
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25.4 Economic Outlook of Microalgal Biodiesel |
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617 | (5) |
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25.5 Conclusions and Perspectives |
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622 | (7) |
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623 | (6) |
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26 Cultivation of Algae in Photobioreactors for Biodiesel Production |
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629 | (1) |
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26.2 Basic Concepts of Photobioreactor Engineering |
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630 | (4) |
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26.3 Modeling of Microalgae Cultivation Systems |
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634 | (5) |
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26.4 Productivity of Microalgal Cultivation Systems |
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639 | (3) |
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26.5 Engineering Parameters Governing Photobioreactor Productivity |
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642 | (11) |
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26.6 Existing Technology MS |
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26.7 Conclusions and Perspectives |
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653 | (8) |
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654 | (1) |
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654 | (7) |
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27 Biodiesel Production From Oleaginous Microorganisms With Wastes as Raw Materials |
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661 | (1) |
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27.2 Oleaginous Microorganisms and Their Potential for Lipid Production |
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662 | (1) |
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27.3 Waste Substrates for Lipid Fermentation |
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663 | (9) |
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27.4 Coproducts Formed During Lipid Fermentation |
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672 | (2) |
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27.5 Recent Developments in Economical Downstream Processing of Biodiesel |
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674 | (6) |
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27.6 Energy Balance of Biodiesel Production From Oleaginous Microorganisms |
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680 | (4) |
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27.7 Techno economic Studies for Biodiesel Production Through Microbial Lipid |
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684 | (1) |
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685 | (1) |
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27.9 Conclusions and Perspectives |
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686 | (7) |
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687 | (6) |
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VI BIOHYDROGEN PRODUCTION |
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28 Biohydrogen Production: Status and Perspectives |
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693 | (1) |
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28.2 Pathways of Biohydrogen Production |
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694 | (3) |
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697 | (7) |
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704 | (2) |
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28.5 Economics Consideration |
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706 | (1) |
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707 | (1) |
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28.7 Conclusions and Perspectives |
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708 | (7) |
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708 | (7) |
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29 Biohydrogen Production From Bio-Oil via Hydrothermal Liquefaction |
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715 | (2) |
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29.2 State-of-the-Art Technology |
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717 | (1) |
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718 | (1) |
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29.4 Techno-Economic Assessment |
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719 | (2) |
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29.5 Results and Discussion |
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721 | (4) |
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29.6 Uncertainty Analysis |
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725 | (1) |
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29.7 Cost Comparison With Previous Studies |
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726 | (1) |
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29.8 Conclusions and Perspectives |
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727 | (6) |
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728 | (1) |
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728 | (5) |
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30 Biohydrogen Production From Industrial Wastewater |
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733 | (1) |
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30.2 Industrial Wastewater: As a Source of Biohydrogen Production |
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734 | (1) |
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30.3 Reactor System for Biohydrogen Production |
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735 | (12) |
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30.4 Factors Affecting Biohydrogen Production |
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747 | (4) |
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30.5 Challenges and Future prospective |
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751 | (2) |
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30.6 Conclusions and Perspectives |
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753 | (10) |
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753 | (10) |
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31 Biogas Production by Anaerobic Digestion: Status and Perspectives |
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763 | (1) |
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31.2 Anaerobic Digestion Pathway for Organic Matters |
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764 | (2) |
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31.3 Important Environmental Factors and Process Parameters for AD |
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766 | (3) |
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31.4 Reactor Configurations |
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769 | (3) |
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772 | (1) |
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773 | (4) |
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31.7 Conclusions and Perspectives |
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777 | (2) |
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777 | (1) |
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777 | (1) |
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778 | (1) |
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32 Biogas Production From Industrial Effluents |
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779 | (1) |
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780 | (2) |
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782 | (3) |
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32.4 Meat Processing Wastewater |
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785 | (2) |
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32.5 Tapioca Starch Wastewater |
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787 | (4) |
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791 | (4) |
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32.7 Palm Oil Mill Effluent |
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795 | (5) |
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32.8 Biodiesel Wastewater |
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800 | (4) |
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32.9 Seafood Processing Wastewater |
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804 | (4) |
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32.10 Conclusions and Perspectives |
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808 | (9) |
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809 | (7) |
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816 | (1) |
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33 Biogas Upgrading: Current and Emerging Technologies |
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Yifeng Zhang Hans Oechsner |
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Raul Munoz Panagiotis G. Kougias |
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817 | (2) |
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33.2 Biogas Cleaning Technologies |
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819 | (2) |
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33.3 Biogas Upgrading Technologies |
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821 | (16) |
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33.4 Economic Efficiency of Biomethane Production |
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837 | (3) |
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33.5 Conclusions and Perspectives |
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840 | (5) |
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840 | (3) |
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843 | (2) |
Index |
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845 | |