Preface |
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vii | |
Contributing Authors |
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ix | |
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Chapter 1 Design, Implementation, and Economic/Societal Considerations of Chelant-Enhanced Soil Washing |
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1 | (26) |
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1 | (3) |
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1.2 Soil Washing Technology |
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4 | (7) |
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1.3 Chelant-Enhanced Soil Washing |
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11 | (7) |
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1.4 Economic and Societal Considerations |
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18 | (2) |
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20 | (1) |
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21 | (6) |
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Chapter 2 Remediation of Metal-Contaminated Sediments by Means of Chelant-Assisted Washing |
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27 | (32) |
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2.1 Background on Contaminated Sediments |
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27 | (3) |
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2.2 Management and Treatment of Contaminated Sediments |
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30 | (4) |
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2.3 Sediment Washing Using Chelating Agents |
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34 | (5) |
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2.4 Recovery of Chelating Agents from Waste Washing Solutions |
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39 | (2) |
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2.5 Experimental Results of Chelant-Assisted Washing for Metal Removal from Sediments |
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41 | (13) |
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54 | (1) |
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54 | (5) |
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Chapter 3 Operational Conditions of Chelant-Enhanced Soil Washing for Remediation of Metal-Contaminated Soil |
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59 | (33) |
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3.1 Principle of Soil Washing |
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59 | (1) |
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3.2 General Procedure and Application of Soil Washing |
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59 | (2) |
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3.3 Chelant-Enhanced Soil Washing |
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61 | (1) |
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3.4 Factors Influencing Chelant-Enhanced Soil Washing |
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62 | (8) |
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3.5 Risk Assessment and Control of Chelant-Enhanced Soil Washing |
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70 | (6) |
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3.6 A Case Study of EDTA-Enhanced Soil Washing for Remediation of a Demolished Electroplating Site |
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76 | (8) |
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84 | (1) |
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84 | (1) |
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84 | (8) |
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Chapter 4 Electrochemical Treatment and Recovery of Chelating Agents |
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92 | (17) |
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4.1 Remediation of Metal Contaminated Soils |
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92 | (2) |
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4.2 Chemical Treatments of Waste EDTA Soil Washing Solution |
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94 | (2) |
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4.3 Electrochemical Oxidation |
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96 | (3) |
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99 | (1) |
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4.5 Electrochemical EDTA Recycling |
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100 | (4) |
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104 | (1) |
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105 | (4) |
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Chapter 5 Extraction of Metals from Spent Catalyst Using Fresh and Recovered Chelating Agents |
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109 | (32) |
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109 | (2) |
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5.2 Methods to Extract Metals from Spent Catalyst |
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111 | (5) |
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5.3 Advantages of Chelating Agents |
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116 | (1) |
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5.4 Mechanism of Complex Formation of Metal-Chelating Agent |
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117 | (2) |
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5.5 Extraction of Metals from Spent Catalyst with Fresh Chelating Agents |
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119 | (1) |
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5.6 Recycle or Regeneration Methods of Chelating Agents |
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120 | (4) |
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5.7 Characterization of Recycled EDTA |
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124 | (6) |
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5.8 Reusability of Spent Catalyst after Metal Extraction |
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130 | (1) |
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5.9 Extraction Kinetic Models for Chelating Agents |
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131 | (3) |
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134 | (1) |
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135 | (6) |
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Chapter 6 Enhanced Soil Flushing and Washing of Contaminated Soil and Sediments |
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141 | (30) |
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141 | (2) |
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143 | (2) |
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145 | (2) |
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6.4 Use of Acids and Chelating Agents |
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147 | (2) |
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6.5 Surfactant Washing and Flushing |
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149 | (15) |
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164 | (1) |
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165 | (6) |
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Chapter 7 Heavy Metal Leaching from Contaminated Soils during the Percolation of EDTA: Observations and Modeling |
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171 | (27) |
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7.1 Introduction and Outline |
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171 | (5) |
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7.2 Observations: Solubilization of Heavy Metals from a Soil Contaminated by Long-Term Spreading of Sewage Sludge/Wastewater---Reactivity and Kinetics |
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176 | (6) |
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7.3 Observations and Modeling: Solubilization of Heavy Metals from a Soil Polluted by Long-Term Smelting Activities---A Finite Difference Model, including a Kinetic Leaching Term |
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182 | (10) |
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7.4 Potential for Actual Use of Complexing Agents for Soil Decontamination |
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192 | (1) |
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193 | (1) |
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193 | (1) |
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193 | (5) |
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Chapter 8 Roles of Metal-(Hydr)oxides in Chelant-Enhanced (Phyto)extraction |
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198 | (14) |
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198 | (1) |
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8.2 Interactions of Soil (Hydr)oxides with Chelating Agents |
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198 | (11) |
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209 | (1) |
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209 | (1) |
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209 | (3) |
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Chapter 9 Use of Chelating Agents in Electrochemical Remediation of Contaminated Soil |
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212 | (69) |
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212 | (2) |
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9.2 Electrokinetic Remediation of Contaminated Soils |
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214 | (6) |
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9.3 Enhancement Agents in Electrochemical Remediation |
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220 | (8) |
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9.4 Use of Chelating Agents in Electrochemical Remediation |
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228 | (23) |
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9.5 Selection of Chelating Agents in Electrochemical Remediation |
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251 | (2) |
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9.6 Effects of Electrochemical Reactions during Electrochemical Remediation on Performance of Chelating Agents |
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253 | (3) |
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9.1 Limitations of the Use of Chelating Agents in Enhancing Electrochemical Remediation |
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256 | (1) |
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9.8 Future Research Directions |
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257 | (4) |
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261 | (1) |
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262 | (1) |
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262 | (17) |
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279 | (2) |
Editor Biographies |
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281 | (2) |
Index |
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283 | |