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E-grāmata: Chemistry of Polymers

3.33/5 (3 ratings by Goodreads)
(Bluefield Centre for Biomaterials Ltd, UK and Queen Mary University of London, UK)
  • Formāts: 210 pages
  • Izdošanas datums: 17-Jan-2023
  • Izdevniecība: Royal Society of Chemistry
  • Valoda: eng
  • ISBN-13: 9781788011143
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Chemistry of PolymersPalielināt
  • Formāts: 210 pages
  • Izdošanas datums: 17-Jan-2023
  • Izdevniecība: Royal Society of Chemistry
  • Valoda: eng
  • ISBN-13: 9781788011143
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The Chemistry of Polymers, 5th Edition, is fully updated with the latest developments in polymer science providing a highly readable textbook for those requiring a broad overview of the subject.

Like previous editions, the book continues to explore the subject from an applications point of view, providing a comprehensive introduction to all aspects of polymer science including synthesis, structure, properties, degradation and dendrimers. Recent advances in special topics in polymer chemistry and polymers and the environment are also discussed in an informative and up-to-date manner.

The new edition features additional content on recent developments in new polymer synthesis techniques including reversible addition-fragmentation chain transfer (RAFT) polymerization, atom transfer radical polymerization (ATRP) and ring-opening metathesis polymerization (ROMP). The book also contains new content on the latest developments in polymer characterisation methods as well as applications of polymers including co-ordination polymers and lithium-polymer batteries.

The book is essential reading for university students, teachers and scientists who wish to acquire an up-to-the-minute overview of polymer science and its many specialised topics in an informative and easy to read style.



A new revised and updated version of the well-established and highly readable textbook on polymer science.

Recenzijas

"There have been countless books on polymer science and chemistry, some more successful than others, with one of the best known being Brydsons Plastics Materials. This book is in the same league, deserving equal reverence but covers the subject more succinctly, making it an excellent first purchase on the topic."



"The text is very well written, dealing with a very scientific subject in a clear, easy to read manner."



"This is an excellent introduction and overview of the subject. It will be a useful core text for students studying polymers as part of a materials or chemistry degree and will help designers understand the properties of polymers. I would strongly recommend it as a first purchase in this subject area."

1 Polymer Chemistry
1(24)
1.1 Basic Concepts
1(1)
1.2 The History of the Concept of the Macromolecule
2(2)
1.3 Classification of Polymers
4(2)
1.4 Structure and Properties of Polymers
6(19)
2 Polymerisation Reactions
25(23)
2.1 Chain Polymerisation
26(3)
2.2 Arrangement of Monomer Units
29(1)
2.3 Kinetics of Chain Polymerisation
30(2)
2.4 Autoacceleration
32(1)
2.5 Practical Methods of Chain Polymerisation
33(4)
2.6 Other Chain Polymerisation Mechanisms
37(2)
2.7 Recent Developments in "Living" Polymerisation
39(4)
2.8 Step Polymerisation
43(1)
2.9 Step Polymerisation with Polyfunctional Monomers
44(1)
2.10 Copolymerisation
45(3)
3 Polymer Structure
48(16)
3.1 Polymer Stereochemistry
48(2)
3.2 Polymer Crystallinity
50(4)
3.3 Thermal and Mechanical Properties
54(10)
4 Crosslinking
64(13)
4.1 Introduction
64(3)
4.2 Phenol--Formaldehyde Resins
67(2)
4.3 Unsaturated Polyester Resins
69(3)
4.4 Polyurethanes
72(2)
4.5 Epoxy Resins
74(3)
5 Polymer Solutions
77(16)
5.1 Introduction
77(1)
5.2 Dissolution of Polymers
77(1)
5.3 Solubility Parameters
78(2)
5.4 Simple Liquid Mixtures and Raoult's Law
80(1)
5.5 Entropy of Mixing
81(2)
5.6 Real Molecules in Dilute Solution
83(1)
5.7 Shapes of Polymer Molecules in Solution
84(2)
5.8 Reptation Model of Molecular Motion
86(1)
5.9 Water-soluble Polymers
87(2)
5.10 Uses of High-viscosity Polymer Solutions
89(1)
5.11 Polymer Melts
90(3)
6 Methods of Determining Relative Molar Mass
93(18)
6.1 Introduction
93(2)
6.2 Molar Masses from Colligative Properties
95(2)
6.3 Light Scattering
97(5)
6.4 Viscosity Methods of Determining Relative Molar Mass
102(2)
6.5 End Group Analysis
104(1)
6.6 Gel Permeation Chromatography
105(3)
6.7 MALDI Mass Spectrometry
108(3)
7 Mechanical Properties of Polymers
111(25)
7.1 Introduction
111(1)
7.2 Stress, Strain, and Young's Modulus
112(1)
7.3 Brittle and Tough Fracture
112(3)
7.4 Types of Strength
115(1)
7.5 The Influence of Surfaces
116(3)
7.6 Viscoelasticity
119(2)
7.7 Creep and Stress Relaxation
121(2)
7.8 Cold Drawing
123(1)
7.9 Dynamic Tests
124(2)
7.10 Time/Temperature Relationship
126(1)
7.11 Rubberlike Elasticity
127(3)
7.12 Reinforced Polymers
130(3)
7.13 Practical Measurements of Mechanical Properties
133(3)
Further Reading
135(1)
8 Polymer Degradation
136(16)
8.1 Introduction
136(1)
8.2 Behaviour of Polymers in Fires
136(2)
8.3 Assessment of Combustion Behaviour
138(1)
8.4 Improvement of Stability of Polymers in Fires
139(2)
8.5 Weathering of Polymers
141(2)
8.6 Protection of Polymers From Photo-oxidation
143(2)
8.7 Biological Degradation of Polymers
145(2)
8.8 Exploitation of Polymer Degradation
147(3)
8.9 Polymer Light Emitting Diodes
150(2)
9 Dendrimers
152(18)
9.1 Introduction
152(3)
9.2 Organic Dendrimers
155(3)
9.3 Supramolecular Dendrimers
158(1)
9.4 Shapes and Conformations of Dendrimers
159(1)
9.5 Dendrimer Micelles
160(1)
9.6 Characterization of Dendrimers
161(5)
9.7 Applications of Dendrimers
166(2)
9.8 Megamers
168(2)
Further Reading
169(1)
10 Special Topics in Polymer Chemistry
170(23)
10.1 Introduction
170(1)
10.2 Polymers in Medicine
170(3)
10.3 Ionomers
173(3)
10.4 Electronically Conducting Polymers
176(2)
10.5 Interpenetrating Polymer Networks
178(2)
10.6 Inorganic Polymers
180(3)
10.7 Polymer Liquid Crystals
183(2)
10.8 Polymers for Food Packaging
185(2)
10.9 Polymers for Controlled Drug Delivery
187(3)
10.10 Lithium--Polymer Batteries
190(1)
10.11 Co-ordination Polymers
191(2)
Further Reading
192(1)
11 Polymers and the Environment
193(11)
11.1 Introduction
193(1)
11.2 Pollution by Polymers
193(3)
11.3 The Nature of the Problem
196(2)
11.4 Polymers and Energy
198(1)
11.5 Recycling of Polymers
198(2)
11.6 Degradable Polymers
200(1)
11.7 Green Polymerisation
201(1)
11.8 The Future
202(2)
Further Reading
203(1)
Bibliography 204(1)
Subject Index 205
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