Preface |
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ix | |
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Chemistry and structure of reactive polymers |
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1 | (168) |
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The physical structure of polymers |
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1 | (22) |
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Linear polymers as freely jointed chains |
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2 | (3) |
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Conformations of linear hydrocarbon polymers |
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5 | (3) |
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Molar mass and molar-mass distribution |
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8 | (3) |
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Development of the solid state from the melt |
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11 | (12) |
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Controlled molecular architecture |
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23 | (82) |
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24 | (12) |
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Different polymer architectures achieved by step polymerization |
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36 | (23) |
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59 | (26) |
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Obtaining different polymer architectures by addition polymerization |
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85 | (14) |
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Networks from addition polymerization |
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99 | (6) |
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Polymer blends and composites |
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105 | (22) |
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106 | (5) |
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Phase-separation phenomena |
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111 | (15) |
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Interpenetrating networks |
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126 | (1) |
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Degradation and stabilization |
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127 | (42) |
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Free-radical formation during melt processing |
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128 | (11) |
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Free-radical formation in the presence of oxygen |
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139 | (10) |
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Control of free-radical reactions during processing |
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149 | (13) |
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162 | (7) |
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Physics and dynamics of reactive polymers |
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169 | (26) |
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169 | (1) |
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Polymer physics and dynamics |
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169 | (6) |
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Polymer physics and motion - early models |
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169 | (1) |
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Theories of polymer dynamics |
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170 | (5) |
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Introduction to the physics of reactive polymers |
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175 | (4) |
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176 | (1) |
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Reactively modified polymers |
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177 | (2) |
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Physical transitions in curing systems |
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179 | (7) |
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Gelation and vitrification |
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180 | (1) |
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181 | (1) |
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Time-temperature-transformation (TTT) diagrams |
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181 | (5) |
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Reactive systems without major transitions |
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186 | (1) |
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Physicochemical models of reactive polymers |
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186 | (9) |
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187 | (4) |
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191 | (1) |
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192 | (3) |
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Chemical and physical analyses for reactive polymers |
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195 | (126) |
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Monitoring physical and chemical changes during reactive processing |
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195 | (1) |
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Differential scanning calorimetry (DSC) |
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196 | (12) |
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196 | (1) |
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Isothermal DSC experiments for polymer chemorheology |
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197 | (5) |
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Modulated DSC experiments for chemorheology |
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202 | (1) |
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Scanning DSC experiments for chemorheology |
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203 | (3) |
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Process-control parameters from time-temperature superposition |
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206 | (1) |
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Kinetic models for network-formation from DSC |
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207 | (1) |
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Spectroscopic methods of analysis |
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208 | (51) |
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Information from spectroscopic methods |
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208 | (1) |
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Magnetic resonance spectroscopy |
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209 | (4) |
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Vibrational spectroscopy overview - selection rules |
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213 | (3) |
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Fourier-transform infrared (FT-IR) and sampling methods: transmission, reflection, emission, excitation |
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216 | (6) |
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Mid-infrared (MIR) analysis of polymer reactions |
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222 | (13) |
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Near-infrared (NIR) analysis of polymer reactions |
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235 | (5) |
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Raman-spectral analysis of polymer reactions |
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240 | (4) |
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UV-visible spectroscopy and fluorescence analysis of polymer reactions |
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244 | (11) |
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Chemiluminescence and charge-recombination luminescence |
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255 | (4) |
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259 | (12) |
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Principles of fibre-optics |
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259 | (4) |
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Coupling of fibre-optics to reacting systems |
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263 | (8) |
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Chemometrics and statistical analysis of spectral data |
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271 | (11) |
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Multivariate curve resolution |
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272 | (3) |
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275 | (5) |
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Other curve-resolution and calibration methods |
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280 | (2) |
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Experimental techniques for determining physical properties during cure |
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282 | (39) |
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282 | (1) |
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283 | (4) |
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287 | (5) |
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292 | (13) |
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305 | (6) |
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Dual physicochemical analysis |
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311 | (1) |
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312 | (9) |
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Chemorheological techniques for reactive polymers |
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321 | (30) |
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321 | (1) |
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321 | (6) |
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Fundamental chemorheology |
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321 | (6) |
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327 | (9) |
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327 | (9) |
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336 | (1) |
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Chemorheological techniques |
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336 | (9) |
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338 | (1) |
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Chemoviscosity profiles - shear-rate effects, ηs = ηs(γ, T) |
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338 | (4) |
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Chemoviscosity profiles - cure effects, ηc = ηc(α, T) |
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342 | (1) |
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Filler effects on viscosity: ηsr(F) and ηc(F) |
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343 | (1) |
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Chemoviscosity profiles - combined effects, ηall = ηall(γ α T) |
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344 | (1) |
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344 | (1) |
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345 | (6) |
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347 | (4) |
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Chemorheology and chemorheological modelling |
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351 | (24) |
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351 | (1) |
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Chemoviscosity and chemorheological models |
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351 | (19) |
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351 | (6) |
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357 | (13) |
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Reactive-extrusion systems and elastomer/rubber-processing systems |
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370 | (1) |
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Chemorheological models and process modelling |
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370 | (5) |
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371 | (4) |
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Industrial technologies, chemorheological modelling and process modelling for processing reactive polymers |
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375 | (60) |
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375 | (1) |
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375 | (3) |
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Process diagram and description |
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375 | (1) |
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Quality-control tests and important process variables |
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375 | (1) |
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376 | (1) |
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Chemorheological and process modelling |
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376 | (2) |
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Potting, encapsulation, sealing and foaming |
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378 | (2) |
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Process diagram and description |
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378 | (1) |
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Quality-control tests and important process variables |
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379 | (1) |
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379 | (1) |
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Chemorheological and process modelling |
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380 | (1) |
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380 | (5) |
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380 | (2) |
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382 | (3) |
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385 | (6) |
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Process diagram and description |
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385 | (2) |
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Quality-control tests and important process variables |
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387 | (1) |
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388 | (1) |
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Chemorheological and process modelling |
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389 | (2) |
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391 | (16) |
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391 | (2) |
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393 | (2) |
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Compression, SMC, DMC and BMC moulding |
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395 | (2) |
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397 | (3) |
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Reaction injection moulding |
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400 | (3) |
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Thermoset injection moulding |
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403 | (2) |
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405 | (1) |
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Autoclave moulding (prepreg) |
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406 | (1) |
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Rubber mixing and processing |
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407 | (6) |
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407 | (2) |
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409 | (4) |
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413 | (7) |
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413 | (2) |
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415 | (1) |
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Gamma-irradiation processing |
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416 | (1) |
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Electron-beam-irradiation processing |
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417 | (3) |
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420 | (6) |
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Rapid prototyping and manufacturing |
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420 | (4) |
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424 | (2) |
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426 | (9) |
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Sensors for real-time process monitoring |
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426 | (3) |
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Real-time monitoring using fibre optics |
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429 | (2) |
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431 | (4) |
Glossary of commonly used terms |
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435 | (5) |
Index |
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440 | |