Atjaunināt sīkdatņu piekrišanu

Chemorheology of Polymers: From Fundamental Principles to Reactive Processing [Hardback]

  • Formāts: Hardback, 454 pages, height x width x depth: 253x180x25 mm, weight: 1030 g, 66 Tables, unspecified; 3 Halftones, unspecified
  • Izdošanas datums: 28-May-2009
  • Izdevniecība: Cambridge University Press
  • ISBN-10: 0521807190
  • ISBN-13: 9780521807197
  • Hardback
  • Cena: 217,27 €
  • Grāmatu piegādes laiks ir 3-4 nedēļas, ja grāmata ir uz vietas izdevniecības noliktavā. Ja izdevējam nepieciešams publicēt jaunu tirāžu, grāmatas piegāde var aizkavēties.
  • Daudzums:
  • Ielikt grozā
  • Piegādes laiks - 4-6 nedēļas
  • Pievienot vēlmju sarakstam
  • Formāts: Hardback, 454 pages, height x width x depth: 253x180x25 mm, weight: 1030 g, 66 Tables, unspecified; 3 Halftones, unspecified
  • Izdošanas datums: 28-May-2009
  • Izdevniecība: Cambridge University Press
  • ISBN-10: 0521807190
  • ISBN-13: 9780521807197
Includes coverage of thermoplastics, thermoset and reactive polymers, together with practical industrial processes and the current chemorheological models and tools.

Understanding the dynamics of reactive polymer processes allows scientists to create new, high value, high performance polymers. Chemorheology of Polymers provides an indispensable resource for researchers and practitioners working in this area, describing theoretical and industrial approaches to characterising the flow and gelation of reactive polymers. Beginning with an in-depth treatment of the chemistry and physics of thermoplastics, thermoset and reactive polymers, the core of the book focuses on fundamental characterization of reactive polymers, rheological (flow characterization) techniques and the kinetic and chemorheological models of these systems. Uniquely, the coverage extends to a complete review of the practical industrial processes used for these polymers and an insight into the current chemorheological models and tools used to describe and control each process. This book will appeal to polymer scientists working on reactive polymers within materials science, chemistry and chemical engineering departments as well as polymer process engineers in industry.

Papildus informācija

Includes coverage of thermoplastics, thermoset and reactive polymers, together with practical industrial processes and the current chemorheological models and tools.
Preface ix
Chemistry and structure of reactive polymers
1(168)
The physical structure of polymers
1(22)
Linear polymers as freely jointed chains
2(3)
Conformations of linear hydrocarbon polymers
5(3)
Molar mass and molar-mass distribution
8(3)
Development of the solid state from the melt
11(12)
Controlled molecular architecture
23(82)
Stepwise polymerization
24(12)
Different polymer architectures achieved by step polymerization
36(23)
Addition polymerization
59(26)
Obtaining different polymer architectures by addition polymerization
85(14)
Networks from addition polymerization
99(6)
Polymer blends and composites
105(22)
Miscibility of polymers
106(5)
Phase-separation phenomena
111(15)
Interpenetrating networks
126(1)
Degradation and stabilization
127(42)
Free-radical formation during melt processing
128(11)
Free-radical formation in the presence of oxygen
139(10)
Control of free-radical reactions during processing
149(13)
References
162(7)
Physics and dynamics of reactive polymers
169(26)
Chapter rationale
169(1)
Polymer physics and dynamics
169(6)
Polymer physics and motion - early models
169(1)
Theories of polymer dynamics
170(5)
Introduction to the physics of reactive polymers
175(4)
Network polymers
176(1)
Reactively modified polymers
177(2)
Physical transitions in curing systems
179(7)
Gelation and vitrification
180(1)
Phase separation
181(1)
Time-temperature-transformation (TTT) diagrams
181(5)
Reactive systems without major transitions
186(1)
Physicochemical models of reactive polymers
186(9)
Network models
187(4)
Reactive polymer models
191(1)
References
192(3)
Chemical and physical analyses for reactive polymers
195(126)
Monitoring physical and chemical changes during reactive processing
195(1)
Differential scanning calorimetry (DSC)
196(12)
An outline of DSC theory
196(1)
Isothermal DSC experiments for polymer chemorheology
197(5)
Modulated DSC experiments for chemorheology
202(1)
Scanning DSC experiments for chemorheology
203(3)
Process-control parameters from time-temperature superposition
206(1)
Kinetic models for network-formation from DSC
207(1)
Spectroscopic methods of analysis
208(51)
Information from spectroscopic methods
208(1)
Magnetic resonance spectroscopy
209(4)
Vibrational spectroscopy overview - selection rules
213(3)
Fourier-transform infrared (FT-IR) and sampling methods: transmission, reflection, emission, excitation
216(6)
Mid-infrared (MIR) analysis of polymer reactions
222(13)
Near-infrared (NIR) analysis of polymer reactions
235(5)
Raman-spectral analysis of polymer reactions
240(4)
UV-visible spectroscopy and fluorescence analysis of polymer reactions
244(11)
Chemiluminescence and charge-recombination luminescence
255(4)
Remote spectroscopy
259(12)
Principles of fibre-optics
259(4)
Coupling of fibre-optics to reacting systems
263(8)
Chemometrics and statistical analysis of spectral data
271(11)
Multivariate curve resolution
272(3)
Multivariate calibration
275(5)
Other curve-resolution and calibration methods
280(2)
Experimental techniques for determining physical properties during cure
282(39)
Torsional braid analysis
282(1)
Mechanical properties
283(4)
Dielectric properties
287(5)
Rheology
292(13)
Other techniques
305(6)
Dual physicochemical analysis
311(1)
References
312(9)
Chemorheological techniques for reactive polymers
321(30)
Introduction
321(1)
Chemorheology
321(6)
Fundamental chemorheology
321(6)
Chemoviscosity profiles
327(9)
Chemoviscosity
327(9)
Gel effects
336(1)
Chemorheological techniques
336(9)
Standards
338(1)
Chemoviscosity profiles - shear-rate effects, ηs = ηs(γ, T)
338(4)
Chemoviscosity profiles - cure effects, ηc = ηc(α, T)
342(1)
Filler effects on viscosity: ηsr(F) and ηc(F)
343(1)
Chemoviscosity profiles - combined effects, ηall = ηall(γ α T)
344(1)
Process parameters
344(1)
Gelation techniques
345(6)
References
347(4)
Chemorheology and chemorheological modelling
351(24)
Introduction
351(1)
Chemoviscosity and chemorheological models
351(19)
Neat systems
351(6)
Filled systems
357(13)
Reactive-extrusion systems and elastomer/rubber-processing systems
370(1)
Chemorheological models and process modelling
370(5)
References
371(4)
Industrial technologies, chemorheological modelling and process modelling for processing reactive polymers
375(60)
Introduction
375(1)
Casting
375(3)
Process diagram and description
375(1)
Quality-control tests and important process variables
375(1)
Typical systems
376(1)
Chemorheological and process modelling
376(2)
Potting, encapsulation, sealing and foaming
378(2)
Process diagram and description
378(1)
Quality-control tests and important process variables
379(1)
Typical systems
379(1)
Chemorheological and process modelling
380(1)
Thermoset extrusion
380(5)
Extrusion
380(2)
Pultrusion
382(3)
Reactive extrusion
385(6)
Process diagram and description
385(2)
Quality-control tests and important process variables
387(1)
Typical systems
388(1)
Chemorheological and process modelling
389(2)
Moulding processes
391(16)
Open-mould processes
391(2)
Resin-transfer moulding
393(2)
Compression, SMC, DMC and BMC moulding
395(2)
Transfer moulding
397(3)
Reaction injection moulding
400(3)
Thermoset injection moulding
403(2)
Press moulding (prepreg)
405(1)
Autoclave moulding (prepreg)
406(1)
Rubber mixing and processing
407(6)
Rubber mixing processes
407(2)
Rubber processing
409(4)
High-energy processing
413(7)
Microwave processing
413(2)
Ultraviolet processing
415(1)
Gamma-irradiation processing
416(1)
Electron-beam-irradiation processing
417(3)
Novel processing
420(6)
Rapid prototyping and manufacturing
420(4)
Microlithography
424(2)
Real-time monitoring
426(9)
Sensors for real-time process monitoring
426(3)
Real-time monitoring using fibre optics
429(2)
References
431(4)
Glossary of commonly used terms 435(5)
Index 440
Peter J. Halley is a Professor in the School of Engineering and a Group Leader in the Australian Institute for Bioengineering and Nanotechnology (AIBN) at the University of Queensland. He is a Fellow of the Institute of Chemical Engineering (FIChemE) and a Fellow of the Royal Australian Chemical Institute (FRACI). Graeme A. George is Professor of Polymer Science in the School of Physical and Chemical Sciences, Queensland University of Technology. He is a Fellow and Past-president of the Royal Australian Chemical Institute and a Member of the Order of Australia. He has received several awards recognizing his contribution to international polymer science.