Contributors |
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xii | |
Preface |
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xiii | |
Introduction |
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xv | |
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Introduction to Colloidal Dispersions |
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1 | (13) |
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1 | (2) |
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3 | (2) |
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3 | (1) |
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4 | (1) |
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Average particle separation |
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5 | (1) |
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5 | (1) |
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5 | (1) |
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Preparation of colloidal dispersions |
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6 | (3) |
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6 | (2) |
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8 | (1) |
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Properties of dilute dispersions |
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9 | (2) |
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Properties of concentrated dispersions |
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11 | (1) |
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Control of colloid stability |
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12 | (2) |
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13 | (1) |
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General textbooks in colloid and surface science |
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13 | (1) |
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Charge in Colloidal Systems |
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14 | (22) |
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14 | (1) |
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The origin of surface charge |
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14 | (2) |
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Ionisation of surface groups |
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15 | (1) |
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15 | (1) |
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Dissolution of ionic solids |
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16 | (1) |
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16 | (1) |
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Potential determining ions |
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16 | (1) |
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The distribution of inert ions at a charged interface |
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16 | (13) |
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The mercury/electrolyte interface |
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17 | (2) |
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19 | (3) |
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22 | (3) |
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25 | (3) |
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28 | (1) |
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28 | (1) |
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Electrokinetic properties |
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29 | (7) |
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30 | (1) |
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Streaming potential measurements |
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30 | (1) |
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31 | (1) |
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32 | (3) |
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Electroacoustic technique |
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35 | (1) |
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35 | (1) |
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36 | (14) |
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36 | (1) |
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The colloidal pair potential |
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36 | (6) |
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37 | (1) |
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38 | (2) |
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Effect of particle concentration |
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40 | (1) |
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40 | (2) |
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42 | (4) |
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42 | (1) |
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43 | (1) |
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44 | (1) |
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45 | (1) |
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46 | (3) |
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Diffusion limited rapid coagulation |
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46 | (1) |
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Interaction limited coagulation |
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47 | (1) |
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Experimental determination of the ccc |
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48 | (1) |
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49 | (1) |
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49 | (1) |
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Surfactant Aggregation and Adsorption at Interfaces |
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50 | (27) |
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Characteristic features of surfactants |
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50 | (1) |
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Classification and applications of surfactants |
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51 | (4) |
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51 | (2) |
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Surfactant uses and development |
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53 | (2) |
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Adsorption of surfactants at interfaces |
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55 | (7) |
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Surface tension and surface activity |
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55 | (1) |
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Surface excess and thermodynamics of adsorption |
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56 | (4) |
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Efficiency and effectiveness of surfactant adsorption |
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60 | (2) |
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62 | (1) |
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62 | (1) |
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63 | (1) |
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63 | (7) |
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Thermodynamics of micellisation |
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63 | (4) |
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Factors affecting the CMC |
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67 | (1) |
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Structure of micelles and molecular packing |
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68 | (2) |
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Liquid crystalline mesophases |
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70 | (7) |
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70 | (2) |
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72 | (1) |
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73 | (1) |
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74 | (3) |
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77 | (21) |
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Microemulsions: definition and history |
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77 | (1) |
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Theory of formation and stability |
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78 | (3) |
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Interfacial tension in microemulsions |
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78 | (1) |
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79 | (2) |
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Physicochemical properties |
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81 | (17) |
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Predicting microemulsion type |
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81 | (4) |
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Surfactant film properties |
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85 | (5) |
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Microemulsion phase behaviour |
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90 | (6) |
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96 | (2) |
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Polymers and Polymer Solutions |
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98 | (15) |
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98 | (1) |
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98 | (2) |
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99 | (1) |
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99 | (1) |
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99 | (1) |
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100 | (1) |
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Polymer physical properties |
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100 | (2) |
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102 | (1) |
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Theoretical models of polymer structure |
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102 | (4) |
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103 | (1) |
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104 | (1) |
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Radius of gyration in ideal solution |
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104 | (1) |
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104 | (1) |
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105 | (1) |
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106 | (1) |
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Measuring polymer molecular weight |
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106 | (2) |
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108 | (5) |
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112 | (1) |
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113 | (30) |
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113 | (4) |
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113 | (1) |
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The size and shape of polymers in solution |
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114 | (2) |
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Adsorption of small molecules |
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116 | (1) |
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117 | (1) |
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117 | (1) |
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The Flory surface parameter Xs |
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117 | (1) |
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Models and simulations for terminally attached chains |
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118 | (10) |
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118 | (1) |
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Exact enumeration: terminally attached chains |
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119 | (2) |
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Approximate methods: terminally attached chains |
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121 | (1) |
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Scaling models for terminally attached chains |
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122 | (1) |
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Physically adsorbed chains: Scheutjens and Fleer theory |
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123 | (3) |
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Scaling theory for physical adsorption |
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126 | (2) |
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128 | (8) |
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128 | (1) |
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128 | (3) |
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131 | (2) |
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133 | (3) |
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136 | (4) |
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139 | (1) |
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140 | (1) |
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141 | (2) |
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141 | (2) |
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Effect of Polymers on Colloid Stability |
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143 | (16) |
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143 | (1) |
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143 | (1) |
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Limitations of charge stabilisation |
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143 | (1) |
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Effect of polymers on interactions |
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144 | (1) |
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Particle interaction potential |
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144 | (1) |
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144 | (1) |
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145 | (6) |
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145 | (3) |
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148 | (1) |
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149 | (2) |
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151 | (4) |
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155 | (2) |
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157 | (2) |
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157 | (2) |
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159 | (21) |
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159 | (1) |
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159 | (1) |
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160 | (1) |
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161 | (1) |
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161 | (1) |
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162 | (2) |
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Liquid spreading and spreading coefficients |
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164 | (1) |
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165 | (1) |
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166 | (2) |
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168 | (2) |
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Spreading of a liquid on a liquid |
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170 | (2) |
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Characterisation of a solid surface |
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172 | (1) |
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Polar and dispersive components |
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172 | (1) |
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173 | (1) |
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174 | (2) |
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176 | (2) |
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178 | (2) |
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178 | (2) |
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180 | (21) |
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180 | (4) |
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Generating and sampling aerosol |
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184 | (4) |
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185 | (1) |
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186 | (2) |
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Determining particle concentration and size |
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188 | (7) |
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Determining number concentration |
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189 | (1) |
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Determining mass concentration |
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189 | (1) |
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Determining particle size |
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190 | (5) |
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Determining particle composition |
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195 | (4) |
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Sampling and off-line analysis |
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195 | (1) |
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196 | (1) |
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197 | (2) |
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199 | (2) |
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200 | (1) |
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201 | (27) |
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201 | (1) |
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201 | (11) |
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201 | (2) |
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203 | (3) |
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206 | (1) |
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207 | (3) |
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Shear thinning and thickening behaviour |
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210 | (2) |
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Rheometry and viscoelasticity |
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212 | (7) |
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Viscoelasticity and Deborah number |
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212 | (1) |
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Oscillation and linearity |
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212 | (2) |
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214 | (1) |
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Liquid and solid behaviour |
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214 | (2) |
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Sedimentation and storage stability |
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216 | (3) |
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Examples of soft materials |
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219 | (8) |
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Simple particles and polymers |
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220 | (1) |
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Networks and functionalisation |
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221 | (2) |
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223 | (2) |
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225 | (2) |
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227 | (1) |
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227 | (1) |
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Scattering and Reflection Techniques |
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228 | (27) |
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228 | (1) |
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The principle of a scattering experiment |
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229 | (1) |
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Radiation for scattering experiments |
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230 | (1) |
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231 | (2) |
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233 | (1) |
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234 | (1) |
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235 | (1) |
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Small angle scattering apparatus |
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235 | (2) |
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Scattering and absorption by atoms |
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237 | (1) |
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Scattering length density |
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237 | (2) |
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Small angle scattering from a dispersion |
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239 | (1) |
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Form factor for spherical particle |
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240 | (1) |
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Determining particle size from SANS and SAXS |
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240 | (1) |
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Guinier plots to determine radius of gyration |
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241 | (1) |
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Determination of particle shape |
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242 | (1) |
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242 | (1) |
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Determination of particle size distribution |
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242 | (2) |
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Alignment of anisotropic particles |
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244 | (1) |
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245 | (1) |
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Contrast variation using SANS |
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246 | (1) |
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247 | (3) |
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Introduction to X-ray and neutron reflection |
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250 | (1) |
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250 | (1) |
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A simple example of a reflection measurement |
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251 | (1) |
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252 | (3) |
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253 | (2) |
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255 | (11) |
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255 | (1) |
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Manipulating matter with light |
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255 | (3) |
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Force generation in optical tweezers |
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258 | (2) |
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260 | (1) |
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261 | (4) |
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Measuring nanometre displacements |
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261 | (1) |
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Brownian fluctuations in an optical trap |
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262 | (1) |
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Dynamical complexity in colloidal gels |
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263 | (2) |
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265 | (1) |
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265 | (1) |
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266 | (17) |
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General features of (electron) optical imaging systems |
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266 | (2) |
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268 | (7) |
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268 | (1) |
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268 | (1) |
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269 | (1) |
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270 | (2) |
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272 | (3) |
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275 | (6) |
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275 | (1) |
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275 | (1) |
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275 | (6) |
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281 | (2) |
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282 | (1) |
Index |
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283 | |