List of Figures |
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xiii | |
Preface |
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xxxiii | |
About the Author |
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xlv | |
Chapter 1 Semiconductors |
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1 | (48) |
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1.1 Metals, Semiconductors, and Insulators |
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1.2 Energy Band Formation |
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1.3 General Properties of the Bandgap |
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1.3.1 Carrier Generation and Recombination |
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1.3.2 Pressure Dependence of the Bandgap |
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1.3.3 Temperature Dependence of the Bandgap |
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1.3.4 Direct and Indirect Bandgaps |
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1.3.4.1 Electrons in Solids |
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1.3.4.2 Electrons in the Conduction Band |
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1.6.1 Saturated Carrier Velocities |
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1.7 Conduction in Semiconductors |
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1.7.1 Intrinsic Semiconductors |
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1.7.1.1 Intrinsic Carrier Concentration |
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1.7.2 Extrinsic Semiconductors |
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1.7.2.1 Donors and Acceptors |
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1.7.2.2 Extrinsic Carrier Concentration |
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1.7.2.3 Doping Dependence of the Energy Bandgap |
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1.7.2.4 Practical Considerations |
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1.7.3 Conductivity and Resistivity |
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Chapter 2 Growth Techniques |
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49 | (70) |
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2.1.3 The Pearson Notation |
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2.2 Underlying Crystal Structure of Compound Semiconductors |
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2.2.1 Lattice Constant and Bandgap Energy of Alloy Semiconductors |
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2.2.3 Common Semiconductor Structures |
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2.2.4 Polycrystalline and Amorphous Structures |
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2.4.2 Line Defects (Dislocations) |
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2.4.2.1 Edge Dislocations |
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2.5.1 Material Purification |
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2.6 Bulk Growth Techniques |
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2.6.2 Liquid Encapsulated Czochralski (LEC) |
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2.6.2.1 Limitations of the Czochralski Method |
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2.6.3 Vapor Pressure Controlled Czochralski (VCz) |
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2.6.4 Float-Zone Growth Technique (FZ) |
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2.6.5 Bridgman-Stockbarger (B-S) |
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2.6.6 High Pressure Bridgman (HPB) |
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2.6.7 Travelled Molten Zone (TMZ) or Heater Method (THM) |
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2.6.8 Vertical Gradient Freeze (VGF) |
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2.8.2 Strain and Electronic Properties |
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2.8.4 Bandgap Engineering |
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2.9 Growth Techniques: VPE, LPE, MBE, and MOCVD |
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2.9.1 Liquid-Phase Epitaxy (LPE) |
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2.9.2 Chemical Vapor Deposition (CVD)/ Vapor-Phase Epitaxy (VPE) |
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2.9.2.1 Doping in Vapor Deposition Systems |
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2.9.3 The Multi-Tube Physical Vapor Transport (MTVPT) Technique |
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2.9.4 Molecular-Beam Epitaxy (MBE) |
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2.9.5 Metal Organic Chemical Vapor Deposition (MOCVD) |
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Chapter 3 Detector Fabrication |
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119 | (88) |
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3.1 Mechanical Processing Overview |
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3.1.3 Lapping and Polishing |
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3.2 Detector Characterization |
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3.2.1.1 Inductively Coupled Plasma Spectroscopy (ICP-MS and ICP-OES) |
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3.2.1.2 Glow-Discharge Mass Spectrometry (GDMS) |
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3.2.2 Crystallographic Characterization |
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3.2.2.1 Single-Crystal X-Ray Diffraction |
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3.2.2.2 Powder Diffraction |
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3.2.2.3 Rocking Curve (RC) Measurements |
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3.2.2.4 XRD and Detector Performance |
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3.2.3 Electrical Characterization |
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3.2.3.1 Current-Voltage (I-V) Measurements |
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3.2.3.2 Contact Characterization |
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3.2.3.3 Measuring Contact Resistance |
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3.2.3.4 Capacitance-Voltage (C-V) Measurements |
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3.2.4 Electronic Characterization |
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3.2.4.1 Determining the Majority Carrier |
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3.2.4.2 Determining Effective Mass |
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3.2.5 Evaluating the Charge Transport Properties |
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3.2.5.1 Estimating the Mobilities |
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3.2.5.2 Estimating the Mu-Tau (u1) Products |
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3.2.5.3 Limitations of the Hecht Equation |
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3.2.5.4 Measuring the Charge Collection Efficiency |
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3.2.6 Defect Characterization |
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3.2.6.1 Thermally Stimulated Current (TSC) Spectroscopy |
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3.2.6.2 Deep Level Transient Spectroscopy |
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3.2.6.3 Photo-Induced Current Transient Spectroscopy (PICTS) |
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3.2.7.1 Synchrotron Radiation |
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3.2.7.3 Synchrotron Radiation Facilities |
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3.2.7.4 Properties of the Beam |
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3.2.7.6 Installing the Detector |
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3.2.7.7 Harmonic Suppression |
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3.2.7.8 Extending the Energy Range |
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3.2.7.9 Detector Characterization |
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3.2.7.10 Probing Depth Dependences |
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3.2.7.11 Defect Metrology |
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3.2.7.12 Pump and Probe Techniques |
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3.2.7.13 X-Ray Absorption Fine Structure (XAFS) Metrology |
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3.2.7.14 Structural Studies |
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3.2.7.15 Topographical and Surface Studies |
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Chapter 4 Contacting Systems |
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207 | (40) |
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4.1 Metal Semiconductor Interfaces |
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4.2.1 Image Force Reduction of the Schottky Barrier |
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4.2.3 Measured Barrier Heights |
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4.2.3.1 Metal-Induced Gap States (MIGS) |
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4.2.3.2 Fermi Level Pinning |
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4.3 Current Transport across a Schottky Barrier |
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4.3.1 Thermionic Emission (TE) |
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4.3.2 Thermionic Assisted Field Emission (TFE) |
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4.3.3 Field Emission (FE) |
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4.3.4 Relative Contributions of TE, TFE, and FE |
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4.3.5 Estimated Contact Resistances for TE, FTE, and FE Current Modes |
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4.3.6 Other Current Components |
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4.3.6.1 Current Due to Image Force Lowering of the Potential Barrier |
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4.3.6.2 Generation-Recombination Effects |
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4.3.6.3 Surface Leakage Current |
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4.4.1 Practical Ohmic Contacts |
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4.4.2 Barrier Height Reduction |
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4.4.2.2 Doping Concentration |
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4.4.3 Barrier Width Reduction |
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4.4.4 Introducing Recombination Centers |
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4.4.5 Desirable Properties of Ohmic Contacts |
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4.4.6 Nonideal Effects in Metal-Semiconductor Junctions |
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4.5 Contactless (Proximity Effect) Readout |
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Chapter 5 Radiation Detection and Measurement |
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247 | (40) |
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5.1 Interaction of Radiation with Matter |
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5.2.1 Energy Loss of Secondary Electrons-Collisional and Bremsstrahlung |
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5.4.1 Photoelectric Effect |
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5.4.2 Coherent Scattering-Thomson and Rayleigh Scattering |
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5.4.3 Incoherent Scattering-Compton Scattering |
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5.5 Attenuation and Absorption of Electromagnetic Radiation |
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5.6 Radiation Detection Using Compound Semiconductors |
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5.6.2 The Solid-State Ionization Chamber |
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5.6.2.1 Spectral Broadening in Radiation Detection Systems |
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Chapter 6 Present Detection Systems |
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287 | (82) |
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6.1 Compound Semiconductors and Radiation Detection |
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6.2 Group IV and IV-IV Materials |
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6.3 Group III-V Materials |
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6.3.6 Narrow-Gap Materials |
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6.3.6.2 Indium Antimonide |
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6.4 Group II-VI Materials |
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6.4.2 Cadmium Zinc Telluride |
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6.4.3 Cadmium Manganese Telluride |
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6.4.5 Cadmium Zinc Selenide |
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6.4.6 Cadmium Telluride Selenide |
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6.5 Group III-VI Materials |
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6.6 Group n-VII Materials |
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6.6.2 Mercuric Bromoiodide |
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6.6.4 Thallium Bromoiodide |
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6.7.1 Thallium Lead Iodide |
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6.7.2 Thallium Chalcohalides |
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6.7.2.1 Thallium Gallium Selenide |
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6.7.2.2 Thallium Iodide Selenide |
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6.8 Other Inorganic Compounds |
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6.11.1 Indirect Neutron Detection |
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6.11.2 Direct Neutron Detection |
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6.11.3 Choice of Compound |
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Chapter 7 Chapter Improving Performance |
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369 | (40) |
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7.1 Single Carrier Collection and Correction Techniques |
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7.1.1 Rise Time Discrimination |
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7.1.2 Bi-Parametric Techniques |
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7.1.4 Hemispherical Detectors |
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7.2 Electrode Design and the Near-Field Effect |
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7.2.1 Frisch Grid /Ring Detectors |
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7.2.2 Small-Pixel Effect Detectors |
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7.2.3 Drift-Strip Detectors |
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7.2.4 Coplanar Grid Detectors |
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7.2.5 Ring-Drift Detectors |
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7.2.6 Other Implementations |
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7.2.7 Combinations of Techniques |
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7.3 Discussion and Conclusions |
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7.4.1 General Requirements on Detector Material |
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Appendix A: Table of Physical Constants |
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409 | (4) |
Appendix B: Units and Conversions |
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413 | (4) |
Appendix C: Periodic Table of the Elements |
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417 | (2) |
Appendix D: Properties of the Elements |
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419 | (8) |
Appendix E: General Properties of Semiconducting Materials |
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427 | (56) |
Appendix F: Table of Radioactive Calibration Sources |
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483 | (28) |
Index |
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511 | |