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E-grāmata: Cyclolinear Organosilicon Copolymers: Synthesis, Properties, Application

  • Formāts: 498 pages
  • Sērija : New Concepts in Polymer Science 17
  • Izdošanas datums: 06-Jan-2023
  • Izdevniecība: VSP International Science Publishers
  • Valoda: eng
  • ISBN-13: 9781466562660
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  • Formāts: 498 pages
  • Sērija : New Concepts in Polymer Science 17
  • Izdošanas datums: 06-Jan-2023
  • Izdevniecība: VSP International Science Publishers
  • Valoda: eng
  • ISBN-13: 9781466562660
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Authors Mukbaniani (I. Javakhishvili Tbilisi State U., Georgia) and Zaikov (N.M. Emanuel Institute of Biochemical Physics, Moscow, Russia) offer a discussion of methods for synthesizing and studying properties of newly designed organosilicon polymers, particularly organosiloxane copolymers with cyclolinear structure of macromolecules. Topics addressed in seven chapters include: linear and cyclic organosiloxanes; organosilicon oligomers and copolymers of bead-shaped structure; copolymers with cyclic fragments in dimethysiloxane backbone; organosilixane copolymers with cyclic fragments in the side chain; organosilicon copolymers with carbocyclosiloxane fragments in dimethylsiloxane backbone; organosilicon copolymers with bi-, tri-, and tetracyclic structures in dimethylsiloxane backbone; and synthesis of organosilicon cyclolinear block-copolymers. There is no subject index. VSP is a subsidiary of Brill Academic Publishers, The Netherlands. Annotation ©2004 Book News, Inc., Portland, OR (booknews.com)

The demand for organosilicon elastomers used in the production of thermally resistant rubbers and organosilicon polymers for making non-metal composite materials is increasing from year to year

The demand for organosilicon elastomers used in the production of thermally resistant rubbers and organosilicon polymers for making non-metal composite materials is increasing from year to year.This monograph presents a discussion on the methods used for synthesizing and studying properties of newly designed organosilicon polymers, namely organosiloxane copolymers with cyclolinear structure of macromolecules.This book presents an overview of data on methods of synthesizing primary linear and cyclic organosiloxanes of various structures.This book will be of value and interest to researchers working in the field of chemistry of organosilicons.
Preface v
Introduction vi
Chapter
1. Linear and cyclic organosiloxanes
1(58)
1. Linear and cyclic organosiloxanes with assigned disposition of functional groups at silicon atoms
1(51)
1.1. Polyfunctional linear organochlorosiloxanes and carbosilanes
1(10)
1.2. Organocyclosiloxanes with given disposition of functional groups at atoms of silicon
11(16)
1.3. Organocyclocarbosiloxanes with functional groups at silicon atoms
27(25)
References
52(7)
Chapter
2. Organosilicon oligomers and copolymers of bead-shaped structure
59(108)
2.1. Bead-shaped organosiloxane oligomers and copolymers with organocyclotetra(penta,hexa)siloxane fragments in the backbone
59(47)
2.2. Bead-shaped methylphenylsiloxane copolymers with ethylene bridges between cycles
106(14)
2.3. Bead-shaped methyl(ethyl)siloxane polymers with ethylene bridges between rings
120(10)
2.4. Oligomers and copolymers with organocyclocarbosiloxane fragments in the chain
130(5)
2.5. Silarylene cyclosiloxane and silarylene carborganocyclosiloxane oligomers and copolymers
135(24)
References
159(8)
Chapter
3. Copolymers with cyclic fragments in dimethysiloxane backbone
167(78)
3.1. Siloxane cyclolinear copolymers with organocyclotetra(penta,hexa)siloxane fragments in dimethylsiloxane backbone
168(45)
3.2. Cyclolinear copolymers with cyclic carbosiloxane fragments in dimethylsiloxane backbone
213(3)
3.3. Organosiloxane copolymers with heterocyclic fragments in the dimethylsiloxane backbone
216(4)
3.4. Poly(organocarbosiloxanes) with cyclic siloxane fragments in the backbone
220(14)
3.5. Cyclolinear copolymers derived by polymerization of organobicyclo- and organotricyclosiloxanes
234(5)
3.5.1. Synthesis of organodi- and organotricyclosiloxanes with labile cyclic fragments
234(3)
3.5.2. Polymerization of cyclolinear organosiloxane copolymers with cyclic fragments in the backbone
237(2)
References
239(6)
Chapter
4. Organosilixane copolymers with cyclic fragments in the side chain
245(48)
4.1. Synthesis of monomeric difunctional organocyclosiloxanes
245(10)
4.2. Synthesis of organosiloxane copolymers with Monocyclic (cyclotri-, cyclotetra-, cyclopentasiloxane) fragments in the side chain
255(23)
4.3. Synthesis of organosiloxane oligomers with cyclic fragments in the side chain by catalytic dehydrocondensation
278(6)
4.4. Synthesis of cyclolinear organosiloxane copolymers by hydrosilylation
284(6)
References
290(3)
Chapter
5. Organosilicon copolymers with carbocyclosiloxane fragments in dimethylsiloxane backbone
293(38)
5.1. Synthesis of organospirobicyclosiloxanes and organospirobicyclosilazasiloxanes
293(7)
5.2. Synthesis of difunctional heterocyclic compounds
300(3)
5.3. Synthesis and study of properties of organosilicon copolymers with cardocyclosiloxane fragments
303(13)
5.4. Organosilicon copolymers with card-type heterocyclic fragments in the linear chain
316(6)
5.5. Synthesis and studies of properties of card-type organosilicon oligomers with silaoxadihydrophenentrene fragments in the chain
322(6)
References
328(3)
Chapter
6. Organosilicon copolymers with bi-, tri- and tetracyclic structures in dimethylsiloxane backbone
331(78)
6.1. Synthesis of organobi-, organotri- and organotetracyclosiloxanes and bicyclocarbosiloxanes with functional groups
331(34)
6.2. Synthesis of difunctional bicyclocarbosiloxanes
365(1)
6.3. Synthesis of organosilicon copolymers with organobi-, organotri- and organotetracyclosiloxane fragments in dimethylsiloxane backbone
366(27)
6.4. Organosilicon copolymers with bicyclocarbosiloxane fragments in the backbone
393(3)
6.5. Carbosiloxane copolymers with tricyclic fragments in the backbone
396(9)
References
405(4)
Chapter
7. Synthesis of organosilicon cyclolinear block-copolymers
409
7.1. Block-copolymers with poly(phenylsilsesquioxane) fragments in the dimethylsiloxane backbone
410(84)
7.1.1. Synthesis of poly(phenylsilsesquioxanes) with functional groups
410(12)
7.1.2. Phenylsilsesquioxane-dimethylsiloxane copolymers.Block copolymers of AmBn type
422(58)
7.1.3. Organosilicon cyclolinear block-copolymers of the (AB)mCn type
480(14)
References
494


O.V. Mukbaniani, G.E. Zaikov