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E-grāmata: Functional Metal-Organic Frameworks: Structure, Properties and Applications

(Tarbiat Modares University, Tehran, Iran), (Tarbiat Modares University, Tehran, Iran)
  • Formāts: EPUB+DRM
  • Izdošanas datums: 18-Nov-2020
  • Izdevniecība: Wiley-Scrivener
  • Valoda: eng
  • ISBN-13: 9781119641032
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Functional Metal-Organic Frameworks: Structure, Properties and ApplicationsPalielināt
  • Formāts: EPUB+DRM
  • Izdošanas datums: 18-Nov-2020
  • Izdevniecība: Wiley-Scrivener
  • Valoda: eng
  • ISBN-13: 9781119641032
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Owing to the extensive interest in construction of functional metal organic frameworks (FMOFs), this book discusses the roles of functional groups on the structure and application of metal organic frameworks (MOFs). The contents of the book are classified based on the structural and chemical properties of organic functions, in order to make readers able to compare the different effects of each function on the structure and application of the MOFs.

 

In each chapter, the chemical properties of applied functional groups are gathered to give deeper insight into the roles of organic functions in the structure and application of MOFs. In the function-application properties, the authors discuss how a functional group can dominate the host-guest chemistry of the MOFs and how this host-guest chemistry can expand the effectiveness and efficiency of the material in different fields of applications. Finally, function-structure properties are discussed. In function-application properties, it is discussed how a functional group can affect the topology, porosity, flexibility and stability of the framework. The features of this subject are novel and are presented for the first time.

Preface ix
1 Introduction to Functional Metal-Organic Frameworks 1(14)
1.1 Coordination Polymers
1(3)
1.2 Metal-Organic Frameworks
4(2)
1.3 Functional Metal-Organic Frameworks
6(5)
References
11(4)
2 Amine Decorated Metal-Organic Frameworks 15(22)
2.1 General Chemical Properties of Amine Function
15(1)
2.2 Function-Application Properties
16(14)
2.3 Function-Structure Properties
30(1)
References
31(6)
3 Azo and Azine Decorated Metal-Organic Frameworks 37(18)
3.1 General Chemical Properties of Azine and Azo Functions
37(1)
3.2 Function-Application Properties
37(10)
3.3 Function-Structure Properties
47(3)
References
50(5)
4 Imidazolium and Pyridinium Decorated Metal-Organic Frameworks 55(24)
4.1 Imidazolium Functionalized Metal-Organic Frameworks
55(9)
4.1.1 General Chemical Properties of Imidazolium Function
55(1)
4.1.2 Function-Application Properties
56(7)
4.1.3 Function-Structure Properties
63(1)
4.2 Pyridinium Functionalized Metal-Organic Frameworks
64(8)
4.2.1 General Chemical Properties of Pyridinium Function
64(1)
4.2.2 Function-Application Properties
65(6)
4.2.3 Function-Structure Properties
71(1)
References
72(7)
5 Heterocyclic Azine Decorated Metal-Organic Frameworks 79(28)
5.1 General Chemical Properties of Heterocyclic Azine Functions
79(2)
5.2 Function-Application Properties
81(14)
5.3 Function-Structure Properties
95(5)
References
100(7)
6 Heterocyclic Azole Decorated Metal-Organic Frameworks 107(26)
6.1 General Chemical Properties of Heterocyclic Azole Functions
107(1)
6.2 Function-Application Properties
108(10)
6.3 Function-Structure Properties
118(7)
References
125(8)
7 Functional Metal-Organic Frameworks by Oxygen and Sulfur Based Functions 133(32)
7.1 Functionalized Metal-Organic Frameworks by Oxygen Based Functions
133(9)
7.1.1 Function-Application Properties
133(7)
7.1.2 Function-Structure Properties
140(2)
7.2 Functionalized Metal-Organic Frameworks by Sulfur Based Functions
142(14)
7.2.1 Functionalized Metal-Organic Frameworks by Thiol and Sulfide Functions
142(7)
7.2.2 Functionalized Metal-Organic Frameworks by Sulfonate-Sulfonic Acid Function
149(6)
7.2.3 Functionalized Metal-Organic Frameworks by Other S-Based Functions
155(1)
References
156(9)
8 Urea and Amide Decorated Metal-Organic Frameworks 165(36)
8.1 Functionalized Metal-Organic Frameworks by Amide Function
166(14)
8.1.1 General Chemical Properties of Amide Function
166(1)
8.1.2 Function-Application Properties
166(12)
8.1.3 Function-Structure Properties
178(2)
8.2 Functionalized Metal-Organic Frameworks by Urea Function
180(9)
8.2.1 General Chemical Properties of Urea Function
180(2)
8.2.2 Function-Application Properties
182(4)
8.2.3 Structure-Function Properties
186(3)
8.3 Functionalized Metal-Organic Frameworks by Squaramide Function
189(3)
References
192(9)
9 Carbonyl, Carboxy and Imide Functionalized Metal-Organic Frameworks 201(30)
9.1 Functionalized Metal-Organic Frameworks by Carbonyl Function
201(6)
9.1.1 General Chemical Properties of Carbonyl Functional Group
201(1)
9.1.2 Function-Application Properties
202(4)
9.1.3 Function-Structure Properties
206(1)
9.2 Functionalized Metal-Organic Frameworks by Carboxy Function
207(9)
9.2.1 General Chemical Properties of Carboxy Function
207(1)
9.2.2 Synthesis of Functionalized Metal-Organic Frameworks with Free Carboxy Function
208(1)
9.2.3 Function-Application Properties
209(4)
9.2.4 Function-Structure Properties
213(3)
9.3 Functionalized Metal-Organic Frameworks by Imide Function
216(8)
9.3.1 General Chemical Properties of Imide Function
216(2)
9.3.2 Function-Application Properties
218(6)
References
224(7)
10 Fluorine and Phosphonate Functional Metal-Organic Frameworks 231(8)
10.1 Functionalized Metal-Organic Frameworks by Phosphonic Acid/Phosphonate Functions
231(2)
10.2 Functionalized Metal-Organic Frameworks by Fluorine Function
233(1)
References
234(5)
Index 239
Audience

This book is interesting to a diverse group of scientists, including chemists, materials scientists, chemical engineers and any scientist who is working on supramolecular chemistry of MOFs and designing functional materials.

Ali Morsali is Master in Inorganic Chemistry in Tarbiat Modares University, Tehran, Iran. He obtained his PhD in 2003 in Inorganic Chemistry from the same university. He has published more than 400 articles in international journals as well as 5 patents. He has received numerous national awards. Amongst his research interests are coordination chemistry and metal-organic frameworks. He is the co-author of Main Group Metal Coordination Polymers and Pillared Metal-Organic Frameworks (Wiley-Scrivener 2017, 2019 respectively).



Sayed Ali Akbar Razavi received his BSc in pure chemistry in 2014 from Sharif University of Technology and his MSc in inorganic chemistry in 2017 from Tarbiat Modares University, Tehran, Iran. Currently, he is a PhD student under supervision of Prof. Ali Morsali. His research interest focuses on functional metal–organic frameworks.
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