Preface |
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vii | |
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1 Physics, Chemistry and Surface Properties |
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1 | (34) |
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1 | (1) |
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1.2 The Electrochemical Interface |
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2 | (7) |
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1.2.1 Conductivity and Electrical Field: Metal Versus Electrolyte |
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3 | (3) |
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1.2.2 Magnitude of Double Layer Capacitance |
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6 | (3) |
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1.3 Energy in Solids and Liquids: Junction Formation |
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9 | (5) |
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1.4 Surface Reactivity of Low-Index Planes |
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14 | (4) |
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1.5 Electron Charge-Transfer Reactions |
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18 | (8) |
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1.5.1 Hydrogen Electrode vs. Oxygen Electrode |
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21 | (1) |
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1.5.2 Organic-Fuels vs. Oxygen Electrode |
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22 | (4) |
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1.6 The Effect of CN-Surface Coordination on Low-Index Pt Surface: ORR |
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26 | (3) |
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29 | (6) |
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2 Computational Chemistry for Electro-Catalysis |
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35 | (40) |
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35 | (4) |
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2.2 Scope and Limitations of Different Models |
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39 | (25) |
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40 | (9) |
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49 | (10) |
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59 | (5) |
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2.3 Influence of the Support in Electrocatalysis |
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64 | (5) |
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69 | (6) |
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3 The Hydrogen Electrode Reaction |
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75 | (68) |
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75 | (2) |
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77 | (1) |
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3.3 Hydrogen Evolution Reaction-HER |
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78 | (22) |
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3.3.1 HER on Platinum Catalytic Center |
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85 | (5) |
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3.3.2 HER on Non-Noble Metal Catalyst Centers |
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90 | (10) |
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3.4 Hydrogen Oxidation Reaction-HOR |
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100 | (24) |
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3.4.1 HOR on Precious Metal Centers |
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108 | (11) |
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3.4.2 HOR on Non-Precious Metal Centers |
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119 | (5) |
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124 | (19) |
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4 Oxygen Reduction/Evolution Reaction |
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143 | (44) |
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143 | (3) |
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4.2 Electrolyzer Thermodynamics |
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146 | (2) |
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4.3 Oxygen Reduction Reaction |
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148 | (25) |
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4.3.1 ORR Pt-Based Nano-Structure Materials |
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157 | (2) |
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159 | (12) |
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4.3.3 ORR on Au and Pd-Based Nano-Structure Materials |
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171 | (2) |
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4.4 Oxygen Evolution Reaction |
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173 | (5) |
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178 | (9) |
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5 Electrochemical Energy Storage |
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187 | (38) |
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187 | (1) |
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5.2 Basic Terminology in Batteries |
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188 | (7) |
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5.3 Present Status of Electrochemical Batteries |
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195 | (4) |
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196 | (1) |
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5.3.2 Nickel-Cadmium Battery |
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197 | (1) |
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5.3.3 Nickel-Metal Hydride Battery |
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198 | (1) |
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199 | (11) |
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5.4.1 Insertion Electrode Materials |
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202 | (7) |
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5.4.2 Conversion Reaction Electrodes |
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209 | (1) |
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210 | (1) |
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210 | (10) |
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210 | (2) |
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5.5.2 Lithium-Sulfur Batteries |
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212 | (3) |
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5.5.3 Metal Air Batteries |
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215 | (1) |
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5.5.3.1 Aqueous Metal Air Batteries |
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216 | (2) |
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5.5.3.2 Non-Aqueous Metal Air Batteries |
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218 | (2) |
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220 | (5) |
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6 Electrocatalysis and Remediation |
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225 | (52) |
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225 | (3) |
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228 | (12) |
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6.3 COx Reduction and Methanol Oxidation |
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240 | (17) |
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246 | (3) |
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249 | (5) |
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6.3.3 Oxidation of Emergent Pollutants |
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254 | (3) |
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6.4 Determination of Nitrate-Based Compounds in DNA |
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257 | (5) |
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262 | (15) |
Subject Index |
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277 | |