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E-grāmata: Fundamentals of Electrocatalyst Materials and Interfacial Characterization: Energy Producing Devices and Environmental Protection

  • Formāts: EPUB+DRM
  • Izdošanas datums: 28-Feb-2019
  • Izdevniecība: Wiley-Scrivener
  • Valoda: eng
  • ISBN-13: 9781119460541
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  • Formāts: EPUB+DRM
  • Izdošanas datums: 28-Feb-2019
  • Izdevniecība: Wiley-Scrivener
  • Valoda: eng
  • ISBN-13: 9781119460541
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This book addresses some essential topics in the science of energy converting devices emphasizing recent aspects of nano-derived materials in the application for the protection of the environment, storage, and energy conversion.  The aim, therefore, is to provide the basic background knowledge. The electron transfer process and structure of the electric double layer and the interaction of species with surfaces and the interaction, reinforced by DFT theory for the current and incoming generation of fuel cell scientists to study the interaction of the catalytic centers with their supports. The chief focus of the chapters is on materials based on precious and non-precious centers for the hydrogen electrode, the oxygen electrode, energy storage, and in remediation applications, where the common issue is the rate-determining step in multi-electron charge transfer processes in electrocatalysis. These approaches are used in a large extent in science and technology, so that each chapter demonstrates the connection of electrochemistry, in addition to chemistry, with different areas, namely, surface science, biochemistry, chemical engineering, and chemical physics.

Preface vii
1 Physics, Chemistry and Surface Properties
1(34)
1.1 Introduction
1(1)
1.2 The Electrochemical Interface
2(7)
1.2.1 Conductivity and Electrical Field: Metal Versus Electrolyte
3(3)
1.2.2 Magnitude of Double Layer Capacitance
6(3)
1.3 Energy in Solids and Liquids: Junction Formation
9(5)
1.4 Surface Reactivity of Low-Index Planes
14(4)
1.5 Electron Charge-Transfer Reactions
18(8)
1.5.1 Hydrogen Electrode vs. Oxygen Electrode
21(1)
1.5.2 Organic-Fuels vs. Oxygen Electrode
22(4)
1.6 The Effect of CN-Surface Coordination on Low-Index Pt Surface: ORR
26(3)
References
29(6)
2 Computational Chemistry for Electro-Catalysis
35(40)
2.1 Introduction
35(4)
2.2 Scope and Limitations of Different Models
39(25)
2.2.1 Clusters
40(9)
2.2.2 Slabs
49(10)
2.2.3 Nanoparticles
59(5)
2.3 Influence of the Support in Electrocatalysis
64(5)
References
69(6)
3 The Hydrogen Electrode Reaction
75(68)
3.1 Introduction
75(2)
3.2 Thermodynamics
77(1)
3.3 Hydrogen Evolution Reaction-HER
78(22)
3.3.1 HER on Platinum Catalytic Center
85(5)
3.3.2 HER on Non-Noble Metal Catalyst Centers
90(10)
3.4 Hydrogen Oxidation Reaction-HOR
100(24)
3.4.1 HOR on Precious Metal Centers
108(11)
3.4.2 HOR on Non-Precious Metal Centers
119(5)
References
124(19)
4 Oxygen Reduction/Evolution Reaction
143(44)
4.1 Introduction
143(3)
4.2 Electrolyzer Thermodynamics
146(2)
4.3 Oxygen Reduction Reaction
148(25)
4.3.1 ORR Pt-Based Nano-Structure Materials
157(2)
4.3.2 Reaction Pathways
159(12)
4.3.3 ORR on Au and Pd-Based Nano-Structure Materials
171(2)
4.4 Oxygen Evolution Reaction
173(5)
References
178(9)
5 Electrochemical Energy Storage
187(38)
5.1 Introduction
187(1)
5.2 Basic Terminology in Batteries
188(7)
5.3 Present Status of Electrochemical Batteries
195(4)
5.3.1 Lead Acid Battery
196(1)
5.3.2 Nickel-Cadmium Battery
197(1)
5.3.3 Nickel-Metal Hydride Battery
198(1)
5.4 Lithium Ion Battery
199(11)
5.4.1 Insertion Electrode Materials
202(7)
5.4.2 Conversion Reaction Electrodes
209(1)
5.4.3 Alloy Electrodes
210(1)
5.5 Post-Li Technologies
210(10)
5.5.1 Na-Ion Batteries
210(2)
5.5.2 Lithium-Sulfur Batteries
212(3)
5.5.3 Metal Air Batteries
215(1)
5.5.3.1 Aqueous Metal Air Batteries
216(2)
5.5.3.2 Non-Aqueous Metal Air Batteries
218(2)
References
220(5)
6 Electrocatalysis and Remediation
225(52)
6.1 Introduction
225(3)
6.2 NOx Reduction
228(12)
6.3 COx Reduction and Methanol Oxidation
240(17)
6.3.1 Methanol Oxidation
246(3)
6.3.2 SO Reduction
249(5)
6.3.3 Oxidation of Emergent Pollutants
254(3)
6.4 Determination of Nitrate-Based Compounds in DNA
257(5)
References
262(15)
Subject Index 277
Nicolas Alonso-Vante is full professor of chemistry, doing research at the IC2MP laboratory at the University of Poitiers. He holds a Docteur Troisičme Cycle, in electrochemistry, and a Doctorat d'Etat in Physical Science from the University of Strasbourg, France. He is the author of over 220 publications, the editor of a two-volume e-book on electrochemistry in Spanish, and holds 6 patents.

Carlos Augusto Campos-Roldįn received his Master degree in 2016 under a collaboration between ESIQIE-IPN, Mexico, and the University of Poitiers, France.

Rosa de Guadalupe Gonzįlez Huerta PhD is a professor at at ESIQIE-IPN, Mexico City. She has co-authored 36 publications, 3 patents and 2 registered trademarks.

Guadalupe Ramos Sįnchez is a research fellow at the Chemistry Department of the Universidad Autónoma Metropolitana, Iztapalapa in Mexico City. He has coauthored 37 publications.

Arturo Manzo Robledo is a full professor at ESIQIE-IPN, Mexico City, Mexico. He has authored 35 articles.