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1 | (20) |
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1.1 What is Environmental Engineering? |
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1 | (3) |
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1.2 The Environmental Engineering Process -- Modeling |
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4 | (3) |
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1.3 Example Activities of Environmental Engineers |
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7 | (3) |
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1.4 History of Environmental Pollution and Its Control |
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10 | (8) |
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10 | (1) |
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1.4.2 Air Pollution Episodes |
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11 | (2) |
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1.4.3 Water Pollution Regulation in the U.S. |
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13 | (1) |
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1.4.4 Air Pollution Regulation in the U.S. |
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14 | (1) |
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15 | (3) |
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18 | (1) |
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19 | (2) |
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Chapter 2 Environmental Hazards and Their Management |
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21 | (68) |
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21 | (1) |
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21 | (14) |
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2.2.1 Population Growth and Standard of Living |
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21 | (1) |
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22 | (3) |
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2.2.1.2 Standard of Living |
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25 | (1) |
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2.2.2 Loss of Biological Diversity |
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26 | (1) |
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27 | (4) |
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2.2.4 Stratospheric Ozone Depletion |
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31 | (4) |
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35 | (13) |
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35 | (2) |
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37 | (1) |
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38 | (4) |
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42 | (1) |
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43 | (1) |
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2.3.6 Photochemical Oxidants |
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44 | (1) |
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45 | (3) |
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2.4 Water Pollutants and Their Effects |
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48 | (10) |
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48 | (1) |
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49 | (3) |
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2.4.3 Suspended and Floating Solids |
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52 | (1) |
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2.4.4 Priority Pollutants |
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53 | (1) |
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53 | (1) |
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2.4.4.2 Polychlorinated Biphenyls |
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54 | (1) |
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2.4.4.3 Metals and Inorganics |
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55 | (1) |
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2.4.4.4 Halogenated Aliphatics |
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55 | (1) |
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56 | (1) |
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56 | (1) |
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56 | (1) |
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2.4.4.8 Monocyclic Aromatics |
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57 | (1) |
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2.4.4.9 Polycyclic Aromatics |
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57 | (1) |
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57 | (1) |
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2.4.5 Inorganic Pollutants |
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58 | (1) |
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58 | (1) |
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2.5 Management of Environmental Hazards |
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58 | (23) |
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58 | (1) |
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2.5.2 Environmental Assessment Criteria |
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59 | (1) |
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2.5.2.1 Source Performance Standards |
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60 | (1) |
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2.5.2.2 Environmental Quality Standards |
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60 | (4) |
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2.5.2.3 Risk-Based Standards |
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64 | (1) |
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2.5.2.4 Cost-Benefit Analysis |
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64 | (3) |
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2.5.2.5 Community-Based Standards |
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67 | (1) |
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2.5.3 Assessment of Environmental Effects |
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68 | (2) |
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2.5.3.1 Exposure Assessment |
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70 | (4) |
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2.5.3.2 Human Health Risk Assessment |
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74 | (7) |
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2.6 Management of Pollutant Releases |
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81 | (4) |
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2.6.1 Pollution Prevention |
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81 | (1) |
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2.6.1.1 Lifestyle Analysis |
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82 | (1) |
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2.6.1.2 Operation for Pollution Prevention |
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83 | (1) |
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2.6.2 Recycling of Waste Materials |
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84 | (1) |
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2.6.3 Destruction, Treatment, or Storage of Wastes |
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84 | (1) |
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85 | (1) |
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86 | (3) |
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Chapter 3 Introduction to Environmental Engineering Calculations |
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89 | (42) |
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89 | (3) |
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3.2 Units and Nomenclature for Basic Environmental Variables |
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92 | (13) |
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3.2.1 Density and Concentration |
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92 | (6) |
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3.2.2 Reaction Stoichiometry |
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98 | (2) |
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100 | (1) |
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101 | (4) |
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105 | (4) |
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109 | (17) |
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3.4.1 Mean and Standard Deviation |
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109 | (3) |
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3.4.2 Probability Distributions |
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112 | (1) |
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3.4.2.1 Gaussian Distribution |
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112 | (3) |
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3.4.2.2 Log-Normal Distribution |
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115 | (1) |
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3.4.3 Propagation of Error |
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116 | (3) |
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119 | (2) |
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3.4.4.1 Linearization and Errors |
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121 | (3) |
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3.4.4.2 General Linear Regression |
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124 | (2) |
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126 | (3) |
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129 | (2) |
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Chapter 4 Physical and Chemical Equilibrium |
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131 | (82) |
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131 | (11) |
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131 | (2) |
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133 | (5) |
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138 | (2) |
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4.1.4 General Phase Behavior |
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140 | (2) |
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4.2 Thermodynamics of Phase Changes |
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142 | (8) |
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4.2.1 Sensible Heat Transitions |
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143 | (6) |
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4.2.2 Latent Heat Transitions |
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149 | (1) |
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4.3 Thermodynamics of Equilibrium |
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150 | (9) |
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4.3.1 First and Second Laws of Thermodynamics |
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151 | (3) |
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4.3.2 Gibb's Free Energy and Equilibrium |
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154 | (5) |
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159 | (3) |
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162 | (4) |
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4.6 Fluid-Fluid Partitioning |
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166 | (9) |
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167 | (2) |
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169 | (5) |
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174 | (1) |
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4.7 Fluid-Solid Partitioning |
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175 | (10) |
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4.7.1 Linear Partitioning |
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177 | (4) |
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181 | (1) |
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4.7.3 Brauner-Emmett-Teller (BET) Isotherm |
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182 | (2) |
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4.7.4 Freundlich Isotherm |
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184 | (1) |
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185 | (7) |
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190 | (2) |
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192 | (7) |
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4.10 Acid Dissociation Constant |
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199 | (4) |
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4.11 Mineral Dissolution Reactions |
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203 | (1) |
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4.12 Ion Exchange and Adsorption |
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204 | (3) |
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4.13 Oxidation-Reduction Reactions |
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207 | (2) |
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209 | (1) |
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209 | (2) |
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211 | (2) |
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213 | (68) |
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213 | (3) |
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216 | (15) |
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216 | (4) |
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5.2.2 Steady-State Material Balance |
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220 | (5) |
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5.2.3 Dynamic Balance on a Stirred System |
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225 | (4) |
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5.2.4 Balance on an Unstirred System |
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229 | (2) |
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5.3 Fate Processes -- Sorption and Reaction |
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231 | (9) |
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5.3.1 Irreversible Reactions -- Kinetic Models |
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231 | (3) |
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5.3.2 Estimation of Reaction Rate Parameters |
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234 | (2) |
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5.3.3 Reversible Reactions |
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236 | (1) |
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5.3.4 Reversible Processes and System Dynamics |
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237 | (3) |
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240 | (15) |
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240 | (1) |
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5.4.2 Diffusion -- Fick's First Law |
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241 | (4) |
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5.4.3 Film Theory of Mass Transfer |
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245 | (2) |
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247 | (6) |
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253 | (1) |
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5.4.6 Diffusion of Momentum |
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254 | (1) |
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255 | (1) |
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255 | (12) |
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5.5.1 Turbulent Fluctuations |
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255 | (5) |
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5.5.2 Mixing Length Theory |
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260 | (1) |
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5.5.3 The Logarithmic Velocity Profile Law |
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261 | (2) |
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5.5.4 Heat, Mass, and Momentum Transfer Analogies |
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263 | (1) |
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5.5.5 The Effect of Stratification on Turbulent Transport |
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264 | (3) |
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5.6 Microscopic Mass, Energy, and Momentum Balances |
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267 | (9) |
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5.6.1 Development of Microscopic Balances |
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267 | (3) |
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5.6.2 Error Function Solution to the Microscopic Material Balance |
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270 | (2) |
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5.6.3 Solutions to the Advection-Diffusion Equation |
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272 | (4) |
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276 | (3) |
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279 | (2) |
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Chapter 6 Air Pollution and Its Control |
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281 | (90) |
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281 | (1) |
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6.2 Atmospheric Processes |
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281 | (25) |
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6.2.1 Global Atmospheric Structure and Mixing |
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281 | (5) |
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286 | (4) |
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290 | (2) |
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292 | (1) |
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292 | (2) |
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294 | (1) |
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6.2.4 Observed Structure and Mixing in the Atmospheric Boundary Layer |
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295 | (1) |
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6.2.4.1 Boundary Layer Temperature Structure |
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295 | (8) |
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6.2.4.2 Boundary Layer Velocity Profile |
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303 | (1) |
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6.2.4.3 Empirical Turbulence Classification Schemes |
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304 | (2) |
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6.3 Pollutant Transport and Dispersion in the Boundary Layer |
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306 | (21) |
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6.3.1 Well-Mixed Box Model for Area Sources |
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310 | (2) |
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6.3.2 Point Source Dispersion Model |
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312 | (1) |
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313 | (3) |
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6.3.2.2 Point Source Dispersion |
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316 | (3) |
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6.3.2.3 Parameter Estimation |
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319 | (8) |
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6.4 Particulate Control Processes |
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327 | (23) |
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327 | (5) |
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6.4.2 Particle Settling in the Atmosphere |
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332 | (1) |
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333 | (1) |
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6.4.3.1 Unmixed Collector |
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334 | (1) |
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6.4.3.2 Plug Flow Collector |
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335 | (1) |
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6.4.3.3 Completely Mixed Settler |
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336 | (1) |
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337 | (3) |
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6.4.5 Electrostatic Precipitator |
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340 | (4) |
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344 | (5) |
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349 | (1) |
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6.5 Gaseous Control Processes |
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350 | (15) |
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6.5.1 Process Changes to Control Gaseous Emissions |
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350 | (2) |
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352 | (1) |
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352 | (1) |
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6.5.2.2 Catalytic Reaction Systems |
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353 | (1) |
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6.5.3 Sorption Processes -- Adsorption |
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353 | (6) |
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6.5.4 Sorption Processes -- Absorption |
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359 | (6) |
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365 | (1) |
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365 | (4) |
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369 | (2) |
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Chapter 7 Water Pollution and Its Control |
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371 | (72) |
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371 | (1) |
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7.2 Surface Water Processes |
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371 | (11) |
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7.2.1 Ocean and Lake Circulations |
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371 | (2) |
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373 | (3) |
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7.2.3 Surface Water Runoff |
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376 | (2) |
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7.2.4 Stratification and Stability in Temperate, Shallow Freshwater Systems |
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378 | (2) |
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7.2.5 Other Effects on Stability of Surface Waters |
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380 | (2) |
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7.3 Contaminant Processes in Surface Waters |
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382 | (17) |
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7.3.1 Phase Partitioning in Surface Waters |
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383 | (3) |
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7.3.2 Turbulent Mixing and Transport in Streams, Lakes, and Oceans |
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386 | (1) |
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7.3.2.1 Transport Across the Air-Water Interface |
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387 | (2) |
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7.3.2.2 Transport Near the Sediment--Water Interface |
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389 | (2) |
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7.3.2.3 Mixing in Lakes and Oceans |
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391 | (2) |
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7.3.3 Chemical and Biological Degradation Processes in Surface Waters |
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393 | (3) |
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7.3.4 Kinetics of Biological Degradation Processes |
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396 | (3) |
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7.4 Modeling Contaminant Dynamics in Surface Waters |
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399 | (6) |
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399 | (1) |
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399 | (4) |
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403 | (2) |
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405 | (13) |
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7.5.1 Summary of Processes |
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405 | (1) |
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406 | (3) |
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409 | (3) |
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412 | (2) |
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7.5.5 Contaminant Transport by Sediment Relocation |
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414 | (1) |
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7.5.6 Contaminant Transport by Porewater Processes |
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414 | (4) |
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7.6 Primary Water Treatment |
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418 | (6) |
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7.6.1 Fundamentals of Sedimentation |
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418 | (3) |
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421 | (1) |
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422 | (2) |
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7.7 Secondary Wastewater Treatment |
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424 | (7) |
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425 | (1) |
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7.7.2 Activated Sludge System |
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426 | (5) |
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7.8 Tertiary Wastewater Treatment |
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431 | (8) |
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431 | (1) |
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431 | (1) |
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431 | (3) |
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434 | (1) |
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435 | (4) |
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439 | (1) |
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439 | (3) |
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442 | (1) |
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Chapter 8 Soil Pollution and Its Control |
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443 | (56) |
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443 | (1) |
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443 | (19) |
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8.2.1 Solid Phase Characteristics |
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444 | (3) |
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8.2.2 Flow of Fluid in Fully Saturated Media |
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447 | (10) |
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8.2.3 Flow of Fluid in a Partially Saturated Media |
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457 | (5) |
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8.3 Contaminant Transport in Soils |
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462 | (20) |
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8.3.1 First Zone of Contamination -- NAPL Residual in the Vadose Zone |
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464 | (4) |
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8.3.2 Second Zone of Contamination -- Contaminant Vapors in Vadose Zone |
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468 | (3) |
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8.3.3 Third Zone of Contamination -- NAPL Residual in Initially Water-Saturated Zone |
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471 | (2) |
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8.3.4 Fourth Zone of Contamination -- Dissolved Contaminant in Subsurface Water |
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473 | (7) |
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8.3.5 Natural Attenuation of Contaminants in Soils |
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480 | (2) |
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8.4 Remediation of Contaminated Soils |
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482 | (1) |
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8.5 Removal Options for Soil Remediation |
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482 | (3) |
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482 | (1) |
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483 | (1) |
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8.5.3 Stabilization/Solidification |
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484 | (1) |
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8.5.4 Ex Situ Bioremediation |
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485 | (1) |
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8.6 In Situ Soil Remediation Processes |
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485 | (9) |
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8.6.1 Pump and Treat Extraction of Contaminated Groundwater |
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486 | (3) |
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8.6.2 Enhancement of Pump and Treat Processes |
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489 | (1) |
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8.6.3 Vacuum Extraction in the Unsaturated Zone |
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489 | (4) |
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8.6.4 In Situ Bioremediation of Soils |
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493 | (1) |
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494 | (1) |
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495 | (2) |
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497 | (2) |
Appendix |
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499 | (8) |
Index |
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507 | |