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E-grāmata: Green Chemistry for Sustainable Water Purification [Wiley Online]

  • Formāts: 304 pages
  • Izdošanas datums: 05-Apr-2023
  • Izdevniecība: Wiley-Scrivener
  • ISBN-10: 1119852323
  • ISBN-13: 9781119852322
  • Wiley Online
  • Cena: 198,60 €*
  • * this price gives unlimited concurrent access for unlimited time
  • Formāts: 304 pages
  • Izdošanas datums: 05-Apr-2023
  • Izdevniecība: Wiley-Scrivener
  • ISBN-10: 1119852323
  • ISBN-13: 9781119852322
GREEN CHEMISTRY for Sustainable Water Purification Green Chemistry for Sustainable Water Purification provides systematic coverage of the most recent research and development in clean water treatment technologies based on green materials and nanocomposites.

Providing safe drinking water is one of the top priorities for scientists and industrialists working on projects, and one particular problem is the contamination of groundwater with toxic organic and inorganic compounds released by various industries. The presence of contaminants or industrial effluents in drinking water systems has increasingly become a major environmental challenge. To address the problem, several methods, including ion exchange, membrane filtration, advanced oxidation, biological degradation, photocatalytic degradation, electro-coagulation, and adsorption, are in operation for removing or minimizing these wastes. The purification process of wastewater using conventional methods, however, has proved to be markedly ineffective, very difficult, and highly expensive.

On the other hand, for the remediation of water resources, a concept like green chemistry, based on the application of biological agents including polymers, bacteria, and fungi, has received great scientific attention as it helps to avoid the toxic by-products of conventional techniques and enhances eco-friendly wastewater treatment approaches.

This book discusses the different treatment technologies with a special focus on the green adsorption approach, using biological and hybrid biochemical treatment technologies to prevent water contamination and maintain the ecosystem. It discusses the analysis of organic and inorganic pollutants from industrial wastewater. It also focuses on the removal and recovery of organic and inorganic contaminants from the environment and several case studies describing the removal and recovery of environmental pollutants using green technology are given. The recycling of low-cost along with green adsorbent technology is explained in detail. Finally, the book highlights treatment technologies with effective pollutant removal capacities that are used in modern water treatment units.

Audience

The book will serve as an important resource for materials scientists, chemists, chemical engineers, biotechnologists, textile engineers and environmental scientists. It will also be valuable to industrial organizations, consulting engineering companies, etc. for the selection and implementation of the most sustainable wastewater treatment technologies.
Preface xiii
1 Green Chemistry for Water Remediation
1(20)
Syed Wazed Ali
Satyaranjan Bairagi
Swagata Barterjee
1.1 Introduction
2(1)
1.2 Challenges in Water Remediation
3(1)
1.3 Green Chemistry as a Novel Alternative to Conventional Wastewater Treatment
4(10)
1.3.1 Green Chemistry
4(5)
1.3.2 Applications of Green Chemistry in Water Remediation
9(5)
1.4 Conclusion
14(7)
Acknowledgment
15(1)
References
15(6)
2 Advances in Wastewater Treatment Using Natural and Modified Zeolites
21(28)
Sheikh A. Majid
Gowher Jan
Aabid H. Shalla
2.1 Global Impact of Wastewater Treatment
21(1)
2.2 Different Wastewater Treatments
22(1)
2.3 Technologies to Treat Chemical Industry Effluents
23(1)
2.4 Oil-Water Separator--Treatment of Oily Effluent
23(1)
2.5 Coagulation-Flocculation
24(1)
2.6 Techniques for Treating Wastewater Using Adsorption
25(1)
2.7 Adsorption of Dyes
26(1)
2.8 Zeolite in Wastewater Treatment
27(1)
2.9 Negative Impact of Heavy Metals on Health
28(4)
2.9.1 Origin of Heavy Metal Exposure to Humans
29(1)
2.9.1.1 Arsenic
30(1)
2.9.1.2 Lead
31(1)
2.9.1.3 Mercury
31(1)
2.10 Wastewater Treatment Using Different Zeolites
32(1)
2.10.1 Natural Zeolites
32(1)
2.11 Treatment of Surface Waters, Ground, and Underground Waters
33(1)
2.12 Drinking and Greywater Treatment
33(1)
2.13 Heavy Metal Removal Comparison by Zeolites
34(6)
2.13.1 Different Adsorbents Used to Remove Cr3+
34(1)
2.13.2 Different Adsorbents Employed for the Removal of Cd3+
34(3)
2.13.3 Removal of Cu2+by Different Adsorbents
37(1)
2.13.4 Different Adsorbents Used to Remove Pb2+
37(1)
2.13.5 Removal of Zn2+ by Different Adsorbents
37(3)
2.14 Adsorption Kinetics and Thermodynamics
40(1)
2.15 Conclusion
40(9)
References
41(8)
3 Sustainable Green Synergistic Emulsion Liquid Membrane Formulation for Metal Removal from Aqueous Waste Solution
49(30)
Norasikin Othman
Norela Jusoh
Raja Norimie Raja Sulaiman
Norul Fatiha Mohamed Noah
3.1 Introduction
50(1)
3.2 Theoretical
51(7)
3.2.1 Mass Transfer Mechanism in the ELM Process
53(2)
3.2.2 Component Selection in the ELM
55(3)
3.3 Experimental
58(2)
3.3.1 Materials
58(1)
3.3.2 Reactive Extraction Procedure
58(2)
3.3.3 Determination and Calculations
60(1)
3.4 Results and Discussion
60(13)
3.4.1 Extraction of Metal Ions Using Single Carrier
60(1)
3.4.2 Extraction of Metal Ions Using Mixed of Carriers
61(7)
3.4.3 Approach to a Sustainable ELM Process
68(1)
3.4.4 Prospect and Future Challenges in ELM Technology
69(4)
3.5 Conclusion
73(6)
Acknowledgment
73(1)
References
73(6)
4 Chemical Activation of Carbonized Neem Seed as an Effective Adsorbent for Rhodamine B Dye Adsorption
79(28)
Edwin Andrew Ofudje
Samson O. Alayande
Abimbola A. Ogundiran
Ezekiel Folorunso Sodiya
Oyesolape Basirat Akinsipo-Oyelaja
Godswill Akhigbe
Olugbenga Bowale Oladeji
4.1 Introduction
80(1)
4.2 Materials and Methods
81(2)
4.2.1 Chemicals
81(1)
4.2.2 Preparation of Adsorbent
81(1)
4.2.3 Magnetic Activation Carbonized Neem Seed
82(1)
4.2.4 Adsorbent Characterizations
82(1)
4.2.5 Batch Adsorption Experiments
83(1)
4.3 Results and Discussion
83(19)
4.3.1 Adsorption Studies
87(3)
4.3.2 Adsorption Kinetics of RB Dye Removal
90(5)
4.3.3 Adsorption Isotherms of RB Dye Removal
95(2)
4.3.4 Thermodynamic of RB Dye Removal
97(5)
4.4 Conclusions
102(5)
References
102(5)
5 Green Water Treatment for Organic Pollutions: Photocatalytic Degradation Approach
107(22)
Yahiya Kadaf Manea
Amjad Mumtaz Khan
Ajaz Ahmad Wani
Adel A. M. Saeed
Shaif M. Kasim
Ashrf Mashrai
5.1 Introduction
108(1)
5.2 Solar Energy
109(1)
5.3 Green Photocatalysis
109(1)
5.4 Organic Pollutants
110(1)
5.5 Reactive Species Responsible for Green Photocatalysis Treatment
111(1)
5.6 Advancements in Photocatalysts
112(6)
5.6.1 Titanium/Tin-Based Nanocomposite-Mediated Photocatalysis
112(2)
5.6.2 Synthesis of Various Nanocomposites as Photocatalysts
114(2)
5.6.3 Photocatalytic Degradation of Organic Pollutants
116(2)
5.7 Green Treatment of Pollutants
118(6)
5.7.1 Photodegradation of Toxic Dyes
118(2)
5.7.2 Photodegradation of Antibiotics
120(1)
5.7.3 Photodegradation of BisphenolBPA
121(3)
5.8 Conclusion
124(5)
References
125(4)
6 Treatment of Textile-Wastewater Using Green Technologies
129(28)
Shuchita Tomar
Mohammad Shahadat
S. Wazed Ali
Mangala Joshi
B.S. Butola
6.1 Introduction
130(12)
6.1.1 Textile Industries: Causes of Water Pollution
131(2)
6.1.2 The Effect of Polluted Water Discharged From Textile Industries on the Environment
133(2)
6.1.3 Various Techniques for Effluent Treatment
135(1)
6.1.4 Physical Treatment Technique
136(1)
6.1.4.1 Adsorption Method
136(1)
6.1.4.2 Ion-Exchange Method
137(1)
6.1.4.3 Floatation
137(1)
6.1.5 Chemical Treatment Technique
138(1)
6.1.5.1 Chemical Precipitation Method
138(1)
6.1.5.2 Coagulation and Sedimentation Method
138(1)
6.1.6 Chemical Oxidation
138(1)
6.1.6.1 Ozonation Method
139(1)
6.1.6.2 Fenton Oxidation Method
139(1)
6.1.6.3 Evaporation
139(2)
6.1.6.4 Solar Evaporation Method
141(1)
6.1.7 Mechanical Evaporation Method
141(1)
6.2 Green Water Treatment Technique for Textile Effluents
142(9)
6.2.1 Electrocoagulation (EC)
142(2)
6.2.2 Advanced Oxidation Process (AOP)
144(1)
6.2.3 Rotating Biological Contactor (RBC)
144(1)
6.2.4 Sequencing Batch Reactor (SBR)
145(1)
6.2.5 Effluent Treatment Using Enzymes
145(1)
6.2.6 Membrane Filtration
146(1)
6.2.7 Bioadsorbents Process for Effluent Treatment
146(4)
6.2.7.1 Citrus Fruits
150(1)
6.2.7.2 Coir Fiber
150(1)
6.2.7.3 Coconut Shell-Activated Carbon
151(1)
6.3 Conclusions
151(6)
References
151(6)
7 Photocatalytic Activity of Green Mixed Matrix Membranes for Degradation of Anionic Dye
157(22)
Oladipo
Gabriel Opeoluwa
Alayande
Samson Oluwagbemiga
Ogunyinka Opeyemi
O. Akinsiku
Anuoluwa Abimbola
Akinsipo-Oyelaja
Oyesolape Basirat
Ofudje Edwin Andrew
Bolarinwa Hakeem
S. Akinlabi
Akinola Kehinde
Msagati
A.M. Titus
7.1 Introduction
158(2)
7.2 Materials and Methods
160(2)
7.2.1 Materials
160(1)
7.2.2 Methods
160(1)
7.2.2.1 Synthesis of Ti02 Nanoparticles
160(1)
7.2.2.2 Preparation of Natural Rubber Composites
160(1)
7.2.3 Analysis
161(1)
7.2.3.1 Micrograph Analysis
161(1)
7.2.3.2 Structural Analysis
161(1)
7.2.3.3 Thermal Analysis
161(1)
7.2.3.4 Wetting Analysis
161(1)
7.2.3.5 Photocatalytic Performance
161(1)
7.3 Results and Discussion
162(13)
7.3.1 Fourier Transform Infrared Spectroscopy of Composites Membranes
162(1)
7.3.2 SEM-EDX of Composite Membranes
163(4)
7.3.3 Thermogravimetric Analysis of Composite Membranes
167(1)
7.3.4 Contact Angle Measurement of Composite Membranes
167(2)
7.3.5 Photodegradation of Composite Membranes
169(6)
7.4 Conclusion
175(4)
References
175(4)
8 Advanced Technologies for Wastewater Treatment
179(24)
Asim Ali Yaqoob
Claudia Guerrero-Barajas
Akil Ahmad
Mohamad Nasir Mohamad Ibrahim
Mohammed B. Alshammari
8.1 Introduction
180(2)
8.2 Advanced Approaches for Wastewater Treatment
182(12)
8.2.1 Photocatalytic Method
182(2)
8.2.1.1 Mechanism of Photocatalysis
184(1)
8.2.2 Nanomembranes Technology
185(2)
8.2.2.1 Limitations and Future of the Nanomembranes Technology
187(1)
8.2.3 Utilization of Nanosorbent for Wastewater Treatment
188(2)
8.2.4 Microbial Fuel Cells as a Sustainable Technique
190(1)
8.2.4.1 Mechanism and Application of MFCs in Wastewater Treatment
191(3)
8.3 Conclusion and Future Recommendations
194(9)
Acknowledgments
195(1)
References
195(8)
9 PDMS-Supported Composite Materials as Oil Absorbent
203(20)
Nur Anis Syazmin
Mohammad Shahadat
Mohd Rizal Razali
Rohana Adrian
9.1 Introduction
203(2)
9.2 Fabrications Techniques of PDMS Sponges as Oil Absorbent
205(11)
9.2.1 Sacrificial Templates
205(2)
9.2.2 Emulsion Templating Method
207(3)
9.2.3 Phase Separation Method
210(1)
9.2.4 3D Printing Techniques
211(2)
9.2.5 Gas-Forming Technique
213(3)
9.3 PDMS Sponges as an Oil/Water Separation
216(1)
9.4 Conclusion
217(6)
References
218(5)
10 Polymer Nanocomposite-Based Anode for Bioelectrochemical Systems: A Review
223(20)
Mohammad Danish Khan
Abdul Hakeem Anwer
Mohammad Zain Khan
10.1 Introduction
224(2)
10.2 Conventional Anode Materials Based on Carbon
226(1)
10.3 Modification of Anode with Nanomaterials Based on Carbon
226(2)
10.4 Metal or Metal Oxide-Based Modified Anode
228(2)
10.5 Polymer-Based Modified Anode
230(1)
10.6 Polymer Nanocomposites for Anode Modification
231(4)
10.7 Concluding Remarks and Future Perspectives
235(8)
References
236(7)
11 Electrospinning Setup Design and Modification for Fabrication of Photocatalytic Electrospun Nanofibrous Membranes for Water Treatment
243(28)
N. Awang
A.M. Nasir
S.J. Fatihhi
A. Johari
S. Shaharuddin
A.H. Bakri
M.F.M. Alkbir
M.A.M. Yajid
J. Jaafar
11.1 Introduction
244(3)
11.2 Application of Electrospun Nanofibers Polymeric Membranes (ENPM) on Wastewater Treatments
247(4)
11.3 Improvements in Morphology and Physical Structure of ENPM
251(5)
11.3.1 Surface Modification
252(2)
11.3.2 Chemical Modification
254(2)
11.4 Setup and Configurations of Electrospinning for Core-Sheath Structures of EPNM for Photocatalytic Membranes
256(9)
11.4.1 Impacts of Electrospinning Set Up on EPNM Structures
256(1)
11.4.1.1 Coaxial Electrospinning
257(2)
11.4.1.2 Electrospinning and Electrospraying
259(3)
11.4.1.3 Separation of the Melt Phase Technique
262(1)
11.4.1.4 Process of Electrospinning and Precipitation
263(2)
11.5 Future Directions and Challenges
265(2)
11.6 Conclusion
267(1)
11.7 Acknowledgment
267(4)
References
268(3)
Index 271
Shahid-ul-Islam, PhD, is a Research Scientist at the Department of Textile & Fiber Engineering, Indian Institute of Technology Delhi (IIT). His area of interests are antimicrobial coatings, green chemistry, fibers & polymers, polymeric composites and nanocomoposites and nano-biotechnology. He has published numerous peer-reviewed research articles in journals of high repute including contributions to several internationally recognized books published by the Wiley-Scrivener imprint, Springer, and Elsevier.

Aabid Hussain Shalla, PhD, is an associate professor in the Department of Chemistry at Islamic University of Science and Technology, J&K, India. He has more than 35 publications in international journals, three books, and many book chapters to his credit. His research interests include the synthesis of hybrid ion exchange materials/ion-selective electrodes/synthesis of smart responsive hydrogels to envisage their application in the removal and identification of toxic heavy metal ions, dyes, and polyaromatic hydrocarbons (PAHs) in wastewaters.

Mohammad Shahadat, PhD, is a senior lecturer at the School of Chemical Sciences, Universiti Sains Malaysia (USM), Penang, Malaysia. He has published over 60 research papers and 8 review articles in international journals as well as edited one book and 25 book chapters. His research interests include synthesis, characterization, green technologies, chitosan/polyaniline-supported biodegradable nanocomposite materials, and their significant applications in various fields, including drug delivery systems.