Handbook Introduction |
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iii | |
Preface |
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v | |
Contributors |
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ix | |
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Detergents: Technical and Practical Challenges |
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1 | (6) |
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Surfactants: Classification |
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7 | (40) |
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Louis Oldenhove de Guertechin |
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47 | (52) |
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99 | (34) |
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Anionic-Cationic Surfactant Mixtures |
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133 | (24) |
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Polymer-Surfactant Interactins: Their Behavior at the Solid-Liquid Interface |
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157 | (24) |
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Anne-Marie Misselyn-Bauduin |
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181 | (72) |
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253 | (50) |
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Equilibrium and Dynamics of Surfactant Adsorption Monolayers and Thin Liquid Films |
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303 | (116) |
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Foam in Consumer Products |
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419 | (14) |
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Surfactant Interactions with Skin |
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433 | (36) |
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Models for Studying Surfactant interactions with the Skin |
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469 | (42) |
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Properties of Builders: Nonphosphate Builders |
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511 | (48) |
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559 | (38) |
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597 | (22) |
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619 | (12) |
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Applications of Hypochlorite |
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631 | (8) |
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Detergent Enzymes: A Challenge! |
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639 | (52) |
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691 | (30) |
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The Use of Colorants in Soaps and Detergents |
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721 | (22) |
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Disinfection and Preservation in Detergents |
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743 | (14) |
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Rheological Modifiers for Aqueous Solutions |
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757 | (30) |
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Index |
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787 | (24) |
Handbook Introduction |
|
iii | |
Preface |
|
vii | |
Contributors |
|
xiii | |
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Part I The Multidimensionality of Detergent-Related Environmental Impact and Its Assessment |
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Sustainable Relationships: Raw Materials-Surfactant/Detergent Production/Formulation-Usage/Consumption-Environment: A Systemic Challenge for the New Millennium |
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1 | (10) |
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Detergents and the Environment: Historical Review |
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11 | (66) |
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Distribution, Behavior, Fate, and Effects of Surfactants and Their Degradation Products in the Environment |
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77 | (34) |
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Relevance of Biodegradation Assessments of Detergents/Surfactants |
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111 | (18) |
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Toxicology and Ecotoxicology of Detergent Chemicals |
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129 | (18) |
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Generation and Use of Data to Predict Environmental Concentrations for use in Detergent Risk Assessments |
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147 | (48) |
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Life Cycle Assessment: A Novel Approach to the Environmental Profile of Detergent Consumer Products |
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195 | (16) |
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Biodegradability and Toxicity of Surfactants |
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211 | (38) |
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The Biodegradability of Detergent Ingredients in an Environemental Context: A Practical Approach |
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249 | (22) |
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Environmental Risk Assessment of Surfactants: Quantitative Structure-Activity Relationships for Aquatic Toxicity |
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271 | (28) |
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Environmental Impacts of Detergent Packaging: The Case of Plastic Bottles |
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299 | (18) |
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European Environmental Safety Legislation on Detergents |
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317 | (30) |
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The Application of Environmental Risk Assessment to Detergent Ingredients in Consumer Products |
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347 | (26) |
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Christina Cowan-Ellsberry |
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Part II Environmental Behavior, Effects, and Impact of Detergent Components |
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Surfactants in the Enviroment: Fate and Effects of Linear Alkylbenzene Sulfonates (LAS) and Alcohol-Based Surfactants |
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373 | (56) |
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The Environmental Safety of Alkylphenol Ethoxylates Demonstrated by Risk Assessment and Guidelines for Their Safe Use |
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429 | (18) |
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Estrogenic Effects of the Alklyphenol Ethoxylates and Their Biodegradation Products |
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447 | (20) |
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The Survival and Distribution of Alkylphenol Ethoxylate Surfactants in Surface Water and Groundwater: The Case of Isreal-Is There an Environmental Problem? |
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467 | (20) |
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Ecology and Toxicology of Alkyl Polyglysosides |
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487 | (36) |
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Biodegradation of Cationic Surfactants: An Environmental Perspective |
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523 | (28) |
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Biodegradability of Amphoteric Surfactants |
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551 | (22) |
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Environmental Impact of Inorganic Detergent Builders |
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573 | (38) |
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Environmental Impact of Aminocarboxylate Chelating Agents |
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611 | (18) |
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Environmental Impact of Bleaching Activators |
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629 | (16) |
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Perborates: The Environmentally Problematic Bleaching Agents |
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645 | (18) |
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Toxicology and Ecotoxicology of Minor Components in Personal Care Products |
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663 | (28) |
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The Environmental Impact of Surfactant Ingredients in Pesticide Formulations---Special Focus on Alcohol Ethoxylates and Alkylamine Ethoxylates |
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691 | (28) |
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Biodegradation of Surface-Active Detergent Components in Sewage Treatment Plants |
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719 | (20) |
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Surfactant Biodegradation: Sugar-based Surfactants Compared to Other Surfactants |
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739 | (22) |
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Biotreatment of Wastewater with a High Concentration of Surfactants |
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761 | (24) |
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Science Versus Politics in the Environmental Regulatory Process |
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785 | (18) |
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The Environmental Impact of Detergents: Which Way is the Wind Blowing? |
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803 | (8) |
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Index |
|
811 | |
Handbook Introduction |
|
iii | |
Preface |
|
vii | |
Contributors |
|
xi | |
|
Types and Typical Ingredients of Detergents |
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1 | (100) |
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Analysis of Detergent Formulations---General Procedure |
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101 | (48) |
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Determination of Nonionic Surfactants |
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149 | (66) |
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Determination of Anionic Surfactants |
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215 | (74) |
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Analysis of Cationic and Amphoteric Surfactants |
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289 | (100) |
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Analysis of Inorganic Detergent Builders |
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389 | (36) |
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Sequestrants and Chelating Agents |
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425 | (14) |
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Analysis of Bleaching Agents and Bleaching Accelerators |
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439 | (32) |
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Analysis of Detergent Enzymes |
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471 | (16) |
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Determination of Optical Brighteners in Laundry Detergents |
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487 | (20) |
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Miscellaneous Ingredients |
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507 | (34) |
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Testing Performance of Detergents and Cleansers |
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541 | (10) |
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Environmentally Related Analysis |
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551 | (30) |
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Analytical Techniques: Basics and Fields of Application |
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581 | (62) |
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Future Trends |
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643 | (2) |
Index |
|
645 | |
|
Introduction to Detergents |
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1 | (26) |
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Statistical Mixture Design for Optimization of Detergent Formulations |
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27 | (24) |
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Laundry Detergent Formulations |
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51 | (54) |
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Dishwashing Detergents for Household Applications |
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105 | (48) |
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The Formulation of Liquid Household Cleaners |
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153 | (26) |
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Liquid Bleach Formulations |
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179 | (28) |
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Personal Care Formulations |
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207 | (54) |
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Special Purpose Cleaning Formulations: Auto Care and Industrial/Institutional Products |
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261 | (18) |
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Surfactant Applications in Textile Processing |
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279 | (26) |
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Detergent Formulations in Separation Science |
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305 | (20) |
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Surfactant Formulations in Enhanced Oil Recovery |
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325 | (22) |
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Surfactant-Based Systems for Environmental Remediation |
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347 | (22) |
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369 | (18) |
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Surfactant Formulations in Polymerization |
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387 | (50) |
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Detergent Formulations in Lubricants |
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437 | (36) |
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|
473 | (10) |
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|
Future Outlook for Detergent Formulations |
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|
483 | (36) |
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Index |
|
519 | |
Handbook Introduction |
|
xiii | |
Handbook of Detergents Series |
|
xv | |
Preface |
|
xvii | |
Editor |
|
xix | |
Contributors |
|
xxi | |
|
Detergents Application: Current Realities and Future Perspectives |
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|
1 | (4) |
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All-Purpose Cleaners and Their Formulation |
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5 | (34) |
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Dishwashing with Detergents |
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39 | (30) |
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Applications of Detergent in Laundering |
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69 | (14) |
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83 | (26) |
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Application of Personal Care Detergent Formulations |
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109 | (26) |
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Body-Cleansing Technology |
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135 | (16) |
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Applications of Surfactants in Shampoos |
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151 | (30) |
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181 | (20) |
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Industrial and Institutional Cleaners |
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201 | (86) |
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Applications of Amphoterics-Based Formulations |
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287 | (14) |
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Detergents in Agrochemical and Pesticide Applications |
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301 | (30) |
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Application of Surfactants in Lubricants and Fuels |
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331 | (14) |
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Polymeric Surfactants and Their Applications: Steric, Emulsion, and Suspension Stabilization |
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345 | (18) |
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Application of Surfactants in Environmental Remediation |
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363 | (12) |
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Application of Bleaching Detergent Formulations |
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375 | (44) |
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Role of Surfactants in Paints, Inks, and Polishes |
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419 | (36) |
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Applications of Surfactants in Pharmaceutical Dosage Forms |
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|
455 | (14) |
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Index |
|
469 | (110) |
Handbook Introduction |
|
xv | |
Handbook of Detergents Series |
|
xvii | |
Preface |
|
xix | |
Editor |
|
xxi | |
Co-Editor |
|
xxiii | |
Contributors |
|
xxv | |
|
Surfactant Production: Present Realities and Future Perspectives |
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|
1 | (38) |
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Detergent Alkylate and Detergent Olefins Production |
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39 | (10) |
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Production and Economics of Alkylphenols, Alkylphenolethoxylates, and Their Raw Materials |
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49 | (20) |
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Production of Alkyl Glucosides |
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69 | (14) |
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Production of Linear Alkylbenzene Sulfonate and α-Olefin Sulfonates |
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83 | (34) |
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Production of Alcohols and Alcohol Sulfates |
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117 | (22) |
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Production of Alkanesulfonates and Related Compounds (High-Molecular-Weight Sulfonates) |
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139 | (20) |
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Production of Glyceryl Ether Sulfonates |
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159 | (12) |
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Manufacture of Syndet Toilet Bars |
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171 | (12) |
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Phosphate Ester Surfactants |
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183 | (18) |
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Production of Methyl Ester Sulfonates |
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201 | (20) |
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Amphoteric Surfactants: Synthesis and Production |
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221 | (18) |
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Production of Alkanolamides, Alkylpolyglucosides, Alkylsulfosuccinates, and Alkylgucamides |
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239 | (8) |
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Production of Hydrotropes |
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247 | (6) |
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Production of Ethylene Oxide/Propylene Oxide Block Copolymers |
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253 | (18) |
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Production of Oxyethylated Fatty Acid Methyl Esters |
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271 | (14) |
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Production of Silicone Surfactants and Antifoam Compounds in Detergents |
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285 | (16) |
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|
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Production of Fluorinated Surfactants by Electrochemical Fluorination |
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301 | (22) |
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323 | (42) |
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Production of Quaternary Surfactants |
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365 | (10) |
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Production of Detergent Builders: Phosphates, Carbonates, and Polycarboxylates |
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375 | (12) |
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Production of Silicates and Zeolites for Detergent Industry |
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387 | (34) |
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Production of Inorganic and Organic Bleaching Ingredients |
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421 | (14) |
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Inorganic Bleaches: Production of Hypochlorite |
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435 | (38) |
|
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Production of Key Ingredients of Detergent Personal Care Products |
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473 | (18) |
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|
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Production of Solvents for Detergent Industry |
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491 | (40) |
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Production of Proteases and Other Detergent Enzymes |
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|
531 | (16) |
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|
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Chemistry, Production, and Application of Fluorescent Whitening Agents |
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|
547 | (14) |
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|
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Production of Gemini Surfactants |
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|
561 | (18) |
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Index |
|
579 | |