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E-grāmata: Handbook of Green Materials: Processing Technologies, Properties and Applications [World Scientific e-book]

Edited by (Lulea Univ Of Technology, Sweden), Edited by (North Carolina State Univ, Usa), Edited by (Lulea Univ Of Technology, Sweden), Edited by (Univ Of Toronto, Canada), Edited by (Univ Of Vienna, Austria & Imperial College London, Uk)
  • Formāts: 1124 pages
  • Sērija : Materials and Energy 5
  • Izdošanas datums: 11-Jun-2014
  • Izdevniecība: World Scientific Publishing Co Pte Ltd
  • ISBN-13: 9789814566469
  • World Scientific e-book
  • Cena: 1 828,25 €*
  • * this price gives unlimited concurrent access for unlimited time
  • Formāts: 1124 pages
  • Sērija : Materials and Energy 5
  • Izdošanas datums: 11-Jun-2014
  • Izdevniecība: World Scientific Publishing Co Pte Ltd
  • ISBN-13: 9789814566469
Green materials and green nanotechnology have gained widespread interest over the last 15 years; first in academia, then in related industries in the last few years.The Handbook of Green Materials serves as reference literature for undergraduates and graduates studying materials science and engineering, composite materials, chemical engineering, bioengineering and materials physics; and for researchers, professional engineers and consultants from polymer or forest industries who encounter biobased nanomaterials, bionanocomposites, self- and direct-assembled nanostructures and green composite materials in their lines of work.This four-volume set contains material ranging from basic, background information on the fields discussed, to reports on the latest research and industrial activities, and finally the works by contributing authors who are prominent experts of the subjects they address in this set.The four volumes comprise of: Vol. 1. Bionanomaterials: separation processes, characterization and properties Vol. 2. Bionanocomposites: processing, characterization and properties Vol. 3. Self- and direct-assembling of bionanomaterials Vol. 4. Biobased composite materials, their processing properties and industrial applications The first volume explains the structure of cellulose; different sources of raw material; the isolation/separation processes of nanomaterials from different material sources; and properties and characteristics of cellulose nanofibers and nanocrystals (starch nanomaterials). Information on the different characterization methods and the most important properties of biobased nanomaterials are also covered. The industrial point of view regarding both the processability and access of these nanomaterials, as well as large scale manufacturing and their industrial application is discussed — particularly in relation to the case of the paper industry.The second volume expounds on different bionanocomposites based on cellulose nanofibers or nanocrystals and their preparation/manufacturing processes. It also provides information on different characterization methods, the most important properties of bionanocomposites, as well as techniques of modeling the mechanical properties of nanocomposites. This volume presents the industrial point of view regarding large scale manufacturing and their applications from the perspective of their medical uses in printed electronics and in adhesives.The third volume deals with the ability of bionanomaterials to self-assemble either in liquids or forming organized solid materials. The chemistry of cellulose nanomaterials and chemical modifications as well as different assembling techniques and used characterization methods and the most important properties which can be achieved by self-assembly are described. The chapters, for example, discuss subjects such as ultra-light biobased aerogels based on cellulose and chitin, thin films suitable as barrier layers, self-sensing nanomaterials, and membranes for water purification.The fourth volume reviews green composite materials — including green raw materials — such as biobased carbon fibers, regenerated cellulose fibers and thermoplastic and thermoset polymers (e.g. PLA, bio-based polyolefines, polysaccharide polymers, natural rubber, bio-based polyurethane, lignin polymer, and furfurylalchohol). The most important composite processing technologies are described, including: prepregs of green composites, compounding, liquid composite molding, foaming, and compression molding. Industrial applications, especially for green transportation and the electronics industry, is also described.This four-volume set is a must-have for anyone keen to acquire knowledge on novel bionanomaterials — including structure-property correlations, isolation and purification processes of nanofibers and nanocrystals, their important characteristics, processing technologies, industrial up-scaling and suitable industry applications.The handbook is a useful reference not only for teaching activities but also for researchers who are working in this field.
List of Corresponding Authors (Volume 1)
xi
1 Bionanomaterials: Separation Processes, Characterization, and Properties
1(4)
Aji P. Mathew
Kristiina Oksman
1.1 Introduction to the content
1(1)
1.2 Contents
2(3)
2 Structure and Physical Properties of Cellulose: Micro- to Nanoscale
5(14)
Yoshiharu Nishiyama
2.1 Introduction
5(1)
2.2 Biosynthesis and the morphogenesis of nanocellulose
6(2)
2.2.1 Crystalline nature of native cellulose nanofibers
7(1)
2.3 Packing of cellulose chains and polymorphism
8(3)
2.3.1 Native cellulose
8(1)
2.3.2 Amine complex and cellulose III
9(1)
2.3.3 Alkali swelling and cellulose II
10(1)
2.4 Accessibility, constraint, and chemical reactivity
11(2)
2.4.1 Core, surface, and bundle
11(1)
2.4.2 Long-range periodicity along the chain
11(1)
2.4.3 Terminology and perception of nanocellulose
12(1)
2.5 Mechanical properties of cellulose microfibrils
13(1)
2.5.1 Intrinsic tensile modulus
13(1)
2.5.2 Other elastic moduli
14(1)
2.6 Thermal properties of cellulose
14(1)
2.7 Conclusion and perspectives
15(4)
References
15(4)
3 Natural Resources and Residues for Production of Bionanomaterials
19(16)
Mehdi Jonoobi
Aji P. Mathew
Kristiina Oksman
3.1 Introduction
19(2)
3.2 Structure of the raw material source
21(3)
3.3 Bionanomaterials from plant sources
24(5)
3.4 Bionanomaterials from marine sources
29(2)
3.5 Conclusions
31(4)
Acknowledgments
31(1)
References
32(3)
4 Pretreatment of Cellulose for Further Processing
35(18)
Akira Isogai
4.1 Introduction
35(1)
4.2 TEMPO-mediated oxidation
36(7)
4.2.1 TEMPO/NaBr/NaClO system at pH 10
37(3)
4.2.2 TEMPO/NaClO/NaClO2 system at pH 5 or 7
40(1)
4.2.3 TEMPO electro-mediated oxidation at pH 7 or 10
41(2)
4.3 Nanofibrillation of TEMPO-oxidized cellulose
43(5)
4.3.1 Characterization of TOCNs
45(1)
4.3.2 Conversion of TOCN/water dispersion to bulk materials
45(3)
4.4 TOCN-containing composites and future applications
48(5)
References
49(4)
5 Technologies for Separation of Cellulose Nanofibers
53(20)
Maiju Hietala
Kristiina Oksman
5.1 Introduction
53(2)
5.2 Pretreatments
55(2)
5.3 Mechanical separation of CNFs
57(9)
5.3.1 High-pressure homogenization
57(6)
5.3.2 Other methods
63(3)
5.4 Conclusions
66(7)
References
68(5)
6 Separation of Cellulose Nanocrystals
73(16)
Gregory Chauve
Carole Fraschini
Bruno Jean
6.1 Introduction
73(1)
6.2 CNC: Emergence of a versatile material
74(1)
6.3 Various recipes, sources, and end products
74(1)
6.4 H2SO4 hydrolysis and its influencing parameters
75(3)
6.5 The special features of sulfuric acid-extracted CNCs
78(1)
6.6 CNCs size and morphology
78(2)
6.7 Stability over time issues
80(1)
6.8 Size fractionation/size separation/collection
80(1)
6.9 Pre-industrialization challenges
81(1)
6.9.1 Drying issues
82(1)
6.9.2 Control of the self-assembly
82(1)
6.9.3 Toxicity evaluation
82(1)
6.9.4 Scale-up equipment and safety issues
82(1)
6.10 World production capacity
82(1)
6.11 Post-industrialization challenges
83(6)
Acknowledgments
84(1)
References
84(5)
7 Starch Nanocrystals
89(16)
Mariana Pereda
Alain Dufresne
7.1 Introduction
89(1)
7.2 Starch
90(2)
7.2.1 Multiscale structure of starch granules --- semicrystallinity
91(1)
7.3 Starch nanocrystals
92(2)
7.3.1 Hydrolysis treatments
92(1)
7.3.2 Morphology
93(1)
7.4 Kinetics of hydrolysis
94(3)
7.5 Optimization of the SNC extraction process
97(4)
7.5.1 Membrane microfiltration
97(2)
7.5.2 Enzymatic pretreatment
99(2)
7.6 Conclusions
101(4)
References
101(4)
8 Production of Bacterial Cellulose: Use of a New Strain of Microorganism
105(18)
Cristina Castro
Ilse Cleenwerck
Robin Zuluaga
Gloria Caro
Jean-Luc Putaux
Orlando J. Rojas
Piedad Ganan
8.1 Introduction
105(1)
8.2 New cellulose-producing bacteria belonging to the Gluconacetobacter genus
106(4)
8.3 Cellulose synthesis by G. medellinensis ID13488
110(3)
8.4 Morphology and structure of the bacterial cellulose
113(4)
8.5 Conclusions
117(6)
References
118(5)
9 Chemical Functionalization as a Powerful Tool to Broaden the Scope of Applications of Cellulose Nanofibers
123(16)
Philippe Tingaut
Tanja Zimmermann
9.1 Introduction
123(2)
9.2 Functional films from CNFs
125(3)
9.3 Reinforcing agent in composite materials
128(2)
9.4 Aerogels and foams from CNFs
130(3)
9.5 Conclusions
133(6)
References
133(6)
10 Rheological Properties of Nanocellulose Materials
139(20)
Guan Gong
10.1 Introduction
139(1)
10.2 Rheological properties of CNF suspensions
140(7)
10.2.1 Effect of fiber concentration and dimension
140(5)
10.2.2 Effect of surface modification and polymer additives
145(2)
10.3 Rheological properties of CNC suspensions
147(7)
10.3.1 Influence of concentration, surface charge, and crystalline structure of crystals
147(5)
10.3.2 Influence of organic solvents and polymer solutions
152(2)
10.4 Summary
154(5)
References
154(5)
11 Microscopic Characterization of Nanofibers and Nanocrystals
159(22)
Robert J. Moon
Tiina Pohler
Tekla Tammelin
11.1 Introduction
159(1)
11.2 Cellulose nanomaterials morphology characterization
160(7)
11.2.1 Optical microscopy
160(2)
11.2.2 Scanning electron microscopy
162(2)
11.2.3 Transmission electron microscopy
164(1)
11.2.4 Atomic force microscopy --- topography
165(2)
11.3 Cellulose nanomaterial structural characterization
167(5)
11.3.1 Wide-angle X-ray diffraction
168(1)
11.3.1.1 Peak height method
168(1)
11.3.1.2 Peak deconvolution method
169(1)
11.3.1.3 Amorphous subtraction method
169(1)
11.3.2 Raman spectroscopy
170(1)
11.3.3 Fourier transform infrared spectroscopy
171(1)
11.3.4 Solid-state 13C nuclear magnetic resonance
171(1)
11.4 Cellulose nanomaterials mechanical property measurement
172(3)
11.4.1 AFM --- force spectroscopy
173(1)
11.4.1.1 Axial mechanical properties
173(1)
11.4.1.2 Transverse mechanical properties
174(1)
11.4.2 Raman spectroscopy
174(1)
11.4.3 X-ray diffraction and inelastic X-ray scattering
175(1)
11.5 Cellulose nanomaterials surface chemistry
175(1)
11.6 Conclusions
176(5)
References
176(5)
12 Toxicity and Health Issues
181(26)
Marja Pitkanen
Heli Kangas
Jari Vartiainen
12.1 Introduction
181(2)
12.2 Biobased nanomaterials
183(4)
12.2.1 Nanostructured celluloses: Fibrillated, crystalline and bacterial
183(3)
12.2.2 Nanostructured chitin --- chitin and chitosan nanofibrils
186(1)
12.2.3 Nanostructured starch --- starch nanocrystals
187(1)
12.3 Current regulatory status for nanomaterials
187(2)
12.4 Risk assessment for nanomaterials
189(1)
12.5 Toxicity of biobased nanomaterials
190(9)
12.5.1 Toxicity to humans
190(1)
12.5.1.1 Cellulose microfibrils
190(1)
12.5.1.2 Cellulose nanofibrils
190(1)
12.5.1.3 Bacterial cellulose
191(1)
12.5.1.4 Cellulose nanocrystals
192(1)
12.5.1.5 Nanostructured chitin
193(1)
12.5.1.6 Nanostructured starch
193(1)
12.5.2 Environmental toxicity
194(2)
12.5.3 Exposure assessment
196(1)
12.5.3.1 Consumers' exposure
196(1)
12.5.3.2 Occupational exposure
197(1)
12.5.3.3 Environmental exposure
198(1)
12.5.3.4 Risk assessment
198(1)
12.6 Discussion
199(2)
12.7 Conclusions
201(6)
References
201(6)
13 Cellulose Nanofibers and Their Use in Paper Industry
207(26)
Raphael Bardet
Julien Bras
13.1 Introduction
207(2)
13.2 Bulk addition
209(7)
13.2.1 Direct addition of CNF in the pulp suspension
209(2)
13.2.2 Multiply strategy
211(1)
13.2.3 CNF and polyelectrolytes
212(1)
13.2.3.1 Retention and strengthening agents
212(1)
13.2.3.2 Sizing agent
213(1)
13.2.3.3 Optical brightening agent
213(1)
13.2.3.4 Hybrid furnish additives: Filler/CNF
214(2)
13.3 CNFs and paper surface treatment
216(10)
13.3.1 Barrier properties
217(1)
13.3.1.1 Pure CNF coating
217(1)
13.3.1.2 Multilayer approach for barrier applications
218(1)
13.3.1.3 CNF blend for barrier packaging
219(1)
13.3.1.4 Hybrid barrier coating
220(1)
13.3.2 Printing properties
221(1)
13.3.2.1 Pure CNF coating
222(1)
13.3.2.2 CNFs and polymer blend for printing applications
222(1)
13.3.2.3 CNF/hybrid and replacement of synthetic binder
223(2)
13.3.3 Functional properties
225(1)
13.3.3.1 Hydrophobic paper
225(1)
13.3.3.2 Antimicrobial paper
225(1)
13.3.3.3 Conductive paper
226(1)
13.4 Conclusions
226(7)
References
227(6)
14 Industrial Point of View of Nanocellulose Materials and Their Possible Applications
233(20)
Gregory Chauve
Julien Bras
14.1 Introduction
233(1)
14.2 The emergence of nanocellulose materials
234(1)
14.3 Cellulose nanocrystals
235(3)
14.3.1 Today's CNC players
235(1)
14.3.2 Production process issues
235(2)
14.3.3 Marketing issues
237(1)
14.3.4 Environmental and regulation issues
237(1)
14.3.5 The cost aspect
237(1)
14.3.6 Main possible applications and industrial end users
237(1)
14.4 Cellulose nanofibers
238(5)
14.4.1 Today players and production perspectives
240(3)
14.5 Possible applications and industrial users
243(5)
14.5.1 Nanocomposites
244(1)
14.5.2 Paper application
245(1)
14.5.3 Films and aerogels
246(1)
14.5.4 Challenges for industrial applications
247(1)
14.6 Perspectives and challenges of the nanocellulose industries
248(5)
References
249(4)
Index 253