|
List of Corresponding Authors (Volume 1) |
|
|
xi | |
|
1 Bionanomaterials: Separation Processes, Characterization, and Properties |
|
|
1 | (4) |
|
|
|
1.1 Introduction to the content |
|
|
1 | (1) |
|
|
2 | (3) |
|
2 Structure and Physical Properties of Cellulose: Micro- to Nanoscale |
|
|
5 | (14) |
|
|
|
5 | (1) |
|
2.2 Biosynthesis and the morphogenesis of nanocellulose |
|
|
6 | (2) |
|
2.2.1 Crystalline nature of native cellulose nanofibers |
|
|
7 | (1) |
|
2.3 Packing of cellulose chains and polymorphism |
|
|
8 | (3) |
|
|
8 | (1) |
|
2.3.2 Amine complex and cellulose III |
|
|
9 | (1) |
|
2.3.3 Alkali swelling and cellulose II |
|
|
10 | (1) |
|
2.4 Accessibility, constraint, and chemical reactivity |
|
|
11 | (2) |
|
2.4.1 Core, surface, and bundle |
|
|
11 | (1) |
|
2.4.2 Long-range periodicity along the chain |
|
|
11 | (1) |
|
2.4.3 Terminology and perception of nanocellulose |
|
|
12 | (1) |
|
2.5 Mechanical properties of cellulose microfibrils |
|
|
13 | (1) |
|
2.5.1 Intrinsic tensile modulus |
|
|
13 | (1) |
|
2.5.2 Other elastic moduli |
|
|
14 | (1) |
|
2.6 Thermal properties of cellulose |
|
|
14 | (1) |
|
2.7 Conclusion and perspectives |
|
|
15 | (4) |
|
|
15 | (4) |
|
3 Natural Resources and Residues for Production of Bionanomaterials |
|
|
19 | (16) |
|
|
|
|
|
19 | (2) |
|
3.2 Structure of the raw material source |
|
|
21 | (3) |
|
3.3 Bionanomaterials from plant sources |
|
|
24 | (5) |
|
3.4 Bionanomaterials from marine sources |
|
|
29 | (2) |
|
|
31 | (4) |
|
|
31 | (1) |
|
|
32 | (3) |
|
4 Pretreatment of Cellulose for Further Processing |
|
|
35 | (18) |
|
|
|
35 | (1) |
|
4.2 TEMPO-mediated oxidation |
|
|
36 | (7) |
|
4.2.1 TEMPO/NaBr/NaClO system at pH 10 |
|
|
37 | (3) |
|
4.2.2 TEMPO/NaClO/NaClO2 system at pH 5 or 7 |
|
|
40 | (1) |
|
4.2.3 TEMPO electro-mediated oxidation at pH 7 or 10 |
|
|
41 | (2) |
|
4.3 Nanofibrillation of TEMPO-oxidized cellulose |
|
|
43 | (5) |
|
4.3.1 Characterization of TOCNs |
|
|
45 | (1) |
|
4.3.2 Conversion of TOCN/water dispersion to bulk materials |
|
|
45 | (3) |
|
4.4 TOCN-containing composites and future applications |
|
|
48 | (5) |
|
|
49 | (4) |
|
5 Technologies for Separation of Cellulose Nanofibers |
|
|
53 | (20) |
|
|
|
|
53 | (2) |
|
|
55 | (2) |
|
5.3 Mechanical separation of CNFs |
|
|
57 | (9) |
|
5.3.1 High-pressure homogenization |
|
|
57 | (6) |
|
|
63 | (3) |
|
|
66 | (7) |
|
|
68 | (5) |
|
6 Separation of Cellulose Nanocrystals |
|
|
73 | (16) |
|
|
|
|
|
73 | (1) |
|
6.2 CNC: Emergence of a versatile material |
|
|
74 | (1) |
|
6.3 Various recipes, sources, and end products |
|
|
74 | (1) |
|
6.4 H2SO4 hydrolysis and its influencing parameters |
|
|
75 | (3) |
|
6.5 The special features of sulfuric acid-extracted CNCs |
|
|
78 | (1) |
|
6.6 CNCs size and morphology |
|
|
78 | (2) |
|
6.7 Stability over time issues |
|
|
80 | (1) |
|
6.8 Size fractionation/size separation/collection |
|
|
80 | (1) |
|
6.9 Pre-industrialization challenges |
|
|
81 | (1) |
|
|
82 | (1) |
|
6.9.2 Control of the self-assembly |
|
|
82 | (1) |
|
6.9.3 Toxicity evaluation |
|
|
82 | (1) |
|
6.9.4 Scale-up equipment and safety issues |
|
|
82 | (1) |
|
6.10 World production capacity |
|
|
82 | (1) |
|
6.11 Post-industrialization challenges |
|
|
83 | (6) |
|
|
84 | (1) |
|
|
84 | (5) |
|
|
89 | (16) |
|
|
|
|
89 | (1) |
|
|
90 | (2) |
|
7.2.1 Multiscale structure of starch granules --- semicrystallinity |
|
|
91 | (1) |
|
|
92 | (2) |
|
7.3.1 Hydrolysis treatments |
|
|
92 | (1) |
|
|
93 | (1) |
|
7.4 Kinetics of hydrolysis |
|
|
94 | (3) |
|
7.5 Optimization of the SNC extraction process |
|
|
97 | (4) |
|
7.5.1 Membrane microfiltration |
|
|
97 | (2) |
|
7.5.2 Enzymatic pretreatment |
|
|
99 | (2) |
|
|
101 | (4) |
|
|
101 | (4) |
|
8 Production of Bacterial Cellulose: Use of a New Strain of Microorganism |
|
|
105 | (18) |
|
|
|
|
|
|
|
|
|
105 | (1) |
|
8.2 New cellulose-producing bacteria belonging to the Gluconacetobacter genus |
|
|
106 | (4) |
|
8.3 Cellulose synthesis by G. medellinensis ID13488 |
|
|
110 | (3) |
|
8.4 Morphology and structure of the bacterial cellulose |
|
|
113 | (4) |
|
|
117 | (6) |
|
|
118 | (5) |
|
9 Chemical Functionalization as a Powerful Tool to Broaden the Scope of Applications of Cellulose Nanofibers |
|
|
123 | (16) |
|
|
|
|
123 | (2) |
|
9.2 Functional films from CNFs |
|
|
125 | (3) |
|
9.3 Reinforcing agent in composite materials |
|
|
128 | (2) |
|
9.4 Aerogels and foams from CNFs |
|
|
130 | (3) |
|
|
133 | (6) |
|
|
133 | (6) |
|
10 Rheological Properties of Nanocellulose Materials |
|
|
139 | (20) |
|
|
|
139 | (1) |
|
10.2 Rheological properties of CNF suspensions |
|
|
140 | (7) |
|
10.2.1 Effect of fiber concentration and dimension |
|
|
140 | (5) |
|
10.2.2 Effect of surface modification and polymer additives |
|
|
145 | (2) |
|
10.3 Rheological properties of CNC suspensions |
|
|
147 | (7) |
|
10.3.1 Influence of concentration, surface charge, and crystalline structure of crystals |
|
|
147 | (5) |
|
10.3.2 Influence of organic solvents and polymer solutions |
|
|
152 | (2) |
|
|
154 | (5) |
|
|
154 | (5) |
|
11 Microscopic Characterization of Nanofibers and Nanocrystals |
|
|
159 | (22) |
|
|
|
|
|
159 | (1) |
|
11.2 Cellulose nanomaterials morphology characterization |
|
|
160 | (7) |
|
11.2.1 Optical microscopy |
|
|
160 | (2) |
|
11.2.2 Scanning electron microscopy |
|
|
162 | (2) |
|
11.2.3 Transmission electron microscopy |
|
|
164 | (1) |
|
11.2.4 Atomic force microscopy --- topography |
|
|
165 | (2) |
|
11.3 Cellulose nanomaterial structural characterization |
|
|
167 | (5) |
|
11.3.1 Wide-angle X-ray diffraction |
|
|
168 | (1) |
|
11.3.1.1 Peak height method |
|
|
168 | (1) |
|
11.3.1.2 Peak deconvolution method |
|
|
169 | (1) |
|
11.3.1.3 Amorphous subtraction method |
|
|
169 | (1) |
|
11.3.2 Raman spectroscopy |
|
|
170 | (1) |
|
11.3.3 Fourier transform infrared spectroscopy |
|
|
171 | (1) |
|
11.3.4 Solid-state 13C nuclear magnetic resonance |
|
|
171 | (1) |
|
11.4 Cellulose nanomaterials mechanical property measurement |
|
|
172 | (3) |
|
11.4.1 AFM --- force spectroscopy |
|
|
173 | (1) |
|
11.4.1.1 Axial mechanical properties |
|
|
173 | (1) |
|
11.4.1.2 Transverse mechanical properties |
|
|
174 | (1) |
|
11.4.2 Raman spectroscopy |
|
|
174 | (1) |
|
11.4.3 X-ray diffraction and inelastic X-ray scattering |
|
|
175 | (1) |
|
11.5 Cellulose nanomaterials surface chemistry |
|
|
175 | (1) |
|
|
176 | (5) |
|
|
176 | (5) |
|
12 Toxicity and Health Issues |
|
|
181 | (26) |
|
|
|
|
|
181 | (2) |
|
12.2 Biobased nanomaterials |
|
|
183 | (4) |
|
12.2.1 Nanostructured celluloses: Fibrillated, crystalline and bacterial |
|
|
183 | (3) |
|
12.2.2 Nanostructured chitin --- chitin and chitosan nanofibrils |
|
|
186 | (1) |
|
12.2.3 Nanostructured starch --- starch nanocrystals |
|
|
187 | (1) |
|
12.3 Current regulatory status for nanomaterials |
|
|
187 | (2) |
|
12.4 Risk assessment for nanomaterials |
|
|
189 | (1) |
|
12.5 Toxicity of biobased nanomaterials |
|
|
190 | (9) |
|
12.5.1 Toxicity to humans |
|
|
190 | (1) |
|
12.5.1.1 Cellulose microfibrils |
|
|
190 | (1) |
|
12.5.1.2 Cellulose nanofibrils |
|
|
190 | (1) |
|
12.5.1.3 Bacterial cellulose |
|
|
191 | (1) |
|
12.5.1.4 Cellulose nanocrystals |
|
|
192 | (1) |
|
12.5.1.5 Nanostructured chitin |
|
|
193 | (1) |
|
12.5.1.6 Nanostructured starch |
|
|
193 | (1) |
|
12.5.2 Environmental toxicity |
|
|
194 | (2) |
|
12.5.3 Exposure assessment |
|
|
196 | (1) |
|
12.5.3.1 Consumers' exposure |
|
|
196 | (1) |
|
12.5.3.2 Occupational exposure |
|
|
197 | (1) |
|
12.5.3.3 Environmental exposure |
|
|
198 | (1) |
|
|
198 | (1) |
|
|
199 | (2) |
|
|
201 | (6) |
|
|
201 | (6) |
|
13 Cellulose Nanofibers and Their Use in Paper Industry |
|
|
207 | (26) |
|
|
|
|
207 | (2) |
|
|
209 | (7) |
|
13.2.1 Direct addition of CNF in the pulp suspension |
|
|
209 | (2) |
|
|
211 | (1) |
|
13.2.3 CNF and polyelectrolytes |
|
|
212 | (1) |
|
13.2.3.1 Retention and strengthening agents |
|
|
212 | (1) |
|
|
213 | (1) |
|
13.2.3.3 Optical brightening agent |
|
|
213 | (1) |
|
13.2.3.4 Hybrid furnish additives: Filler/CNF |
|
|
214 | (2) |
|
13.3 CNFs and paper surface treatment |
|
|
216 | (10) |
|
13.3.1 Barrier properties |
|
|
217 | (1) |
|
13.3.1.1 Pure CNF coating |
|
|
217 | (1) |
|
13.3.1.2 Multilayer approach for barrier applications |
|
|
218 | (1) |
|
13.3.1.3 CNF blend for barrier packaging |
|
|
219 | (1) |
|
13.3.1.4 Hybrid barrier coating |
|
|
220 | (1) |
|
13.3.2 Printing properties |
|
|
221 | (1) |
|
13.3.2.1 Pure CNF coating |
|
|
222 | (1) |
|
13.3.2.2 CNFs and polymer blend for printing applications |
|
|
222 | (1) |
|
13.3.2.3 CNF/hybrid and replacement of synthetic binder |
|
|
223 | (2) |
|
13.3.3 Functional properties |
|
|
225 | (1) |
|
13.3.3.1 Hydrophobic paper |
|
|
225 | (1) |
|
13.3.3.2 Antimicrobial paper |
|
|
225 | (1) |
|
13.3.3.3 Conductive paper |
|
|
226 | (1) |
|
|
226 | (7) |
|
|
227 | (6) |
|
14 Industrial Point of View of Nanocellulose Materials and Their Possible Applications |
|
|
233 | (20) |
|
|
|
|
233 | (1) |
|
14.2 The emergence of nanocellulose materials |
|
|
234 | (1) |
|
14.3 Cellulose nanocrystals |
|
|
235 | (3) |
|
14.3.1 Today's CNC players |
|
|
235 | (1) |
|
14.3.2 Production process issues |
|
|
235 | (2) |
|
|
237 | (1) |
|
14.3.4 Environmental and regulation issues |
|
|
237 | (1) |
|
|
237 | (1) |
|
14.3.6 Main possible applications and industrial end users |
|
|
237 | (1) |
|
14.4 Cellulose nanofibers |
|
|
238 | (5) |
|
14.4.1 Today players and production perspectives |
|
|
240 | (3) |
|
14.5 Possible applications and industrial users |
|
|
243 | (5) |
|
|
244 | (1) |
|
|
245 | (1) |
|
14.5.3 Films and aerogels |
|
|
246 | (1) |
|
14.5.4 Challenges for industrial applications |
|
|
247 | (1) |
|
14.6 Perspectives and challenges of the nanocellulose industries |
|
|
248 | (5) |
|
|
249 | (4) |
Index |
|
253 | |