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E-grāmata: Handbook of Natural Colorants [Wiley Online]

Edited by (Institute for Textile Chemistry), Edited by (Textile Chemistry)
  • Formāts: 440 pages
  • Sērija : Wiley Series in Renewable Resource
  • Izdošanas datums: 17-Apr-2009
  • Izdevniecība: John Wiley & Sons Inc
  • ISBN-10: 470744979
  • ISBN-13: 9780470744970
Citas grāmatas par šo tēmu:
  • Wiley Online
  • Cena: 205,73 €*
  • * this price gives unlimited concurrent access for unlimited time
  • Formāts: 440 pages
  • Sērija : Wiley Series in Renewable Resource
  • Izdošanas datums: 17-Apr-2009
  • Izdevniecība: John Wiley & Sons Inc
  • ISBN-10: 470744979
  • ISBN-13: 9780470744970
Citas grāmatas par šo tēmu:
Concentration on renewable resources, sustainability and replacement of oil based products are driving forces to reassess the potential of natural resources including natural colorants. The growing consumer interest in purchasing “green” products, which exhibit an improved environmental profile, can be seen as the break-through force needed to reintroduce natural colorants into the modern markets.

Written by scientists with specialised knowledge in the field, Handbook of Natural Colorants provides a unique source of information, summarising the present knowledge of natural colorants in depth. Supporting researchers in this emerging field of sustainable chemistry, it provides easy access to the theory and practice of natural colorants from different viewpoints, including agricultural, economic and legislative aspects.

Topics covered include:

  • History of coloration technology
  • Present position of natural colorants
  • Regional plant source availability
  • Specific application techniques
  • Chemical properties that professional dyers and chemists have to consider
  • Agricultural sourcing of dyes with an emphasis on renewable resources
  • Discussions on energy and material balance issues arising from the sourcing of  materials
  • Production aspects of colorants, leading on to the key applications
  • Environmental and economic aspects

Also included are the pros and cons of natural dyestuffs, presenting some promising results and evaluating the potential use of vegetable dyes as alternatives to chemical-based ones with a focus on green chemistry

List of Contributors
xv
Series Preface xix
Preface xxi
Part I Historical Aspects
1(36)
History of Natural Dyes in the Ancient Mediterranean World
3(18)
Maria J. Melo
Introduction
3(3)
Ancient Mediterranean World
3(1)
Dyes from Antiquity
4(1)
Unveiling the Secrets of Ancient Dyes with Modern Science
5(1)
Ancient Reds
6(4)
Anthraquinone Reds
6(2)
Redwoods
8(1)
Flavylium/Anthocyanin Reds
8(2)
Ancient Blues
10(3)
Indigo Blues
10(2)
Anthocyanin Blues
12(1)
Ancient Purple (Tyrian Purple)
13(2)
Ancient Yellows
15(2)
Flavonoid Yellows
15(2)
Carotenoid Yellows
17(1)
Chalcone and Aurone Yellows
17(1)
Acknowledgement
17(1)
References
17(4)
Colours in Civilizations of the World and Natural Colorants: History under Tension
21(6)
Dominique Cardon
Introduction
21(1)
The Triumph of Mauvein: Synthetic Fulfilment of the Antique Purplemania
22(1)
Blue: from Kingly Regional to Globally Democratic
23(1)
Red and Yellow: from Micro to Macro Scales
24(1)
What Future for Natural Colorants in the Dawning Era of Renewable Resources?
25(2)
Acknowledgement
26(1)
References
26(1)
History of Natural Dyes in North Africa `Egypt'
27(10)
Harby Ezeldeen Ahmed
Introduction
27(1)
Natural Dyes in Pharaonic Textiles
28(1)
Dyeing Techniques
28(1)
Dye Sources
29(2)
Woad
29(1)
Indigo
30(1)
Red
30(1)
Yellow
30(1)
Black
31(1)
Brown
31(1)
Green
31(1)
Purple
31(1)
Dyeing in Coptic Textiles
31(2)
Wool Dyed Fabric with Natural Dye
33(1)
Dyes in Islamic Textiles
33(1)
Mordants
34(3)
References
36(1)
Part II Regional Aspects of Availability of Plant Sources
37(36)
Dye Plants in Europe
39(14)
Andrea Biertumpfel
Gunter Wurl
Introduction
39(1)
Potential European Dye Plants
39(1)
Cultivation of Dye Plants Yesterday and Now
40(1)
Modern Cultivation Methods for Important European Dye Plants
41(7)
General Facts
41(1)
Blue Dyeing Plants
42(1)
Red Dyeing Plants
43(1)
Yellow Dyeing Plants
44(2)
Brown Dyeing Plants
46(2)
Production of Dye Extracts
48(2)
Relevant Examples for the Application
50(1)
Conclusions, Discussion and Summary
50(3)
References
51(2)
Dyes in South America
53(12)
Veridiana Vera de Rosso
Adriana Zerlotti Mercadante
Introduction
53(2)
Annatto
55(2)
Turmeric
57(2)
Marigold
59(1)
Cochineal and Carmine
60(5)
Acknowledgements
62(1)
References
62(3)
Natural Dyes in Eastern Asia (Vietnam and Neighbouring Countries)
65(8)
Hoang Thi Linh
Introduction
65(1)
Annatto (Botanical Name Bixa orellana L., Family Bixaceae)
65(2)
Tea (Botanical Name Camellia sinensis (L.) Kuntze, Family Theaceae)
67(1)
Umbrella Tree (Botanical Name Terminalia catappa L., Family Combretaceae)
67(1)
Diospyros mollis - Mackloeur (Botanical Name Diospyros mollis L. Griff, Family Ebenaceae)
68(1)
Indigo (Botanical Name Indigofera L., Family Fabaceae)
68(1)
Indigofera tinctoria L.
68(1)
Indigofera galegoides DC.
69(1)
Strobilanthes cusia (Baphicacanthus)
69(1)
Henna (kok khan, or khao youak in Laos) (Botanical Name Lawsonia spinosa L., Family Lythraceae)
69(1)
Nacre (Botanical Name Khaya senegalensis, Family Meliaceae)
69(1)
Sappan Wood (Botanical Name Caesalpinia sappan L., Family Fabaceae)
69(1)
Sophora japonica Flowers (Botanical Name Sophora japonica L., Family Leguminosae)
70(1)
Turmeric (Botanical Name Curcuma longa L., Family Zingiberaceae)
70(1)
Sapodilla (Botanical Name Manilkara zapota L. or Achras zapota, Family Sapotaceae)
70(1)
Betel (Botanical Name Piper betle L., Family Piperaceae)
71(1)
Eucalyptus (Botanical Name Eucalyptus, Family Myrtaceae)
71(1)
Caesalpinia Yellow (Botanical Name Caesalpinia pulcherrima L., Family Fabaceae)
71(1)
Brow-tuber (Botanical Name Dioscorea cirrhosa Lour, Family Dioscoreaceae)
71(2)
Part III Colorant Production and Properties
73(182)
Indigo - Agricultural Aspects
75(30)
Philip John
Luciana Gabriella Angelini
Introduction
75(1)
Isatis
76(16)
Introduction
76(1)
Agronomy
77(15)
Persicaria (Polygonum)
92(9)
Introduction
92(1)
Agronomy
93(8)
Indigofera
101(4)
Acknowledgements
103(1)
References
103(2)
Indigo - Extraction
105(30)
Philip John
Introduction
105(1)
Methods of Determining Indigo
106(2)
Precursors in the Plants and Indigo Formation
108(6)
Extraction Procedures
114(12)
Traditional Process Using Crushed Leaf Material
114(3)
Steeping in Water
117(9)
Purity of Natural Indigo
126(9)
Acknowledgements
130(1)
References
130(5)
Anthocyanins: Nature's Glamorous Palette
135(16)
Maria J. Melo
Fernando Pina
Claude Andary
Chemical Basis
135(7)
Chemical Structures
135(2)
Equilibria in Solution
137(3)
Colour and Colour Stability
140(1)
Anthocyanins as Antioxidants
141(1)
Natural Sources for Anthocyanins
142(2)
Plant Sources, Content, Influencing Parameters
142(2)
Applications
144(2)
Food Colorants
144(1)
Other Uses
145(1)
Examples of Commercial Products and Processing
146(5)
References
147(4)
Natural Colorants - Quinoid, Naphthoquinoid and Anthraquinoid Dyes
151(32)
Thomas Bechtold
Introduction
151(1)
Benzoquinone Dyes
151(1)
Naphthoquinone Dyes
152(5)
Lawson (2-hydroxy-1,4-naphthoquinone, CI Natural Orange 6)
153(3)
Juglone (5-hydroxy-1,4-naphthoquinone, CI Natural Brown 7)
156(1)
Anthraquinone Dyes
157(14)
Main Components Emodin and Chrysophanol - Rheum Species and Rumex Species
157(2)
Main Components Alizarin and/or Pseudopurpurin/Purpurin
159(12)
Other Sources of Anthraquinoid Dyes
171(12)
References
171(12)
Dyes from Lichens and Mushrooms
183(18)
Riikka Raisanen
Use of Lichen and Mushroom Dyes in the Past
183(1)
Cultivation of Lichens and Mushrooms
184(1)
Dyestuffs in Lichens and Mushrooms
185(12)
Lichen Dyestuffs: Orchils and Litmus
185(6)
Yellowish, Brownish and Reddish Colorants from Lichen
191(1)
Benzoquinone Derivatives
192(1)
Anthraquinones
192(4)
Other Colorants of Fungi
196(1)
Colour-fastness of Lichen and Mushroom Dyes
197(1)
New Approaches to Lichen and Fungal Natural Dyes
198(3)
References
198(3)
Tannins and Tannin Agents
201(20)
Riitta Julkunen-Tiitto
Hely Haggman
Introduction
201(2)
Chemical Structure, Biosynthesis and Degradation
203(4)
Properties of Tannins
207(1)
Chemical Activities of Tannins
208(1)
Analysis of Tannins
209(3)
Sample Preservation
209(1)
Extraction and Purification
209(1)
Quantification of Tannins
210(2)
Use, Toxicology and Safety Aspects of Tannins
212(9)
References
214(7)
Carotenoid Dyes - Properties
221(16)
U. Gamage Chandrika
Introduction
221(4)
Occurrence of Carotenoids
221(1)
Chemistry of Carotenoids
221(1)
Chemical Characteristics of Natural Carotenoids
222(3)
Properties and Functions of Carotenoids
225(3)
Carotenoids Role as Pro-vitamin A
225(2)
Use of Carotenoids as Markers of Dietary Practices
227(1)
Carotenoids as Antioxidants
227(1)
Carotenoids in the Macular Region of the Retina
227(1)
Carotenoids as Anticancer Agent
228(1)
Carotenoids as a Natural Colorant
228(1)
General Procedure for Carotenoid Analysis
228(5)
Sampling
228(2)
Extraction
230(1)
Saponification of Carotenoids
230(1)
Chromatographic Separation
230(1)
Chemical Tests
231(1)
Detection and Identification of Carotenoids
231(2)
Quantification of Carotenoids
233(1)
Problems in Carotenoid Analysis
233(4)
References
234(3)
Carotenoid Dyes - Production
237(6)
U. Gamage Chandrika
Factors Influencing Carotenoid Composition in Plant Sources
237(6)
Stage of Maturity
237(1)
Cultivar or Varietal Differences
238(1)
Climatic or Geographic Effects
238(1)
Post-harvest Storage and Packing
239(1)
Changes in Processing/Cooking
239(2)
Effect of Agrochemicals
241(1)
References
241(2)
Chlorophylls
243(12)
Ursula Maria Lanfer Marquez
Daniela Borrmann
Introduction
243(1)
Chlorophylls as Colorants
244(3)
Other Applications of Chlorophylls and their Derivatives
247(1)
Chemical Structures and Physicochemical Properties
247(3)
Stability and Analysis
250(1)
Sources, Storage and Handling
250(1)
Purity, Standardization and Quality Control
251(1)
Toxicological and Safety Aspects
252(3)
References
253(2)
Part IV Application in Technical Use and Consumer Products
255(96)
Flavonoids as Natural Pigments
257(20)
M. Monica Giusti
Taylor C. Wallace
Introduction
257(1)
Role of Localized Flavonoids in the Plant
258(1)
General Flavonoid Chemical Structure
258(1)
Biosynthesis of Flavonoids
259(2)
Anthocyanins as Natural Colorants
261(7)
Color Stability
261(1)
Structure
261(2)
Structural Transformation and pH
263(1)
Temperature
264(1)
Oxygen and Ascorbic Acid
264(1)
Light
265(1)
Enzymes and Sugars
265(1)
Sulfur Dioxide
266(1)
Co-pigmentation and Metal Complexation
267(1)
Other Flavonoids as Natural Colorants
268(2)
Yellow Flavonoid Pigments
268(1)
Tannins
269(1)
Therapeutic Effects of Flavonoids in the Diet
270(1)
Regulations on the Use of Flavonoid Colorants
271(6)
References
272(5)
Application of Natural Dyes in the Coloration of Wood
277(38)
Martin Weigl
Andreas Kandelbauer
Christian Hansmann
Johannes Pockl
Ulrich Muller
Michael Grabner
Introduction
277(6)
General Basics
278(4)
Color Measurement
282(1)
Color Stability
283(1)
Coatings
283(2)
Dyes
285(5)
Dyeing for Analytical Purposes
285(1)
Impregnation
286(4)
Color Modification
290(18)
Drying
291(4)
Steaming
295(2)
Thermal Treatment
297(1)
Ammoniation
298(3)
Bleaching
301(2)
Enzymatic Treatment
303(2)
Radiation
305(3)
Outlook
308(7)
References
308(7)
Natural Colorants in Textile Dyeing
315(24)
Rita A. M. Mussak
Thomas Bechtold
Introduction
315(1)
Reasons for Natural Coloration
316(1)
Analysis of a Dyeing Process
317(4)
Water
318(1)
Energy
318(1)
Dyestuff and Chemicals (Mordants and Auxiliaries)
319(2)
Machinery
321(1)
Basics of Natural Dyeings
321(11)
Requirements of the Dyestuff
321(1)
Dye-ability of Substrates
321(5)
Standardization of the Dyestuff
326(1)
Ecological Aspects
327(1)
Aspects of Application
328(1)
Dyeing Technology
329(1)
Mordanting
330(1)
Standardization of the Coloration Process
331(1)
Mixtures of Plant Material
331(1)
Natural Dyes on an Industrial Scale
332(2)
Hank Dyeing of Woolen Yarn and Production of Woolen Caps
332(1)
Dyeing of Cones in a Yarn Dyeing Machine
333(1)
Dyeing of Cotton Fabric on a Jet Dyeing Machine
333(1)
Dyeing of Cotton Fabric on a Jig Dyeing Machine
333(1)
Fabric Dyeing on a Garment Dyeing Machine
333(1)
Dyeing of Polyamide Tights in a Paddle Dyeing Machine
334(1)
Conclusion
334(5)
Acknowledgment
334(1)
References
335(4)
Natural Colorants in Hair Dyeing
339(12)
Thomas Bechtold
Introduction
339(1)
Human Hair
340(1)
General Requirements on Hair Dyeing Concepts
340(1)
Chemical Principles of Dyestuff Binding
341(1)
Relevant Natural Dyes for Hair Dyeing
342(5)
Naphthoquinone Dyes - Henna and Walnut
342(1)
Indigo
343(2)
Metal Complexes
345(1)
Metal Reaction Dyes
346(1)
Anthraquinoid Dyes
347(1)
Specialities
347(1)
Regulations
347(4)
References
347(4)
Part V Environmental
351(34)
Environmental Aspects and Sustainability
353(14)
Erika Ganglberger
Introduction
353(1)
Supply of Plant Material
354(3)
Cultivation of Dye Plants
354(1)
Residual Materials and By-products
355(1)
Selection Process for a Sustainable Supply of Plant Material
356(1)
Processing to Dyestuff
357(3)
Energy Consumption
358(1)
Water Consumption
359(1)
Application of Colouring Matter
360(1)
Dyeing Procedure
361(1)
Considerations Concerning the Life Cycle
361(3)
Raw Material
361(1)
Processing of Raw Material
362(1)
Extraction of Dyestuff
362(1)
Dyeing Procedure
363(1)
Transport
363(1)
Conclusion
364(3)
Dealing with Sustainability
364(1)
References
365(2)
Economic Aspects of Natural Dyes
367(18)
Susanne Geissler
Introduction
367(1)
Basic Requirements for the Industrial Use of Natural Colorants
368(2)
Challenges for the Industrial Use of Natural Colorants
370(1)
Quality of Raw Material and Reproducibility of Colours
370(1)
Range of Available Colours
370(1)
Consumer Expectations
371(4)
Market Research for Naturally Dyed Products
372(3)
Production Costs of Natural Colorant Products
375(6)
Cost Categories
375(1)
Aspects Influencing Production Costs
376(2)
Prices of Synthetic Dyes - How Much Are Textile Companies Prepared to Pay for Dyes?
378(1)
Acceptable Production Costs through a Mixed Portfolio (Agricultural Primary Production and Residues from Other Production Processes)
379(2)
Closed-Loop Economy: Towards a Zero-Emission and Zero-Waste Society
381(1)
Conclusion: Aspects Influencing Market Development for Natural Colorants
382(3)
References
383(2)
Index 385
Dr Thomas Bechtold is Head of the Institute for Textile Chemistry and Textile Physics at the Leopold-Franzens University of Innsbruck, Austria. His key research interests are: dyeing with vat, indigo and sulfur dyes; electrochemistry in textile processes; formulation of special detergents. He has published over 70 papers in this research field in the last 20 years. Dr Rita Mussak is based in the Department of Theoretical Chemistry at the Leopold-Franzens University of Innsbruck, Austria.