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Chapter 1 Introduction and background |
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1 | (14) |
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1.1 Primary energy sources - fossil fuels |
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1 | (1) |
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1.2 Renewable energy resources |
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2 | (1) |
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1.3 Conclusion energy sources |
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3 | (1) |
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3 | (1) |
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1.5 Electrochemical devices |
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4 | (2) |
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6 | (2) |
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8 | (2) |
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10 | (1) |
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10 | (3) |
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13 | (1) |
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13 | (2) |
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Chapter 2 Electrochemistry and thermodynamics |
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15 | (22) |
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15 | (1) |
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2.2 The electrochemical cell |
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15 | (2) |
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17 | (6) |
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2.3.1 First law of thermodynamics |
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18 | (1) |
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2.3.2 Enthalpy of formation h***of |
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19 | (1) |
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19 | (1) |
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20 | (1) |
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2.3.5 The Faraday's laws in electrochemistry |
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20 | (1) |
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21 | (1) |
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2.3.7 The Nernst equation |
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21 | (2) |
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2.4 The electrical double layer and electrode kinetics |
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23 | (2) |
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2.5 Polarization curve and overpotential |
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25 | (3) |
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26 | (1) |
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27 | (1) |
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2.5.3 Mass transport loss or concentration loss |
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27 | (1) |
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2.5.4 Internal current and crossover |
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27 | (1) |
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2.5.5 Cell voltage under load |
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28 | (1) |
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28 | (3) |
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2.6.1 Modes of heat transfer |
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28 | (3) |
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31 | (2) |
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33 | (2) |
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2.8.1 Governing equations of transport in porous media |
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35 | (1) |
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35 | (2) |
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37 | (20) |
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37 | (1) |
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3.2 Properties of hydrogen |
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38 | (1) |
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3.3 Production of hydrogen |
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39 | (5) |
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39 | (1) |
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3.3.2 Gasification of coal and biomass |
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40 | (1) |
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3.3.3 Electrolysis of water |
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41 | (2) |
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3.3.4 Thermochemical water splitting and thermolysis |
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43 | (1) |
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3.3.5 Photoelectrochemical water splitting |
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43 | (1) |
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3.3.6 Thermocatalytic cracking |
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44 | (1) |
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3.3.7 Roadmap for hydrogen production |
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44 | (1) |
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44 | (7) |
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45 | (1) |
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46 | (1) |
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3.4.3 Cryo-compressed storage |
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47 | (1) |
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47 | (4) |
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3.5 Transportation of hydrogen |
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51 | (1) |
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3.6 Pros and cons for hydrogen |
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52 | (1) |
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3.6.1 Pros of hydrogen energy |
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52 | (1) |
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3.6.2 Cons of hydrogen energy |
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52 | (1) |
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53 | (1) |
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54 | (3) |
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Chapter 4 Battery technologies |
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57 | (24) |
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57 | (2) |
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59 | (2) |
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4.3 Nickel-metal hydride batteries |
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61 | (1) |
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62 | (3) |
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4.4.1 Lithium metal batteries |
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62 | (1) |
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4.4.2 Lithium-ion and lithium-ion polymer batteries |
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63 | (1) |
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4.4.3 Lithium-oxygen batteries |
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64 | (1) |
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4.4.4 Lithium-sulfur batteries |
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65 | (1) |
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4.5 Nickel-zinc batteries |
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65 | (1) |
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4.6 Zinc-carbon batteries |
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66 | (2) |
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68 | (1) |
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69 | (1) |
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4.8.1 Redox flow batteries |
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69 | (1) |
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4.9 Voltage characteristics |
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70 | (2) |
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4.10 Standards and nomenclature |
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72 | (5) |
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75 | (2) |
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77 | (1) |
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78 | (1) |
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79 | (2) |
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Chapter 5 Transport phenomena in batteries |
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81 | (12) |
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81 | (2) |
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5.2 Electrolyte charge conservation |
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83 | (1) |
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5.2.1 Boundary conditions |
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83 | (1) |
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5.3 Electrolyte species conservation |
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83 | (1) |
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5.3.1 Boundary conditions |
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84 | (1) |
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5.4 Electrode charge conservation |
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84 | (1) |
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5.4.1 Boundary conditions |
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85 | (1) |
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5.5 Electrode species conservation |
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85 | (1) |
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5.5.1 Initial and boundary conditions |
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86 | (1) |
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5.5.2 Effective properties |
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86 | (1) |
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86 | (1) |
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87 | (1) |
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5.7.1 Heat generation mechanism |
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87 | (1) |
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5.7.2 Heat conduction equation |
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88 | (1) |
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88 | (1) |
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88 | (1) |
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89 | (1) |
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90 | (3) |
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Chapter 6 Thermal management of batteries |
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93 | (18) |
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93 | (2) |
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6.1.1 State functions (SOF) |
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94 | (1) |
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6.1.2 State of charge (SOC) |
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94 | (1) |
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6.1.3 State of health (SOH) |
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95 | (1) |
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95 | (1) |
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6.3 Importance of temperature |
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96 | (2) |
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6.4 Examples of thermal management systems |
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98 | (5) |
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98 | (1) |
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99 | (2) |
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6.4.3 Cooling by phase change material (PCM) |
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101 | (2) |
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6.4.4 Drawbacks of thermal management systems |
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103 | (1) |
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6.5 Mathematical modeling and experimental approaches |
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103 | (5) |
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6.5.1 Simple energy balance of a battery |
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104 | (1) |
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6.5.2 Energy balance of a non-isothermal battery |
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105 | (1) |
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6.5.3 Governing equations for convective cooling of a battery pack |
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105 | (1) |
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106 | (1) |
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6.5.5 Multi-scale multi-dimensional modeling |
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107 | (1) |
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108 | (1) |
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109 | (1) |
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109 | (2) |
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Chapter 7 Applications of batteries |
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111 | (12) |
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111 | (1) |
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112 | (1) |
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7.3 Battery types for electric vehicles |
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113 | (4) |
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7.3.1 Lead acid batteries and nickel metal hydride batteries (NiMH) |
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113 | (1) |
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7.3.2 Lithium-ion batteries |
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114 | (1) |
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7.3.3 Estimation of the weight of a long haulage truck |
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115 | (1) |
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7.3.4 Batteries for commercial vehicles |
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116 | (1) |
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7.4 Batteries for aviation |
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117 | (1) |
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7.5 Batteries for aerospace |
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118 | (1) |
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7.6 Batteries in shipping and marine applications |
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118 | (1) |
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119 | (1) |
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7.8 Grid storage batteries |
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120 | (1) |
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7.9 Bottlenecks of batteries |
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120 | (1) |
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121 | (1) |
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122 | (1) |
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Chapter 8 Fuel cell types - overview |
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123 | (22) |
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123 | (4) |
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8.1.1 Types of fuel cells |
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124 | (1) |
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8.1.2 Proton exchange membrane fuel cells (PEMFC) or polymer electrolyte fuel cells (PEFC) |
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124 | (2) |
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8.1.3 Alkaline fuel cells (AFC) |
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126 | (1) |
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8.1.4 Phosforic acid fuel cells (PAFC) |
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126 | (1) |
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8.1.5 Solid oxide fuel cells (SOFC) |
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126 | (1) |
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8.1.6 Molten carbonate fuel cells (MCFC) |
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126 | (1) |
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8.1.7 Direct methanol fuel cells (DMFC) |
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127 | (1) |
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8.1.8 Reversible fuel cells |
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127 | (1) |
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8.1.9 Proton ceramic fuel cells |
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127 | (1) |
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8.1.10 Overall summary of characteristics of some fuel cells |
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127 | (1) |
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8.2 Complementary electrochemistry and thermodynamics for fuel cells |
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127 | (5) |
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8.2.1 Influence of pressure on the electrochemistry of fuel cells |
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128 | (1) |
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8.2.2 Effect of gas concentration, Nernst equation |
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128 | (2) |
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8.2.3 Fuel cell reaction involving hydrogen and oxygen |
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130 | (1) |
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8.2.4 Estimations of consumption of fuel and oxidant |
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130 | (2) |
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8.3 Solid oxide fuel cells --- SOFC |
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132 | (5) |
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132 | (1) |
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132 | (2) |
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134 | (1) |
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8.3.4 Performance of SOFCs |
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135 | (1) |
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136 | (1) |
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8.3.6 Detailed structure of a unit cell |
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136 | (1) |
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137 | (1) |
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8.4 Intermediate solid oxide fuel cells --- ITSOFC |
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137 | (2) |
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8.4.1 ITSOFC design options |
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138 | (1) |
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8.4.2 Performance of ITSOFC at reduced temperatures |
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138 | (1) |
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138 | (1) |
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8.5 Proton exchange membrane fuel cells --- PEMFC |
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139 | (3) |
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139 | (1) |
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140 | (1) |
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8.5.3 Detailed structure of a PEMFC unit cell |
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141 | (1) |
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142 | (1) |
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8.5.5 Performance of a PEMFC |
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142 | (1) |
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8.6 Aerospace applications |
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142 | (2) |
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144 | (1) |
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Chapter 9 Transport phenomena in fuel cells |
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145 | (22) |
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145 | (1) |
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9.1.1 Overall description of basic transport processes and operation of a fuel cell |
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145 | (1) |
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9.1.2 Electrochemical kinetics |
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145 | (1) |
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9.1.3 Heat and mass transfer |
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145 | (1) |
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9.1.4 Charge and water transport |
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146 | (1) |
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146 | (7) |
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147 | (1) |
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9.2.2 Conservation of energy and the heat equation |
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148 | (2) |
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9.2.3 One-dimensional thermal analysis of a fuel cell |
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150 | (2) |
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152 | (1) |
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153 | (3) |
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9.3.1 Diffusion mass transfer |
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153 | (1) |
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9.3.2 Convection mass transfer |
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154 | (1) |
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9.3.3 Mass transport of species in fuel cells |
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155 | (1) |
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9.3.4 Convective mass transfer coefficients |
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155 | (1) |
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156 | (4) |
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9.4.1 Charge transport by diffusion |
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156 | (1) |
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9.4.2 Charge transport by convection |
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157 | (1) |
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9.4.3 Charge transport by electrical potential gradient |
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157 | (1) |
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9.4.4 The Nernst-Planck equation |
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157 | (1) |
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9.4.5 Charge transport equations |
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158 | (1) |
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9.4.6 Boundary conditions for the electrical potential |
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159 | (1) |
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9.4.7 Voltage loss by charge transport |
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159 | (1) |
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160 | (3) |
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9.5.1 Water transport in the electrolyte |
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160 | (2) |
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9.5.2 Water transport in gas channels and in gas-diffusion layers |
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162 | (1) |
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162 | (1) |
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9.6 Diffusion coefficients |
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163 | (2) |
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9.6.1 Binary gas mixtures |
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163 | (1) |
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164 | (1) |
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9.6.3 Diffusion in porous solids |
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164 | (1) |
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165 | (2) |
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Chapter 10 Modeling approaches for fuel cells |
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167 | (36) |
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167 | (2) |
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10.2 Zero-order models of analysis |
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169 | (1) |
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10.3 One-dimensional models of analysis |
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170 | (1) |
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10.4 Multi-dimensional models of analysis |
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171 | (8) |
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10.4.1 Computational fluid dynamics (CFD) approaches |
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171 | (6) |
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10.4.2 Porous media approach |
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177 | (2) |
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10.4.3 Molecular dynamics based approaches |
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179 | (1) |
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10.5 Example proton exchange membrane fuel cells --- PEMFC |
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179 | (12) |
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180 | (1) |
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10.5.2 Governing equations |
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180 | (3) |
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10.5.3 Catalyst layer composition and volume fraction |
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183 | (5) |
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10.5.4 Cathode agglomerate model |
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188 | (1) |
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10.5.5 Determination of porosity of the GDLs after compression |
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189 | (1) |
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10.5.6 On numerical implementation and boundary conditions |
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189 | (1) |
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10.5.7 Some characteristics |
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190 | (1) |
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10.6 Example solid oxide fuel cells --- SOFC |
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191 | (6) |
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10.6.1 Transport of fuel and oxidant in channels |
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192 | (1) |
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10.6.2 Transport in the porous electrodes |
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192 | (1) |
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10.6.3 Transport in the solid electrolyte |
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193 | (1) |
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10.6.4 Transport in the interconnects |
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193 | (1) |
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10.6.5 Model of the electrochemical processes |
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194 | (1) |
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194 | (1) |
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10.6.7 Engineering bridges in analysis of multiscale issues |
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194 | (3) |
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197 | (1) |
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197 | (1) |
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198 | (5) |
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Chapter 11 Fuel cell systems and applications |
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203 | (14) |
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203 | (1) |
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203 | (1) |
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204 | (1) |
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204 | (2) |
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206 | (2) |
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11.5 Maritime applications |
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208 | (1) |
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11.6 Aerospace applications |
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209 | (1) |
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11.7 Aircraft applications |
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210 | (1) |
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11.8 Bottlenecks for fuel cells |
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211 | (1) |
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11.9 Current status FCEVs versus BEVs |
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212 | (1) |
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213 | (1) |
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214 | (3) |
Appendices-tables |
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217 | (6) |
Index |
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223 | |