| Foreword |
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1 | (2) |
| Introduction |
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3 | (8) |
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Glass transition of elastomers |
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|
11 | (32) |
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Methods of glass-transition temperature determination |
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11 | (7) |
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Structural and other physical methods |
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11 | (4) |
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15 | (2) |
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Comparison of the data obtained by different methods |
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17 | (1) |
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Modern views of glass transition |
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18 | (10) |
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Kinetic views of glass transition |
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18 | (7) |
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Thermodynamic views of glass transition |
|
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25 | (1) |
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Morphological views of glass transition |
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26 | (2) |
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Effect of the molecular parameters of rubbers and the composition of rubber compounds on glass-transition temperature |
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28 | (13) |
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|
28 | (2) |
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Effect of the structure of macromolecules |
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30 | (2) |
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Effect of intermolecular interaction |
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32 | (1) |
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Glass transition of copolymers |
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33 | (1) |
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Effect of the composition of rubbers |
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34 | (7) |
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Effect of a mechanical action on glass-transition temperature |
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41 | (2) |
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Mechanical properties of elastomers near the glass transition temperature |
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43 | (16) |
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Mechanical properties in the region of transition from the rubberlike to the glassy state |
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43 | (12) |
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Static mechanical properties |
|
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43 | (5) |
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Dynamic mechanical properties |
|
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48 | (4) |
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Prediction of the mechanical properties of elastomers in the transition region from the glassy to the rubberlike state |
|
|
52 | (3) |
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Mechanical properties at temperatures below glass-transition temperature |
|
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55 | (4) |
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Crystallization of elastomers at low temperatures |
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59 | (38) |
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Methods of crystallization studies |
|
|
60 | (3) |
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Structural and other physical methods |
|
|
60 | (3) |
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63 | (1) |
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Modern views of crystallization |
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|
63 | |
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Morphology of crystals in elastomers |
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64 | (1) |
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Kinetics of isothermal crystallization |
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65 | (3) |
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Temperature range of crystallization |
|
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68 | (5) |
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Kinetics of nonisothermal crystallization |
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73 | (1) |
|
|
|
74 | |
|
Effect of mechanical action and oilier factors on crystallization |
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|
19 | (63) |
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Effect of the molecular parameters of rubbers and the composition of rubber compounds on crystallization |
|
|
82 | (9) |
|
|
|
91 | (3) |
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Prediction of the crystallization rate |
|
|
94 | (3) |
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Stress-induced crystallization of elastomers |
|
|
97 | (18) |
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Kinetics of stress-induced crystallization |
|
|
97 | (3) |
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Morphology in stress-induced crystallization |
|
|
100 | (4) |
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Melting of oriented elastomers |
|
|
104 | (4) |
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Effect of the molecular parameters of rubbers and the composition of rubber compounds on stress-induced crystallization |
|
|
108 | (7) |
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Effect of chain chemical structure, molecular mass and microstructure |
|
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108 | (2) |
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Effect of vulcanization and filling |
|
|
110 | (5) |
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Strength properties of elastomers at low temperatures |
|
|
115 | (10) |
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Strength of amorphous elastomers at low temperatures |
|
|
115 | (3) |
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Strength of crystallizable elastomers |
|
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118 | (7) |
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Strength determined by stress-induced crystallization |
|
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118 | (4) |
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Effect of precrystallization on the strength at low temperatures |
|
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122 | (3) |
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Contribution of crystallization and glass transition to low-temperature resistance of elastomers |
|
|
125 | (12) |
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Mutual interaction of crystallization and glass transition |
|
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125 | (3) |
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Effect of crystallization on glass transition |
|
|
125 | (3) |
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Crystallization from the glassy state |
|
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128 | (1) |
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The ratio of the contributions by crystallization and glass transition to the low-temperature resistance of elastomers |
|
|
128 | (1) |
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Low-temperature resistance of rubber articles |
|
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129 | (4) |
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Ways to improve the low-temperature resistance of rubber articles |
|
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129 | (2) |
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Assessment of low-temperature resistance of rubber articles from the low-temperature behaviour data for elastomers |
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131 | (2) |
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Effect of repeated exposure to low temperatures on the performance of rubber articles |
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133 | (4) |
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Reversibility of changes due to glass transition and crystallization |
|
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133 | (1) |
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Effect of temperature cycling on the performance of rubber articles |
|
|
133 | (4) |
|
Low-temperature resistance specifics of particular elastomers |
|
|
137 | (20) |
|
Styrene-butadiene rubbers |
|
|
137 | (2) |
|
Butadiene acrylonitrile rubbers |
|
|
139 | (1) |
|
|
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140 | (2) |
|
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|
142 | (2) |
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144 | (2) |
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146 | (1) |
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147 | (2) |
|
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149 | (1) |
|
|
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150 | (1) |
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|
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151 | (1) |
|
|
|
151 | (1) |
|
Ethylene-propylene rubbers |
|
|
152 | (1) |
|
|
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153 | (1) |
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|
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154 | (1) |
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|
|
155 | (2) |
| References |
|
157 | (26) |
| Subject index |
|
183 | |
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