| Preface |
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xxv | |
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xxvii | |
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Volume 1 Synthetic Techniques |
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Macromolecular Engineering |
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1 | (6) |
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Anionic Polymerization of Vinyl and Related Monomers |
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7 | (50) |
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7 | (1) |
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General Features of Anionic Polymerization |
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8 | (9) |
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Polymerizability of Vinyl and Related Monomers |
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9 | (2) |
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Various Parameters Influencing the Structure and Reactivity of Active Centers |
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11 | (1) |
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Influence of the Type of Monomer |
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12 | (1) |
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Influence of the Nature of Solvent |
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13 | (2) |
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15 | (1) |
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Influence of the Counterion |
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16 | (1) |
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Experimental Constraints Related to Anionic Polymerization |
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17 | (1) |
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Initiation of Anionic Polymerizations |
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17 | (13) |
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Initiation by Electron Transfer |
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18 | (1) |
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Initiation by Nucleophilic Addition to the Double Bond |
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19 | (1) |
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19 | (2) |
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21 | (4) |
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Bi- and Multifunctional Initiators |
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25 | (4) |
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Initiation by Alkoxides and Silanolates |
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29 | (1) |
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Initiation of the Polymerization of Alkyl (Meth)acrylates by Group Transfer |
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29 | (1) |
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30 | (12) |
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Kinetics of the Propagation Step |
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31 | (1) |
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Kinetics of Polymerization in Non-polar Solvents |
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31 | (3) |
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Polymerizations Carried Out in Polar Media |
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34 | (2) |
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Anionic Polymerization of (Meth)acrylic Monomers |
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36 | (1) |
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36 | (1) |
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Propagation by Group Transfer |
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37 | (1) |
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38 | (1) |
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Regio- and Stereoselectivity in Anionic Polymerization |
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39 | (1) |
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Cases of Conjugated Dienes |
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39 | (1) |
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Case of Vinyl and Related Monomers |
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40 | (2) |
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Persistence of Active Centers |
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42 | (3) |
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Case of Polystyrenic Carbanions |
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43 | (1) |
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Case of Polydiene Carbanions |
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44 | (1) |
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Case of (Meth)acrylic Polymers |
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44 | (1) |
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Application of Anionic Polymerization to Macromolecular Synthesis |
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45 | (12) |
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Prediction of Molar Masses and Control of Their Dispersion |
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46 | (1) |
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Functionalization of Chain Ends |
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46 | (1) |
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Synthesis of Graft and Block Copolymers |
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47 | (1) |
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48 | (1) |
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49 | (1) |
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50 | (7) |
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Carbocationic Polymerization |
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57 | (46) |
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57 | (1) |
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Mechanistic and Kinetic Details of Living Cationic Polymerization |
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58 | (2) |
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Living Cationic Polymerization |
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60 | (1) |
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Monomers and Initiating Systems |
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61 | (1) |
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Additives in Living Cationic Polymerization |
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61 | (9) |
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62 | (2) |
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64 | (1) |
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65 | (1) |
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65 | (1) |
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66 | (1) |
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2,4,6-Trimethylstyrene (TMeSt) |
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66 | (1) |
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p-Methoxystyrene (p-MeOSt) |
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66 | (1) |
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67 | (1) |
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67 | (1) |
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68 | (1) |
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68 | (2) |
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Functional Polymers by Living Cationic Polymerization |
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70 | (4) |
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Functional Initiator Method |
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70 | (2) |
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Functional Terminator Method |
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72 | (2) |
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74 | (2) |
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76 | (4) |
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Synthesis Using a Functional Initiator |
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76 | (2) |
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Synthesis Using a Functional Capping Agent |
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78 | (2) |
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80 | (1) |
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80 | (13) |
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Linear Diblock Copolymers |
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81 | (3) |
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Linear Triblock Copolymers |
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84 | (1) |
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Synthesis Using Difunctional Initiators |
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84 | (1) |
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Synthesis Using Coupling Agents |
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85 | (1) |
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Block Copolymers with Nonlinear Architecture |
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86 | (1) |
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Synthesis of AnBn Hetero-arm Star-block Copolymers |
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87 | (1) |
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Synthesis of AA'B, ABB' and ABC Asymmetric Star-block Copolymers Using Furan Derivatives |
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87 | (2) |
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Block Copolymers Prepared by the Combination of Different Polymerization Mechanisms |
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89 | (1) |
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Combination of Cationic and Anionic Polymerization |
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89 | (1) |
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Combination of Living Cationic and Anionic Ring-opening Polymerization |
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90 | (2) |
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Combination of Living Cationic and Radical Polymerization |
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92 | (1) |
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Branched and Hyperbranched Polymers |
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93 | (1) |
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Surface-initiated Polymerization: Polymer Brushes |
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94 | (1) |
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94 | (9) |
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95 | (8) |
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Ionic and Coordination Ring-opening Polymerization |
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103 | (58) |
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103 | (3) |
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Thermodynamics of Ring-opening Polymerization |
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106 | (3) |
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Equilibrium Monomer Concentration -- Ceiling/Floor Temperatures |
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106 | (1) |
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Recent Results Related to Thermodynamics of Ring-opening Polymerization |
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107 | (1) |
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Thermodynamics of γ-Butyrolactone (Co)polymerization |
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107 | (1) |
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Copolymerization of Lactide at the Polymer--Monomer Equilibrium |
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108 | (1) |
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Basic Mechanistic Features of Ring-opening Polymerization |
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109 | (37) |
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Anionic and Coordination Ring-opening Polymerization of Cyclic Ethers and Sulfides |
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109 | (1) |
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Initiators and Initiation |
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109 | (1) |
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Active Centers -- Structures and Reactivities |
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110 | (1) |
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Controlled Anionic and Coordination Polymerization of Oxiranes |
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111 | (2) |
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Stereocontrolled Polymerization of Chiral Oxiranes |
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113 | (1) |
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Controlled Synthesis of Aliphatic Polyesters by Anionic and Coordination Ring-opening Polymerization |
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114 | (1) |
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Initiators and Active Centers -- Structures and Reactivities |
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114 | (4) |
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Controlled Polymerization of Cyclic Esters with ``Multiple-site'' Metal Alkoxides and Carboxylates |
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118 | (3) |
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Controlled Polymerization of Cyclic Esters with ``Single-site'' Metal Alkoxides |
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121 | (1) |
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Poly(β-hydroxybutyrate)s by Carbonylation of Oxiranes |
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121 | (1) |
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Stereocontrolled Polymerization of Chiral Cyclic Esters |
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122 | (4) |
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Stereocomplexes of Aliphatic Polyesters |
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126 | (1) |
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Controlled Synthesis of Aliphatic Polycarbonates by Anionic and Coordination Ring-opening Polymerization |
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127 | (2) |
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Controlled Synthesis of Branched and Star-shaped Polyoxiranes and Polyesters |
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129 | (1) |
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Anionic Polymerization of Oxiranes |
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129 | (2) |
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Coordination Polymerization of Cyclic Esters |
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131 | (1) |
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Controlled Synthesis of Polyamides by Anionic and Coordination Ring-opening Polymerization |
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132 | (1) |
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Polymerization of Lactams |
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132 | (2) |
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Polymerization of N-Carboxyanhydrides of α-Amino Acids (NCAs) |
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134 | (2) |
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Cationic Ring-opening Polymerization |
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136 | (1) |
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Propagation in Cationic Ring-opening Polymerization |
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137 | (1) |
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Chain Transfer to Polymer in Cationic Ring-opening Polymerization |
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138 | (2) |
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Activated Monomer Mechanism in Cationic Ring-opening Polymerization of Cyclic Ethers and Esters |
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140 | (4) |
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Branched and Star-shaped Polymers Prepared by Cationic Ring-opening Polymerization |
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144 | (1) |
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Cationic Polymerization of Cyclic Imino Ethers (Oxazolines) |
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145 | (1) |
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Dispersion Ring-opening Polymerization |
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146 | (3) |
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149 | (12) |
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150 | (11) |
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161 | (56) |
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161 | (1) |
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Typical Features of Radical Polymerization |
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162 | (9) |
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Fundamentals of Organic Radicals |
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162 | (1) |
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Elementary Reactions and Kinetics |
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163 | (2) |
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165 | (1) |
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166 | (1) |
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166 | (2) |
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168 | (1) |
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Typical Conditions for RP |
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168 | (1) |
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Commercially Important Polymers by RP |
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169 | (1) |
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169 | (1) |
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169 | (1) |
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Poly(vinyl chloride) (PVC) |
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170 | (1) |
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170 | (1) |
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170 | (1) |
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Controlled/Living Radical Polymerization |
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171 | (2) |
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171 | (1) |
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Similarities and Differences Between RP and CRP |
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172 | (1) |
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SFRP and NMP Systems -- Examples and Peculiarities |
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173 | (3) |
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174 | (1) |
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175 | (1) |
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175 | (1) |
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175 | (1) |
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ATRP -- Examples and Peculiarities |
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176 | (6) |
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177 | (1) |
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177 | (1) |
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178 | (1) |
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Transition Metal Complexes as ATRP Catalysts |
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179 | (1) |
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180 | (2) |
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182 | (1) |
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Degenerative Transfer Processes and RAFT |
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182 | (3) |
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184 | (1) |
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185 | (1) |
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185 | (1) |
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Relative Advantages and Limitations of SFRP, ATRP and DT Processes |
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185 | (2) |
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186 | (1) |
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186 | (1) |
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RAFT and Other DT Processes |
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186 | (1) |
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Controlled Polymer Architectures by CRP: Topology |
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187 | (6) |
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188 | (1) |
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188 | (1) |
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189 | (2) |
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Branched and Hyperbranched Polymers |
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191 | (1) |
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192 | (1) |
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Polymer Networks and Microgels |
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192 | (1) |
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192 | (1) |
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193 | (7) |
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193 | (1) |
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Segmented Copolymers (Block, Grafts and Multisegmented Copolymers) |
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193 | (1) |
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Block Copolymers by a Single CRP Method |
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193 | (1) |
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Block Copolymers by Combination of CRP Methods |
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194 | (1) |
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Block Copolymerization by Site Transformation and Dual Initiators |
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195 | (1) |
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Multisegmented Block Copolymers |
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196 | (1) |
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197 | (1) |
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197 | (2) |
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199 | (1) |
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199 | (1) |
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199 | (1) |
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200 | (1) |
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200 | (3) |
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Polymers with Side Functional Groups |
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201 | (1) |
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End-group Functionality: Initiators |
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202 | (1) |
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End-group Functionality Through Conversion of Dormant Chain End |
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202 | (1) |
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Applications of Materials Prepared by CRP |
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203 | (2) |
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Polymers with Controlled Compositions |
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204 | (1) |
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Polymers with Controlled Topology |
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204 | (1) |
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Polymers with Controlled Functionality |
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204 | (1) |
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205 | (1) |
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205 | (12) |
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205 | (1) |
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206 | (1) |
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207 | (1) |
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Structure--Property Relationship |
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207 | (1) |
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207 | (1) |
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208 | (9) |
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Coordination Polymerization: Synthesis of New Homo- and Copolymer Architectures from Ethylene and Propylene using Homogeneous Ziegler--Natta Polymerization Catalysts |
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217 | (32) |
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Introduction, Historical Perspective and Scope of Review |
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217 | (1) |
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Primer on the Homogeneous Coordination Polymerization of Olefins |
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218 | (4) |
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Nature of the Active Species and Mechanism of Initiation |
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218 | (1) |
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219 | (1) |
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Mechanisms of Termination and Chain Transfer |
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220 | (2) |
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222 | (2) |
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224 | (11) |
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Atactic, Isotactic and Syndiotactic Polypropylene |
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224 | (2) |
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Hemiisotactic Polypropylene |
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226 | (1) |
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Stereoblock Polypropylene |
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226 | (7) |
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Graft and Star Polypropylene |
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233 | (2) |
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Ethylene--Propylene Copolymers |
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235 | (7) |
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Random Ethylene--Propylene Copolymers |
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235 | (1) |
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Alternating Ethylene--Propylene Copolymers |
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235 | (3) |
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Ethylene--Propylene Block Copolymers |
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238 | (3) |
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Ethylene--Propylene Graft Copolymers |
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241 | (1) |
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242 | (7) |
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243 | (6) |
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Recent Trends in Macromolecular Engineering |
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249 | (46) |
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249 | (1) |
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The March Towards Well-defined/Selective Catalysts for ROMP |
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250 | (7) |
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Discovery of Olefin Metathesis and its Mechanism |
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250 | (2) |
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Development of Well-defined ROMP Initiators |
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252 | (5) |
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Macromolecular Engineering Using ROMP |
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257 | (16) |
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Block Copolymers by ROMP and Combination of ROMP with Other ``Living'' Polymerizations |
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258 | (4) |
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Graft Copolymers by ROMP with Other ``Living'' Polymerizations |
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262 | (1) |
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262 | (1) |
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Anionic Polymerization/ROMP |
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263 | (2) |
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Cationic Polymerization/ROMP |
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265 | (1) |
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265 | (1) |
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266 | (1) |
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267 | (1) |
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268 | (5) |
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273 | (7) |
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274 | (2) |
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276 | (1) |
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277 | (1) |
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278 | (2) |
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Advanced Materials by ROMP |
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280 | (10) |
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Liquid Crystalline Polymers |
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280 | (1) |
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Conjugated and Electroactive Polymers |
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281 | (2) |
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283 | (1) |
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284 | (2) |
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286 | (4) |
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Hybrid Materials/Particles |
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290 | (1) |
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290 | (5) |
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290 | (5) |
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295 | (56) |
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Monomer Reactivity Control (Stoichiometric-imbalanced Polycondensation) |
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295 | (8) |
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Polycondensation of α,α-Dihalogenated Monomers |
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296 | (2) |
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Pd-catalyzed Polycondensation |
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298 | (1) |
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Crystallization Polycondensation |
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299 | (3) |
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Nucleation--Elongation Polycondensation |
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302 | (1) |
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303 | (7) |
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Sequential Polymers from Symmetrical and Unsymmetrical Monomers |
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304 | (4) |
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Sequential Polymers from Two Unsymmetrical Monomers |
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308 | (1) |
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Sequential Polymers from Two Symmetrical Monomers and One Unsymmetrical Monomer |
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309 | (1) |
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Sequential Polymers from Two Symmetrical Monomers and Two Unsymmetrical Monomers |
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310 | (1) |
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Molecular Weight and Polydispersity Control |
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310 | (14) |
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Transfer of Reactive Species |
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311 | (5) |
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Different Substituent Effects Between Monomer and Polymer |
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316 | (1) |
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Resonance Effect (Polymerization of para-Substituted Monomers) |
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316 | (5) |
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Inductive Effect (meta-Substituted Monomers) |
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321 | (1) |
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322 | (2) |
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Chain Topology and Polymer Morphology Control |
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324 | (10) |
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324 | (2) |
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326 | (1) |
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326 | (1) |
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326 | (2) |
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328 | (1) |
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329 | (1) |
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Poly(Ether Ketone) and Poly(Ether Sulfone) |
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330 | (1) |
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331 | (1) |
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Polyurethane and Polyurea |
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332 | (1) |
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Polymer Morphology Control |
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332 | (2) |
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Condensation Polymer Architecture |
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334 | (17) |
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334 | (1) |
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Block Copolymers of Condensation Polymers |
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334 | (3) |
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Block Copolymers of Condensation Polymers and Coil Polymers |
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337 | (6) |
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343 | (1) |
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344 | (1) |
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345 | (6) |
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Supramolecular Polymer Engineering |
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351 | (50) |
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351 | (1) |
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General Aspects of Supramolecular Polymers |
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352 | (4) |
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Non-covalent Interactions |
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356 | (5) |
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356 | (4) |
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Solvophobic and Coulombic Interactions |
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360 | (1) |
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361 | (26) |
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361 | (1) |
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Supramolecular Polymers Based on Liquid Crystalline Monomers |
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362 | (1) |
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Supramolecular Polymers in Isotropic Solution |
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363 | (10) |
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373 | (1) |
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Main-chain Supramolecular Polymers |
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374 | (4) |
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Supramolecular Block Copolymers |
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378 | (2) |
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Side-chain Supramolecular Polymers |
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380 | (5) |
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Applications Based on Supramolecular UPy Materials |
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385 | (2) |
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Ring--Chain Equilibria in Supramolecular Polymers |
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387 | (5) |
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392 | (9) |
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393 | (8) |
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Polymer Synthesis and Modification by Enzymatic Catalysis |
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401 | (78) |
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401 | (1) |
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Characteristics of Enzymatic Catalysis |
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402 | (2) |
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Synthesis of Poly(aromatic)s Catalyzed by Oxidoreductases |
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404 | (16) |
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Synthesis of Polymers from Phenolic Compounds |
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405 | (1) |
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Polymers from Unsubstituted Phenol |
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406 | (2) |
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Polymers from Substituted Phenols |
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408 | (5) |
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Polymerization of Phenols Catalyzed by Enzyme Model Complexes |
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413 | (1) |
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Synthesis of Polymers from Polyphenols |
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414 | (1) |
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Polymers from Catechol Derivatives |
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414 | (3) |
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417 | (1) |
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Synthesis of Polyaniline and Its Derivatives |
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418 | (2) |
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Synthesis of Vinyl Polymers Catalyzed by Oxidoreductases |
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420 | (2) |
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Synthesis of Polysaccharides Catalyzed by Hydrolases |
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422 | (17) |
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Synthesis of Polysaccharides via Polycondensation |
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422 | (1) |
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Cellulose and Its Derivatives |
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422 | (5) |
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427 | (1) |
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427 | (1) |
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428 | (1) |
|
Oligo- and Polysaccharide Synthesis by Mutated Enzymes |
|
|
429 | (1) |
|
Synthesis of Polysaccharides via Ring-opening Polyaddition |
|
|
430 | (1) |
|
Chitin and its Derivatives |
|
|
431 | (4) |
|
|
|
435 | (2) |
|
Unnatural Hybrid Polysaccharides |
|
|
437 | (2) |
|
Synthesis of Polyesters Catalyzed by Hydrolases, Mainly by Lipases |
|
|
439 | (22) |
|
Polyesters via Ring-opening Polymerization |
|
|
439 | (1) |
|
Ring-opening Polymerization of Lactones |
|
|
439 | (13) |
|
Ring-opening Polymerization of Other Cyclic Monomers |
|
|
452 | (2) |
|
Polyesters via Polycondensation |
|
|
454 | (1) |
|
Polycondensation of Dicarboxylic Acids and Their Derivatives with Glycols |
|
|
454 | (4) |
|
Polycondensation of Oxyacid Derivatives |
|
|
458 | (1) |
|
Synthesis of Functional Polyesters |
|
|
459 | (2) |
|
Modification of Polymers by Enzymatic Catalysis |
|
|
461 | (5) |
|
Modification of Polysaccharides |
|
|
462 | (3) |
|
Modification of Other Polymers |
|
|
465 | (1) |
|
|
|
466 | (13) |
|
|
|
467 | (12) |
|
Biosynthesis of Protein-based Polymeric Materials |
|
|
479 | (40) |
|
|
|
|
|
|
|
Protein Polymers That Mimic Natural Proteins |
|
|
481 | (11) |
|
|
|
481 | (3) |
|
|
|
484 | (2) |
|
Elastin-like Polypeptide Copolymers |
|
|
486 | (1) |
|
Silk--Elastin-like Polypeptides |
|
|
487 | (1) |
|
|
|
488 | (1) |
|
|
|
489 | (2) |
|
Other Naturally Occurring Proteins |
|
|
491 | (1) |
|
|
|
491 | (1) |
|
Mussel Adhesive Plaque Protein and Glutenin |
|
|
491 | (1) |
|
Protein Polymers of De Novo Design |
|
|
492 | (4) |
|
β-Sheet-forming Protein Polymers |
|
|
492 | (1) |
|
|
|
493 | (1) |
|
|
|
494 | (1) |
|
|
|
495 | (1) |
|
Non-structured Protein Polymers |
|
|
495 | (1) |
|
Proteins Containing Non-natural Amino Acids |
|
|
496 | (14) |
|
|
|
496 | (1) |
|
|
|
496 | (2) |
|
In Vitro Suppression Strategies |
|
|
498 | (1) |
|
In Vivo Suppression Strategies |
|
|
498 | (1) |
|
Multisite Incorporation of Non-natural Amino Acids into Protein Polymers In Vivo |
|
|
499 | (4) |
|
Types of Chemically Novel Amino Acids Incorporated into Protein Polymers |
|
|
503 | (1) |
|
Halide-functionalized Side-chains |
|
|
503 | (2) |
|
Azide-functionalized Side-chains |
|
|
505 | (2) |
|
Ketone-functionalized Side-chains |
|
|
507 | (1) |
|
Alkyne- and Alkene-functionalized Side-chains |
|
|
507 | (1) |
|
Photoreactive Side-chains |
|
|
508 | (1) |
|
Unsaturated and Structural Amino Acid Analogues |
|
|
508 | (2) |
|
Prospects for Protein-based Polymers |
|
|
510 | (9) |
|
|
|
512 | (7) |
|
Macromolecular Engineering of Polypeptides Using the Ring-opening Polymerization-Amino Acid N-Carboxyanhydrides |
|
|
519 | (22) |
|
|
|
|
|
|
|
519 | (1) |
|
Polymerization of α-Amino Acid N-Carboxyanhydrides |
|
|
520 | (5) |
|
|
|
520 | (2) |
|
Transition Metal-mediated NCA Polymerization |
|
|
522 | (1) |
|
Other NCA Polymerization Methods |
|
|
522 | (3) |
|
|
|
525 | (6) |
|
|
|
525 | (1) |
|
Conventional NCA Polymerization |
|
|
525 | (3) |
|
Controlled NCA Polymerizations |
|
|
528 | |
|
|
|
526 | (1) |
|
Conventional NCA Polymerization |
|
|
526 | (2) |
|
Controlled NCA Polymerizations |
|
|
528 | (3) |
|
|
|
531 | (2) |
|
Conventional NCA Polymerization |
|
|
531 | (2) |
|
Controlled NCA Polymerizations |
|
|
533 | (1) |
|
Graft and Hyperbranched Polypeptides |
|
|
533 | (4) |
|
|
|
537 | (4) |
|
|
|
539 | (2) |
|
Segmented Copolymers by Mechanistic Transformations |
|
|
541 | (64) |
|
|
|
|
|
|
|
541 | (4) |
|
|
|
545 | (1) |
|
|
|
546 | (44) |
|
Transformations Involving Condensation Polymerization |
|
|
546 | (1) |
|
Condensation Polymerization to Conventional Radical Polymerization |
|
|
547 | (2) |
|
Condensation Polymerization to Controlled Radical Polymerization |
|
|
549 | (2) |
|
Macrocyclic Polymerization to Condensation Polymerization |
|
|
551 | (1) |
|
Condensation Polymerization to Anionic Coordination-Insertion Polymerization |
|
|
552 | (1) |
|
Transformations Involving Suzuki and Yamamoto Polycondensations |
|
|
553 | (2) |
|
Transformation of Anionic Polymerization to Radical Transformation |
|
|
555 | (1) |
|
Anionic Polymerization to Conventional Radical Polymerization |
|
|
555 | (1) |
|
Anionic Polymerization to Controlled Radical Polymerization |
|
|
556 | (7) |
|
Transformation of Cationic Polymerization to Radical Polymerization |
|
|
563 | (1) |
|
Cationic Polymerization to Conventional Radical Transformation |
|
|
563 | (5) |
|
Cationic Polymerization to Controlled Radical Transformation |
|
|
568 | (4) |
|
Transformation of Radical Polymerization to Anionic Polymerization |
|
|
572 | (1) |
|
Conventional Radical Polymerization to Anionic Polymerization |
|
|
572 | (1) |
|
Controlled Radical Polymerization to Anionic Polymerization |
|
|
573 | (1) |
|
Transformation of Radical Polymerization to Cationic Polymerization |
|
|
574 | (4) |
|
Transformations Involving Anionic and Cationic Polymerizations |
|
|
578 | (5) |
|
Transformations Involving Activated Monomer Polymerization |
|
|
583 | (2) |
|
Transformations Involving Metathesis Polymerization |
|
|
585 | (1) |
|
Transformations Involving ZieglerNatta Polymerization |
|
|
586 | (3) |
|
Transformations Involving Group Transfer Polymerization |
|
|
589 | (1) |
|
Coupling Reactions and Concurrent Polymerizations |
|
|
590 | (3) |
|
|
|
593 | (12) |
|
|
|
594 | (11) |
|
Polymerizations in Aqueous Dispersed Media |
|
|
605 | (38) |
|
|
|
|
|
|
|
605 | (1) |
|
Aqueous Suspension Polymerization |
|
|
606 | (7) |
|
Conventional Free Radical Polymerization |
|
|
606 | (1) |
|
Controlled/Living Free Radical Polymerization |
|
|
607 | (1) |
|
Nitroxide-mediated Controlled Free Radical Polymerization (NMP) |
|
|
607 | (1) |
|
Atom-transfer Radical Polymerization (ATRP) |
|
|
607 | (1) |
|
Other Controlled Free Radical Polymerization Methods |
|
|
608 | (1) |
|
Ring-opening Metathesis Polymerization (ROMP) |
|
|
608 | (1) |
|
|
|
608 | (1) |
|
|
|
608 | (2) |
|
|
|
610 | (1) |
|
Polycondensation/Polyaddition |
|
|
610 | (1) |
|
|
|
610 | (2) |
|
Preparation of Microcapsules |
|
|
612 | (1) |
|
Aqueous Miniemulsion Polymerization |
|
|
613 | (13) |
|
Conventional Free Radical Polymerization |
|
|
613 | (2) |
|
Controlled/Living Free Radical Polymerization |
|
|
615 | (1) |
|
Nitroxide-mediated Controlled Free Radical Polymerization |
|
|
615 | (2) |
|
Atom-transfer Radical Polymerization |
|
|
617 | (2) |
|
Control via Reversible Chain Transfer |
|
|
619 | (1) |
|
Other Controlled Free Radical Polymerization Methods |
|
|
620 | (1) |
|
Ring-opening Metathesis Polymerization |
|
|
620 | (1) |
|
Catalytic Polymerization of Ethylene and Butadiene |
|
|
621 | (1) |
|
|
|
622 | (1) |
|
Irreversible Deactivation of the Chain Ends by Water |
|
|
622 | (1) |
|
Reversible Deactivation of the Chain Ends by Water |
|
|
623 | (2) |
|
Polycondensation/Polyaddition Reactions |
|
|
625 | (1) |
|
Aqueous Emulsion Polymerization |
|
|
626 | (7) |
|
Conventional Free Radical Polymerization |
|
|
626 | (3) |
|
Controlled/Living Free Radical Polymerization |
|
|
629 | (1) |
|
Nitroxide-mediated Controlled Free Radical Polymerization |
|
|
629 | (1) |
|
Atom-transfer Radical Polymerization |
|
|
630 | (1) |
|
Control via Reversible Addition--Fragmentation Chain Transfer |
|
|
630 | (2) |
|
Ring-opening Metathesis Polymerization |
|
|
632 | (1) |
|
Catalytic Polymerization of Ethylene |
|
|
632 | (1) |
|
|
|
632 | (1) |
|
Polymerization in Surfactant Templates |
|
|
633 | (3) |
|
Microemulsion Polymerization |
|
|
633 | (1) |
|
Conventional Free Radical Polymerization |
|
|
633 | (1) |
|
Controlled Free Radical Polymerization |
|
|
634 | (1) |
|
|
|
635 | (1) |
|
|
|
635 | (1) |
|
Polymerization in Vesicles |
|
|
635 | (1) |
|
|
|
636 | (7) |
|
|
|
636 | (7) |
|
Polymerization Under Light and Other External Stimuli |
|
|
643 | (30) |
|
|
|
|
|
|
|
|
|
643 | (1) |
|
|
|
643 | (2) |
|
Photopolymerization Reactions |
|
|
643 | (1) |
|
|
|
644 | (1) |
|
|
|
645 | (1) |
|
|
|
645 | (1) |
|
Photoinitiators and Photosensitizers |
|
|
645 | (4) |
|
|
|
646 | (1) |
|
Direct Production of Reactive Species |
|
|
646 | (1) |
|
|
|
646 | (1) |
|
|
|
646 | (1) |
|
|
|
647 | (1) |
|
Photoacid and Photobase Generators |
|
|
647 | (1) |
|
|
|
647 | (1) |
|
|
|
648 | (1) |
|
|
|
648 | (1) |
|
|
|
648 | (1) |
|
|
|
648 | (1) |
|
Properties of Photoinitiators and Photosensitizers |
|
|
649 | (1) |
|
|
|
649 | (3) |
|
|
|
650 | (1) |
|
Radical Monomers and Oligomers |
|
|
650 | (1) |
|
Cationic Monomers and Oligomers |
|
|
650 | (1) |
|
|
|
650 | (1) |
|
|
|
651 | (1) |
|
Brief Overview of Applications in UV Curing |
|
|
652 | (1) |
|
Photochemical/Chemical Reactivity and Final Properties |
|
|
653 | (11) |
|
Different Aspects of Photopolymerization Reactions |
|
|
653 | (1) |
|
|
|
653 | (2) |
|
|
|
655 | (2) |
|
Some Typical Reactions of Industrial Interest in the UV Curing Area |
|
|
657 | (4) |
|
Kinetics and Efficiency of the Photopolymerization Reaction |
|
|
661 | (1) |
|
|
|
661 | (1) |
|
Monitoring of the Photopolymerization Reaction |
|
|
661 | (1) |
|
Kinetics of Photopolymerization |
|
|
662 | (1) |
|
Photochemical and Chemical Reactivity |
|
|
663 | (1) |
|
Electron Beam, Microwave, Gamma Rays, Plasma and Pressure Stimuli Compared with Temperature and Light |
|
|
664 | (2) |
|
|
|
666 | (7) |
|
|
|
667 | (6) |
|
Inorganic Polymers with Precise Structures |
|
|
673 | (58) |
|
|
|
|
|
Metal-containing Polymers |
|
|
673 | (3) |
|
|
|
673 | (1) |
|
Chain Growth Polymerizations |
|
|
674 | (1) |
|
Living Polymerizations and Controlled Polymerizations |
|
|
675 | (1) |
|
Use of Nitroxide-mediated Radical Polymerization |
|
|
676 | (5) |
|
|
|
676 | (1) |
|
Nitroxide-mediated Radical Polymerization Routes to Ligand Functional Homopolymers |
|
|
677 | (1) |
|
Nitroxide-mediated Radical Polymerization Routes to Ligand Functional Block Copolymers |
|
|
678 | (2) |
|
Nitroxide-mediated Radical Polymerization of Metallomonomers |
|
|
680 | (1) |
|
Nitroxide-mediated Radical Polymerization of Metallomonomers to Prepare Block Copolymers |
|
|
680 | (1) |
|
Use of Atom-transfer Radical Polymerization (ATRP) |
|
|
681 | (5) |
|
|
|
681 | (1) |
|
Atom-transfer Radical Polymerization to Ligand Functional Homopolymers |
|
|
682 | (1) |
|
Atom-transfer Radical Polymerization Routes to Ligand Functional Block Copolymers |
|
|
682 | (2) |
|
Atom-transfer Radical Polymerization of Metallomonomers |
|
|
684 | (1) |
|
Use of Atom-transfer Radical Polymerization of Metallomonomers to Prepare Block Copolymers |
|
|
685 | (1) |
|
Use of Reversible Addition Fragmentation Termination (RAFT) Polymerization |
|
|
686 | (2) |
|
|
|
686 | (1) |
|
Reversible Addition Fragmentation Termination Polymerization to Prepare Ligand Functional Block Copolymers |
|
|
687 | (1) |
|
Use of Living Cationic Polymerization |
|
|
688 | (2) |
|
Use of Living Anionic Polymerization |
|
|
690 | (6) |
|
|
|
690 | (1) |
|
Living Anionic Polymerization Routes to Ligand Functional Homopolymers |
|
|
691 | (1) |
|
Living Anionic Polymerization Routes to Ligand Functional Block Copolymers |
|
|
691 | (1) |
|
Living Anionic Polymerization of Metallomonomers |
|
|
692 | (2) |
|
Living Anionic Polymerization of Metallomonomers to Prepare Block Copolymers |
|
|
694 | (2) |
|
Use of Metathesis Polymerization |
|
|
696 | (8) |
|
|
|
696 | (1) |
|
Metathesis Polymerization Routes to Ligand Functional Block Copolymers |
|
|
697 | (1) |
|
Metathesis Polymerization of Metallomonomers |
|
|
697 | (5) |
|
Use of Metathesis Polymerization of Metallomonomers to Prepare Block Copolymers |
|
|
702 | (2) |
|
Indirect Sequential Polymerization Routes to Metal-containing Block Copolymers |
|
|
704 | (3) |
|
Routes to Metallo-linked Block Copolymers |
|
|
707 | (2) |
|
Routes to Metal-centered Star- and Star-block Copolymers |
|
|
709 | (3) |
|
Applications of Metal-containing Polymers with Precise Structures |
|
|
712 | (5) |
|
Polymers Based on Main Group Elements |
|
|
717 | (9) |
|
|
|
717 | (1) |
|
|
|
718 | (2) |
|
|
|
720 | (4) |
|
|
|
724 | (2) |
|
|
|
726 | (5) |
|
|
|
727 | (4) |
|
Volume 2 Elements of Macromolecular Structural Control |
|
|
|
|
|
731 | (44) |
|
|
|
Synthesis of Macromonomers and Telechelic Oligomers by Living Polymerizations |
|
|
775 | (38) |
|
|
|
|
|
|
|
|
|
Statistical, Alternating and Gradient Copolymers |
|
|
813 | (26) |
|
|
|
Multisegmental Block/Graft Copolymers |
|
|
839 | (36) |
|
Constantinos Tsitsilianis |
|
|
Controlled Synthesis and Properties of Cyclic Polymers |
|
|
875 | (34) |
|
|
|
|
|
Polymers with Star-related Structures |
|
|
909 | (64) |
|
|
|
|
|
|
|
Linear Versus (Hyper)branched Polymers |
|
|
973 | (34) |
|
|
|
|
|
|
|
|
|
1007 | (50) |
|
|
|
Molecular Design and Self-assembly of Functional Dendrimers |
|
|
1057 | (46) |
|
|
|
|
|
|
|
Molecular Brushes -- Densely Grafted Copolymers |
|
|
1103 | (34) |
|
|
|
|
|
Grafting and Polymer Brushes on Solid Surfaces |
|
|
1137 | (42) |
|
|
|
|
|
|
|
Hybrid Organic Inorganic Objects |
|
|
1179 | (30) |
|
|
|
|
|
|
|
1209 | (40) |
|
|
|
|
|
Polyelectrolyte Multilayer Films -- A General Approach to (Bio)functional Coatings |
|
|
1249 | (58) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Bio-inspired Complex Block Copolymers/Polymer Conjugates and Their Assembly |
|
|
1307 | (34) |
|
|
|
|
|
|
|
Complex Functional Macromolecules |
|
|
1341 | (46) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Volume 3 Structure-Property Correlation and Characterization Techniques |
|
|
|
Self-assembly and Morphology Diagrams for Solution and Bulk Materials: Experimental Aspects |
|
|
1387 | (44) |
|
|
|
|
|
|
|
|
|
1431 | (40) |
|
|
|
|
|
Transport and Electro-optical Properties in Polymeric Self-assembled Systems |
|
|
1471 | (44) |
|
|
|
|
|
Atomic Force Microscopy of Polymers: Imaging, Probing and Lithography |
|
|
1515 | (60) |
|
|
|
|
|
Scattering from Polymer Systems |
|
|
1575 | (30) |
|
|
|
|
|
From Linear to (Hyper) Branched Polymers: Dynamics and Rheology |
|
|
1605 | (44) |
|
|
|
Determination of Bulk and Solution Morphologies by Transmission Electron Microscopy |
|
|
1649 | (38) |
|
|
|
|
|
|
|
|
|
1687 | (44) |
|
|
|
Miroslava Duskova-Smrckova |
|
|
Block Copolymers for Adhesive Applications |
|
|
1731 | (22) |
|
|
|
|
|
1753 | (30) |
|
|
|
Predicting Mechanical Performance of Polymers |
|
|
1783 | (98) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Chromatography of Polymers |
|
|
1881 | (56) |
|
|
|
|
|
1937 | (30) |
|
|
|
High-throughput Screening in Combinatorial Polymer Research |
|
|
1967 | (34) |
|
|
|
|
|
|
|
|
|
|
Applications of Thermoplastic Elastomers Based on Styrenic Block Copolymers |
|
|
2001 | (32) |
|
|
|
|
|
|
|
|
|
2033 | (38) |
|
|
|
|
|
Polymer/Layered Filler Nanocomposites: An Overview from Science to Technology |
|
|
2071 | (64) |
|
|
|
|
|
2135 | (46) |
|
|
|
|
|
|
|
2181 | (44) |
|
|
|
|
|
Karunakaran Radhakrishnan |
|
|
Molecular and Supramolecular Conjugated Polymers for Electronic Applications |
|
|
2225 | (38) |
|
|
|
|
|
Polymers for Microelectronics |
|
|
2263 | (32) |
|
|
|
|
|
Applications of Controlled Macromolecular Architectures to Lithography |
|
|
2295 | (36) |
|
|
|
|
|
|
|
|
|
Microelectronic Materials with Hierarchical Organization |
|
|
2331 | (38) |
|
|
|
|
|
|
|
Semiconducting Polymers and their Optoelectronic Applications |
|
|
2369 | (40) |
|
|
|
|
|
|
|
|
|
Polymer Encapsulation of Metallic and Semiconductor Nanoparticles: Multifunctional Materials with Novel Optical, Electronic and Magnetic Properties |
|
|
2409 | (42) |
|
|
|
|
|
Polymeric Membranes for Gas Separation, Water Purification and Fuel Cell Technology |
|
|
2451 | (42) |
|
|
|
|
|
|
|
Utilization of Polymers in Sensor Devices |
|
|
2493 | (48) |
|
|
|
|
|
|
|
2541 | (56) |
|
|
|
|
|
|
|
From Biomineralization Polymers to Double Hydrophilic Block and Graft Copolymers |
|
|
2597 | (48) |
|
|
|
Applications of Polymer Bioconjugates |
|
|
2645 | (44) |
|
|
|
|
|
Gel: a Potential Material as Artificial Soft Tissue |
|
|
2689 | (30) |
|
|
|
|
|
|
|
Polymers in Tissue Engineering |
|
|
2719 | (24) |
|
|
| IUPAC Polymer Terminology and Macromolecular Nomenclature |
|
2743 | (4) |
|
|
| Subject Index |
|
2747 | |
