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E-grāmata: Metal Oxide-Carbon Hybrid Materials: Synthesis, Properties and Applications

Edited by (Professor, Department of Chemistry, COMSATS University Islamabad, Islamabad, Pakistan), Edited by (Associate Professor, Department of Physics, Division of Science an), Edited by (Assistant Professor, Government Associate College Raiwind (Lahore), Pakistan)
  • Formāts: EPUB+DRM
  • Sērija : Metal Oxides
  • Izdošanas datums: 20-Mar-2022
  • Izdevniecība: Elsevier Science Publishing Co Inc
  • Valoda: eng
  • ISBN-13: 9780128227084
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  • Formāts: EPUB+DRM
  • Sērija : Metal Oxides
  • Izdošanas datums: 20-Mar-2022
  • Izdevniecība: Elsevier Science Publishing Co Inc
  • Valoda: eng
  • ISBN-13: 9780128227084

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Metal Oxide–Carbon Hybrid Materials: Synthesis, Properties and Applications reviews the advances in the fabrication and application of metal oxide–carbon-based nanocomposite materials. Their unique properties make them ideal materials for gas-sensing, photonics, catalysis, opto-electronic, and energy-storage applications.

In the first section, the historical background to the hybrid materials based on metal oxide–carbon and the hybridized metal oxide composites is provided. It also highlights several popular methods for the preparation of metal oxide–carbon composites through solid-state or solution-phase reactions, and extensively discusses the materials’ properties.

Fossil fuels and renewable energy sources cannot meet the ever-increasing energy demands of an industrialized and technology-driven global society. Therefore, the role of metal oxide–carbon composites in energy generation, hydrogen production, and storage devices, such as rechargeable batteries and supercapacitors, is of extreme importance. These problems are discussed in in the second section of the book.

Rapid industrialization has resulted in serious environmental issues which in turn have caused serious health problems that require the immediate attention of researchers. In the third section, the use of metal oxide–carbon composites in water purification, photodegradation of industrial contaminants, and biomedical applications that can help to clean the environment and provide better healthcare solutions is described.

The final section is devoted to the consideration of problems associated with the development of sensors for various applications. Numerous studies performed in this area have shown that the use of composites can significantly improve the operating parameters of such devices.

Metal Oxide–Carbon Hybrid Materials: Synthesis, Properties and Applications presents a comprehensive review of the science related to metal oxide–carbon composites and how researchers are utilizing these materials to provide solutions to a large array of problems.

  • Reviews the fundamental properties and fabrication methods of metal-oxide–carbon composites
  • Discusses applications in energy, including energy generation, hydrogen production and storage, rechargeable batteries, and supercapacitors
  • Includes current and emerging applications in environmental remediation and sensing
List of contributors
xiii
Volume editor biographies xix
Series editor biography xxi
Preface to the volume xxiii
Preface to the series xxv
Section One Metal oxide-carbon hybrid materials: Synthesis and properties
1(130)
1 Physical and chemical aspects of metal oxide---carbon composites
3(22)
A. A. Farghali
S.I. El-Dek
1.1 Introduction
3(1)
1.2 Materials in the nanoscale
3(1)
1.3 Relevance of the term "nanoparticles"
4(1)
1.4 Metal oxide-carbon nanocomposites
4(2)
1.5 Classification of metal oxide/carbon nanocomposites
6(10)
1.6 Conclusion and future perspectives
16(9)
Acknowledgments
17(1)
References
17(7)
Further reading
24(1)
2 Metal oxide---carbon composite: synthesis and properties by using conventional enabling technologies
25(36)
Muhammad Bilal
Zia Ur Rehman
Jianhua Hou
SaifAli
Sami Ullah
Junaid Ahmad
2.1 Introduction
25(2)
2.2 Specific properties of metal oxide---carbon composites
27(6)
2.3 General routes for making metal oxide---carbon composites
33(6)
2.4 Synthesis methods of carbon-based metal oxide composites for supercapacitors
39(5)
2.5 Synthesis methods of graphene---metal oxide composites for photocatalysis
44(8)
2.6 Conclusion
52(1)
2.7 Challenges and synthesis advancement in using conventional enabling technologies for metal oxide---carbon composites
53(8)
Acknowledgments
54(1)
References
54(7)
3 Electrical conductivity of metal oxide---carbon composites
61(14)
Sara Riaz
Yann Aman
Muhammad Nasir
Akhtar Hayat
Mian Hasnain Nawaz
3.1 Nature of metal oxide---carbon substrate bindings
61(1)
3.2 Carbon interfaces for conductive composites with metal oxides
61(4)
3.3 Synthetic strategies for conductive metal oxide-carbon composites
65(2)
3.4 Parameters affecting the conductive properties of metal oxide---carbon composites
67(2)
3.5 Applications and future perspectives of conductive metal oxide-carbon nanocomposites
69(1)
3.6 Conclusion
70(5)
References
71(4)
4 Photoelectrochemical properties for metal oxide---carbon hybrid materials
75(28)
Faryal Idrees
Fauzia Iqbal
Soman Iqbal
Amir Shehzad Shah
Husnain Joan
4.1 Introduction
75(1)
4.2 Photoelectrochemical hybrid materials
75(1)
4.3 Selection features for photoelectrochemical energy conversion
76(3)
4.4 Electrical double-layered capacitor and battery hybrid materials
79(1)
4.5 Metal oxide---carbon hybrid materials for energy conversion and storage
80(1)
4.6 Materials studied for photocatalysis and photoelectrochemical applications
80(8)
4.7 Materials studied for electrical double-layered capacitors and batteries
88(11)
4.8 Conclusions
99(4)
References
99(4)
5 Functionalized multimetal oxide---carbon nanotube-based nanocomposites and their properties
103(28)
Ebtesam E. Ateia
Amira T. Mohamed
M. Morsy
5.1 Introduction
103(3)
5.2 Methodology
106(2)
5.3 Results and discussion
108(15)
5.4 Conclusion
123(1)
5.5 Future prospects
124(7)
References
124(7)
Section Two Metal oxide-carbon composites in energy technologies
131(176)
6 Metal oxide---carbon composites for supercapacitor applications
133(46)
Zia Ur Rehman
Muhammad Bilal
Jianhua Hou
Junaid Ahmad
Sami Ullah
Xiaozhi Wang
Asif Hussain
6.1 Introduction
133(1)
6.2 Types of supercapacitors
134(9)
6.3 Carbon-based supercapacitors
143(2)
6.4 Metal oxide-based supercapacitors
145(6)
6.5 Transition metal-based supercapacitors
151(4)
6.6 Rare-earth metal oxide-based supercapacitors
155(5)
6.7 Synthesis methods and characteristics of metal oxide-carbon composites for supercapacitors
160(4)
6.8 Challenges and future perspectives of metal oxide-carbon composites
164(2)
6.9 Conclusion
166(13)
Acknowledgments
167(1)
References
167(12)
7 Hierarchical porous carbon-incorporated metal-based nanocomposites for secondary metal-ion batteries
179(38)
Maira Sadaqat
Hassina Tabassum
Qiu Tianjie
Asif Mahmood
Laraib Nisar
Muhammad Naeem Ashiq
7.1 Introduction
179(6)
7.2 Electrode material design for secondary metal-ion batteries
185(9)
7.3 Metal---air batteries
194(6)
7.4 Electrode material design
200(7)
7.5 Opportunities and challenges
207(1)
7.6 Summary and conclusions
207(10)
References
208(9)
8 Metal oxide---carbon nanofibers based composites for supercapacitors and batteries
217(20)
Sadia Khalid
Ashir Saeed
Mohammad Azad Malik
Muhammad Saeed Akhtar
Abbreviations
217(1)
8.1 Introduction
217(1)
8.2 Metal oxides
218(2)
8.3 Carbon nanofibers
220(2)
8.4 Metal oxide---carbon nanofiber based composites
222(2)
8.5 Synthesis of metal oxide---carbon nanofiber based composites
224(1)
8.6 Recent research and development: metal oxide---carbon nanofiber based electrodes
225(6)
8.7 Outlook and future perspectives
231(6)
References
233(4)
9 Metal oxide---carbon composite electrode materials for rechargeable batteries
237(18)
Ghulam Ali
Faiza Jan Iftikhar
9.1 Introduction
237(12)
9.2 Conclusion
249(6)
References
250(5)
10 Two-dimensional transition metal carbide (MXene) for enhanced energy storage
255(30)
Jameela Fatheema
Deji Akinwande
Syed Rizwan
10.1 Introduction
255(2)
10.2 Synthesis and structure
257(2)
10.3 Energy storage in MXene
259(13)
10.4 Conclusion and outlook
272(13)
Abbreviations
273(1)
Acknowledgments
274(1)
References
274(11)
11 Vanadium oxide---carbon composites and their energy storage applications
285(22)
Zeeshan Tariq
Sajid Ur Rehman
Xiaoming Zhang
Chuanbo Li
11.1 Introduction
285(1)
11.2 Vanadium oxide---carbon composite applications
285(18)
11.3 Conclusions
303(4)
References
304(3)
Section Three Metal oxide-carbon composites in biomedical, catalytic, and other applications
307(150)
12 Metal oxide---carbon composites and their applications in optoelectronics and electrochemical energy devices
309(32)
Asadullah Dawood
Junaid Ahmad
Saif Ali
Sami Ullah
Zeeshan Asghar
Matiullah Shah
12.1 Introduction
309(1)
12.2 Types of carbon composites
310(5)
12.3 Why metal oxide---carbon composites?
315(2)
12.4 Synthesis techniques of metal oxide---carbon composites
317(6)
12.5 Applications of metal oxide---carbon composites in optoelectronic devices
323(5)
12.6 Applications of metal oxide---carbon composites in electrochemical energy devices
328(5)
12.7 Conclusion
333(8)
References
334(7)
13 Graphene oxide---metal oxide composites, syntheses, and applications in water purification
341(30)
Kiran Aftab
Jianhua Hou
Zia Ur Rehman
13.1 Overview of graphene oxides and metal oxides
341(3)
13.2 General routes of graphene oxide---metal oxide composites for wastewater treatment
344(4)
13.3 Synthesis and specific properties of graphene oxide---metal oxide composites for wastewater treatment
348(2)
13.4 Water purification methods using graphene oxide---metal oxide composites
350(12)
13.5 Challenges and future perspective for graphene oxide---metal oxide composites
362(9)
References
365(6)
14 Biomedical applications of metal oxide---carbon composites
371(36)
Ammar Z. Alshemary
Ali Motameni
Zafer Evis
14.1 Introduction
371(1)
14.2 Metal oxide nanoparticles
372(7)
14.3 Carbon-based materials
379(8)
14.4 Metal oxide---carbon composites: synthesis and biomedical applications
387(2)
14.5 Conclusions
389(18)
References
389(18)
15 Antimicrobial studies of metal oxide nanomaterials
407(30)
Fakhra Liaqat
Mahammed Ilyas Khazi
Ahmad Sher Awan
Rengin Eltem
Jian Li
15.1 Introduction
407(1)
15.2 Synthesis of metal oxide nanoparticles
408(1)
15.3 Antimicrobial activity of metal oxide nanoparticles
409(9)
15.4 Proposed mechanisms of antimicrobial activity of metal oxide nanoparticles
418(3)
15.5 Safety issues
421(2)
15.6 Stabilization and biocompatibility of metal oxide nanoparticles
423(1)
15.7 Limitations
424(1)
15.8 Conclusion
424(13)
Acknowledgment
425(1)
References
425(12)
16 Metal oxide---carbon nanotube composites for photodegradation
437(20)
Nazia Nasr
Saadia Mushtaq
Hassina Tabassum
Ishaq Ahmad
Salem Abdulkarim
Tingkai Zhao
Muhammad Hassan Sayyad
16.1 Introduction
437(1)
16.2 Photodegradation
438(1)
16.3 Photocatalytic ozonation
438(1)
16.4 Mechanism of photocatalytic ozonation
439(2)
16.5 Metal oxide---carbon nanotubes for photo-ozonation
441(1)
16.6 Fenton and photo-Fenton processes
441(1)
16.7 Metal oxide and carbon-supported nanocatalysts
442(1)
16.8 Photocatalytic degradation
443(1)
16.9 Mechanism of photocatalytic oxidation reactions
443(2)
16.10 Measurement of photocatalytic activity
445(1)
16.11 Features of a photocatalysts
445(1)
16.12 Degradation parameters
445(2)
16.13 Metal oxides and other nanocomposites as potential photocatalysts
447(1)
16.14 Metal oxide---carbon nanotube nanocomposites
448(1)
16.15 Conclusion
449(8)
References
451(6)
Section Four Metal oxide-carbon---based sensors
457(90)
17 Potential carbon nanotube---metal oxide hybrid nanostructures for gas-sensing applications
459(16)
Nuzhat Jamil
Farwah Jameel
Sadia Zafar Bajwa
Asma Rehman
Rao F. Hussain Khan
Arshad Mahmood
Waheed S. Khan
17.1 Introduction
459(1)
17.2 Carbon-based nanomaterials
460(2)
17.3 Types of carbon nanotubes
462(2)
17.4 Metal oxide nanostructures
464(1)
17.5 Carbon nanotube---metal oxide hybrid structures and their features
464(1)
17.6 Gas sensors and their uses
465(7)
17.7 Conclusions
472(3)
Acknowledgments
472(1)
References
473(2)
18 Drug-detection performance of carbon nanotubes decorated with metal oxide nanoparticles
475(20)
Anam Munawar
Rao F. Hussain Khan
M. Zubair Iqbal
Asma Rehman
Sadia Zafar Bajwa
Waheed S. Khan
18.1 Introduction
475(1)
18.2 Carbon-based nanomaterials
476(1)
18.3 Classification of carbon nanomaterials
477(3)
18.4 Nanosensors and their types
480(2)
18.5 Nanosensor application
482(1)
18.6 Drug molecules and their detection
482(1)
18.7 Role of zinc oxide---carbon nanotube nanocomposite in morphine detection
483(1)
18.8 Cerium oxide nanoparticle-decorated carbon nanotubes as an effective platform for acetaminophen
484(2)
18.9 Efficient electrochemical detection of cetirizine antiinflammatory drug using titanium dioxide---carbon nanotube nanohybrid
486(1)
18.10 CuCo2O4/nitrogen-doped carbon nanotubes for electrochemical sensor for metronidazole detection
487(1)
18.11 Carbon nanotube---Fe3O4 magnetic composites for electrochemical detection of triclosan
487(1)
18.12 Nickel oxide/carbon nanotube/PEDOT composite for simultaneous detection of dopamine, serotonin, and tryptophan
488(1)
18.13 Conclusion
489(6)
Acknowledgments
490(1)
References
490(5)
19 Role of functionalized metal oxide---carbon nanocomposites in biomolecule detection
495(34)
Sumaira Younis
Rabisa Zia
Ayesha Taj
Amna Rafiq
Hunza Hayat
Nafeesa Nayab
Waheed S. Khan
Sadia Zafar Bajwa
19.1 Introduction
495(3)
19.2 Detection of biomarkers
498(5)
19.3 Detection of biomolecules
503(12)
19.4 Viruses
515(4)
19.5 Conclusion
519(10)
References
520(9)
20 Metal oxide/carbon nanotube hybrid nanomaterials as ultraviolet photodetectors
529(18)
Gul Naz
Muhammad Ramzan
Muhammad Latif
Muhammad Bilal Tahir
Muhammad Arshad
20.1 Introduction
529(1)
20.2 Metal oxide materials
530(1)
20.3 Photodetectors
531(2)
20.4 Metal oxide-based hybrid photodetectors
533(1)
20.5 Carbon nanotube structures and characteristics
534(2)
20.6 Metal oxide/carbon nanotube hybrid nanomaterials as ultraviolet photodetectors
536(5)
20.7 Conclusion
541(6)
References
541(6)
Index 547
Dr. Muhammad Akram Chaudhry currently serves as assistant professor of chemistry at the Government Associate College, Raiwind (Lahore, Pakistan). He holds his MSc (chemistry) from the Institute of Chemistry, University of the Punjab, Lahore (Pakistan). He taught at the University of Baluchistan, Quetta for 3 years and attended the University of the Punjab, where he completed his MPhil (chemistry). During his stay there, he worked on the spectrophotometric determination of fluoroquinolone drugs and developed a simple and cheap method for their determination. In 2011, he joined Universiti Teknologi Malaysia, Malaysia, to pursue research work in the field of nanosized ceramic materials and received his doctorate in 2014. His PhD dissertation was on the Synthesis and Characterization of Ceramic Nanoparticles through Continuous Microwave Flow Synthesis Process.” His current research interest is focused on continuous microwave flow synthesis and the microwave-assisted synthesis of nanostructured materials, including biomaterials and photocatalytic materials. His work also involves probing the properties and applications of nanostructured material in various fields especially in biomedical and electrochemical devices. He is working collaboratively with various research groups and has published more than 35 research articles/book chapters as an author/coauthor in peer-reviewed international SCI-indexed journals with various publishers, such as Elsevier, Springer, IOP, and Wiley, with an h-index of 16 and ~1003 citations. Prof. Rafaqat Hussain graduated with a BSc (Hons) in chemistry from the University College London, where he also received his MSc in chemistry and a PhD in biochemical engineering. To pursue a career in teaching, he obtained a postgraduate certificate in education (chemistry) from the Goldsmiths College, London. In 2007, he moved to Pakistan to lead an ambitious project to establish the Interdisciplinary Research Centre in Biomedical Materials (IRCBM) at the COMSATS University Islamabad (CUI), Lahore campus. After more than 3 years at the IRCBM, he took up a teaching position at the Department of Chemistry, Universiti Teknologi Malaysia (UTM), where he established a successful materials research group. After more than 5 years teaching and supervising numerous research students at UTM, he returned to CUI to establish the Department of Chemistry at the Islamabad campus. He is actively involved in publishing research articles in leading high-impact journals, an author of over 50 research articles (impact factor >150) and several book chapters, and a winner of many research grants in the field of materials science. Dr. Faheem K. Butt currently works as an associate professor of physics in the Division of Science and Technology at the University of Education, Lahore. Before joining the University of Education, he was an Alexander von Humboldt Fellow at the Technical University of Munich, Germany. He completed his postdoctoral research fellowship from the Centre for Sustainable Nanomaterials, Universiti Teknologi Malaysia, in 2015. He completed his PhD studies at the Beijing Institute of Technology, China. His interests are in optoelectronics devices, energy storage/conversion in nanomaterials, and theoretical studies of materials using various software. He has published more than 120 research articles/book chapters as an author/coauthor in peer-reviewed international SCI journals with various publishers, including the American Chemical Society, Royal Society of Chemistry, Elsevier, Springer, American Scientific Publishers, and Taylor & Francis, with an h-index of 26 and ~3000 citations. He has also provided his services as a reviewer/editor/editorial board member for international publishers. Dr. Faheem has won several national/international awards. He is also a Higher Education Commission (HEC)-approved supervisor for PhD awardees of HEC scholarships, as well as general PhD scholars.