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E-grāmata: Metallic Chains / Chains of Metals

(Physical and Theoretical Chemistry, University of Saarland, Germany.), (Physical and Theoretical Chemistry, University of Saarland, Germany.)
  • Formāts: PDF+DRM
  • Sērija : Handbook of Metal Physics
  • Izdošanas datums: 16-Nov-2006
  • Izdevniecība: Elsevier Science Ltd
  • Valoda: eng
  • ISBN-13: 9780080466613
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  • Formāts: PDF+DRM
  • Sērija : Handbook of Metal Physics
  • Izdošanas datums: 16-Nov-2006
  • Izdevniecība: Elsevier Science Ltd
  • Valoda: eng
  • ISBN-13: 9780080466613
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The present book describes a large variety of different types of chain systems (nanowires), including shorter chains that are artificially produced for instance in break-junction experiments, chains synthesized as guests inside the channels of a host crystal, crystalline chain compounds, organic polymers (synthetic metals), and charge-transfer salts, thus covering an unusual wealth of systems. Both experimental and theoretical studies are discussed. Particular emphasis is put on illustrating the special phenomena that occur in such quasi-one-dimensional systems, and how theoretical and experimental efforts have been used in identifying those properties that are specific for truly one-dimensional systems from those of quasi-one-dimensional systems. Moreover, it is shown that metallic chains can be found in a large range of systems, but also that chains of metals not always are metallic.

· Gives a unifying description of very many different phenomena and systems
· High-Tc superconductors, conjugated polymers, gold nanowires, carbon nanotubes, chain compounds, and charge-transfer salts are all treated in one volume
· Illustrates the very broad range of quasi-one-dimensional systems
Preface vii
Metals and Chains?
1(2)
Single-Particle Properties
3(18)
A simple model
3(3)
Extending the simple model
6(5)
Transmission and complex band structures
11(3)
Conduction
14(5)
Conclusions
19(2)
References
19(2)
Many-Body Properties
21(16)
The electronic Schrodinger equation
21(2)
Hartree--Fock approaches
23(2)
Density-functional theory approaches
25(2)
Single-particle models
27(1)
Many-particle models
28(1)
The Hubbard and the extended Hubbard models for a chain
28(3)
The Luttinger liquid
31(3)
Conclusions
34(3)
References
35(2)
The Jellium Model
37(8)
Chains of jellium
38(6)
Conclusions
44(1)
References
44(1)
Gold Chains: The Prototype?
45(34)
The structure of a linear chain of Au atoms
45(3)
Conduction
48(4)
More complicated structures
52(11)
Chains containing other atoms
63(2)
Gold chains on surfaces -- Luttinger liquids?
65(11)
Conclusions
76(3)
References
77(2)
Chains of other sd Elements
79(18)
Ag
79(4)
Cu
83(3)
Hg, Cd, and Zn
86(1)
Pt
87(3)
Pd and Ni
90(1)
Ir, Rh, and Co
91(1)
Ru
91(1)
Nb
92(3)
Zr and Ti
95(1)
Conclusions
95(2)
References
96(1)
Chains of sp Elements
97(34)
Al
97(6)
Ga, In, and Tl
103(2)
C
105(14)
Si, Ge, and Pb
119(4)
As and Bi
123(1)
S and Se
124(1)
Conclusions
124(7)
References
127(4)
Chains of s Elements
131(10)
Na
131(6)
Li, K, Rb, and Cs
137(2)
Conclusions
139(2)
References
139(2)
Mixed Systems
141(18)
Order, disorder, and quasi-periodicity
141(1)
Alloys and compounds
142(4)
Filled nanotubes
146(4)
Decorating chains
150(1)
Guest--host systems
151(4)
Conclusions
155(4)
References
155(4)
Crystalline Chain Compounds
159(32)
CaNiN
159(3)
SN
162(2)
MX2 chains
164(3)
Metal trichalcogenides
167(4)
Metal tetrachalcogenides
171(2)
Metal oxides: spin-chain and spin-ladder compounds
173(8)
Incommensurate elemental crystals
181(2)
CH3BiI2
183(1)
Pt(CN)4-based chain materials
184(1)
Conclusions
185(6)
References
187(4)
Mixed-Valence MX Chain Compounds and Related Systems
191(12)
The MX chain compounds
191(8)
The MMX chain compounds
199(1)
Magnus' green salt
200(1)
Conclusions
201(2)
References
202(1)
Synthetic Metals: Conjugated Polymers
203(32)
The prototype: polyacetylene
204(10)
Other carbon-based conjugated polymers
214(4)
Incorporating heteroatoms
218(8)
Incorporating metal atoms
226(1)
Applications
227(3)
Conclusions
230(5)
References
231(4)
Charge-Transfer Salts
235(18)
General properties
236(5)
The TTF--TCNQ family
241(4)
The TMTSF2-X and ET2-X families
245(3)
The TTF--CA family
248(2)
Conclusions
250(3)
References
251(2)
Concluding Remarks
253(4)
Reference
255(2)
Subject Index 257
Since almost 25 years I have been working on theoretical studies of electronic and structural properties of atoms, molecules, clusters, colloids, polymers, chain compounds, surfaces, and crystals. I have an interdisciplinary background combining experience in chemistry and physics. My research has resulted in about 150 scientific papers and 2 textbooks. I have a background in technical / applied chemistry but since five years been working on theoretical studies of electronic and structural properties of nanoparticles and chain compounds. Yi Dong and Michael Springborg are married to each other.