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Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials 2007 ed. [Mīkstie vāki]

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  • Formāts: Paperback / softback, 504 pages, height x width: 235x155 mm, weight: 1630 g, XXIV, 508 p., 1 Paperback / softback
  • Sērija : NATO Science Series II: Mathematics, Physics and Chemistry 243
  • Izdošanas datums: 04-Jul-2007
  • Izdevniecība: Springer-Verlag New York Inc.
  • ISBN-10: 1402060904
  • ISBN-13: 9781402060908
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  • Formāts: Paperback / softback, 504 pages, height x width: 235x155 mm, weight: 1630 g, XXIV, 508 p., 1 Paperback / softback
  • Sērija : NATO Science Series II: Mathematics, Physics and Chemistry 243
  • Izdošanas datums: 04-Jul-2007
  • Izdevniecība: Springer-Verlag New York Inc.
  • ISBN-10: 1402060904
  • ISBN-13: 9781402060908
Citas grāmatas par šo tēmu:
Discover why olefin metathesis has asserted itself as a powerful strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials, and functionalized polymers. This volume compiles all the latest trends in olefin metathesis. In particular, you'll learn how olefin metathesis has growing potential for the development of sustainable technologies with many possible industrial applications.

Recently, an important scientific event in metathesis chemistry, the NATO-Advanced Study Institute New Frontiers in Metathesis Chemistry: From Nanostructure Design to Sustainable Technologies for . Synthesis of Advanced Materials was organized in Antalya, Turkey (September 4-16, 2006). Prominent scientists, young researchers and students, convened for two weeks to debate on the newest trends in olefin metathesis and identify future perspectives in this fascinating field of synthetic organic, organometallic and polymer chemistry with diverse potential applications in materials science and technology. Following the fruitful practice of the previous NATO ASI meetings, selected contributions comprising plenary lectures, short communications and posters are compiled in this special volume dedicated to this outstanding international scientific meeting. Olefin metathesis, one of the most efficient transition metal mediated C-C forming reactions, awarded in 2005 with the Nobel Prize for chemistry to Yves Chauvin (IFP), Robert H. Grubbs (Caltech) and Richard R. Schrock (MIT), asserted itself during the last decade as a powerful synthetic strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials and functionalized polymers tailored for specific utilizations (e.g. sensors, semiconductors, microelectronic devices) etc. Metathesis reactions such as ring-closing metathesis (RCM), enyne metathesis, cross-metathesis (CM), acyclic diene metathesis polymerizafion (ADMET) and ring-opening metathesis polymerization (ROMP), largely dealt with during the ASI meeting, have gone far beyond the 20-th century boundaries resulting in a broad diversification towards sustainable technologies with perspectives for industrial applications of a wide range of products, from the manufacture of smart, nanostructured materials to the synthesis of complex organic compounds, natural products, pharmaceuticals and supramolecular assemblies.
Preface ix
List of participants
xv
PART I. DESIGN OF NEW GENERATIONS OF METATHESIS CATALYSTS
New Ruthenium Catalysts for Alkene Metathesis
3(26)
Cedric Fischmeister
Pierre H. Dixneuf
Synthesis and Activity in Ring-Closing Metathesis of Phosphine and NHC-Containing Ruthenium-Indenylidene (Bis)Pyridine Complexes
29(10)
Herve Clavier
Steven P. Nolan
Towards New Generations of Metathesis Metal--Carbene Pre-catalysts
39(40)
Bart Allaert
Nicolai Dieltiens
Chris Stevens
Renata Drozdzak
Ileana Dragutan
Valerian Dragutan
Francis Verpoort
Ruthenium--Aryloxide Catalysts for Olefin Metathesis
79(12)
Sebastien Monfette
Johanna M. Blacquiere
Jay C. Conrad
Nicholas J. Beach
Deryn E. Fogg
Homobimetallic Ruthenium--N-Heterocyclic Carbene Complexes for Olefin Metathesis
91(20)
Xavier Sauvage
Albert Demonceau
Lionel Delaude
Phosphine-Free EWG-Activated Ruthenium Olefin Metathesis Catalysts: Design, Preparation, and Applications
111(14)
Karol Grela
Anna Michrowska
Michal Bieniek
Volodymyr Sashuk
Anna Szadkowska
Metathesis Catalysts Stability and Decomposition Pathway
125(12)
Alexey V. Nizovtsev
Vladimir V. Afanasiev
Egor V. Shutko
Natalia B. Bespalova
Ruthenium--Vinylidene Complexes: An Efficient Class of Homogeneous Metathesis Catalysts
137(14)
Ileana Dragutan
Valerian Dragutan
Renata Drozdzak
Francis Verpoort
Mesoporous Molecular Sieves as Supports for Metathesis Catalysts
151(16)
Hynek Balcar
Jiri Cejka
``Greener Shade of Ruthenium'': New Concepts of Activation, Immobilization, and Recovery of Ruthenium Catalysts for Green Olefin Metathesis
167(18)
Anna Michrowska
Lukasz Lukasz Gulajski
Karol Grela
Ring-Opening Metathesis Activity of Ruthenium-Based Olefin Metathesis Catalyst Coordinated with 1,3-Bis(2,6-Diisopropylphenyl)-4,5-Dihydroimidazoline
185(10)
Solmaz Karabulut
Francis Verpoort
PART II. INTRICATE ORGANIC SYNTHESIS VIA METATHESIS CHEMISTRY
Recent Applications of Alkene Metathesis for Fine Chemical and Supramolecular System Synthesis
195(28)
Franc Pozgan
Pierre H. Dixneuf
The Olefin Metathesis Reactions Combined with Organo-Iron Arene Activation Towards Dendrimers, and Polymers
223(14)
Didier Astruc
Victor Martinez
Olefin Metathesis With Ruthenium-Arene Catalysts Bearing N-Heterocyclic Carbene Ligands
237(14)
Lionel Delaude
Albert Demonceau
Olefin Metathesis Mediated By: - Schiff Base Ru-Alkylidenes - Ru-Alkylidenes Bearing Unsymmetrical NHC Ligands
251(14)
Stijn Monsaert
Nele Ledoux
Bart Allaert
Renata Drozdzak
Pascal Van Der Voort
Francis Verpoort
Cross-Metathesis of Vinyl-Substituted Organosilicon Derivatives With Olefins and Dienes in the Presence of Grubbs Catalysts
265(20)
Cezary Pietraszuk
Helmut Fischer
Bogdan Marciniec
PART III. TAILORED POLYMERS BY METATHESIS POLYMERIZATION
From Drug Cocktails to Tissue Engineering: Synthesis of ROMP Polymers for Biomedical Applications
285(20)
Kenneth D. Camm
Deryn E. Fogg
Precision Polyolefin Structure: Modeling Polyethylene Containing Methyl and Ethyl Branches
305(20)
Giovanni Rojas
Kenneth B. Wagener
Modeling Low Density Polyethylene with Precisely Placed Butyl Branches
325(8)
Giovanni Rojas
Kenneth B. Wagener
Correlating Precisely Defined Primary Structure with Crystalline Properties in Halogen Containing Polyolefins
333(14)
Emine Boz
Rufina G. Alamo
Kenneth B. Wagener
Synthesis of New Elastomers with Controlled Structures Based on Alkylene Oxides, Grafted by ROMP
347(8)
Bogdan Spurcaciu
Emil Buzdugan
Cristian-Andi Nicolae
Ileana Dragutan
Valerian Dragutan
Investigation of the Microstructure of Metal Catalyzed Cyclopentene Co-Norbornene Polymers by Spectral Methods
355(6)
Sevil Cetinkaya
Solmaz Karabulut
Yavuz Imamoglu
ADMET Polymerization Activities of Electrochemically Reduced W-Based Active Species for Ge and Sn Containing Dienes
361(6)
Solmaz Karabulut
Cemil Aydogdu
Bulent Duz
Yavuz Imamoglu
A Study on the Reactivity of WCl6--e- --Al--CH2Cl2 with the Silicon-Containing Dienes
367(8)
Solmaz Karabulut
Cemil Aydogdu
Bulent Duz
Yavuz Imamoglu
PART IV. ADVANCED MATERIALS VIA METATHESIS AND RELATED CHEMISTRY
Catalytic Cycloisomerization of Enynes Involving Various Activation Processes
375(20)
Christian Bruneau
ROMP, ROP, and Addition Polymerization of Silicon-Containing Cyclic Monomers as a Way to New Membrane Materials
395(18)
Maria L. Gringolts
Nikolai V. Ushakov
Yulia. V. Rogan
Kiryll L. Makovetskii
Yuri P. Yampolskii
Eugene Sh. Finkelshtein
Polydiphenylacetylene with Schiff Base End Groups: Synthesis and Characterization
413(8)
Radostina Kalinova
Christo Jossifov
Two-Way Intramolecular Transfer of Chirality in Organocobalt Complexes
421(20)
Claudia Zucchi
Davide Turrini
Roland Boese
Lajos Bencze
Robert Kurdi
Georg Frater
Luciano Caglioti
Gyula Palyi
Nanomolecular Switches Operated by Clockwork Mechanism
441(12)
Lajos Bencze
Robert Kurdi
Copolymerization of Ethylene with Norbornene and its Functional Derivatives Catalyzed by Nickel Complexes with Phosphorylide Ligands
453(8)
Victor I. Bykov
Vitalii A. Dronov
Tamara A. Butenko
Eugene Sh. Finkelshtein
Kiryl L. Makovetskii
Carbonyl--Olefin Exchange Reaction: Present State and Outlook
461(10)
Christo Jossifov
Radostina Kalinova
Immobilization of Metal Nanoparticles in Surface Layer of Silica Matrices
471(12)
Kseniia Katok
Valentin Tertykh
Victor Yanishpolskii
Catalytic Alkene Metathesis in Ionic Liquids
483(20)
Cedric Fischmeister
Subject Index 503