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Modern Aspects of Electrochemistry 41 2007 ed. [Hardback]

  • Formāts: Hardback, 308 pages, height x width: 235x155 mm, weight: 653 g, XI, 308 p., 1 Hardback
  • Sērija : Modern Aspects of Electrochemistry 41
  • Izdošanas datums: 03-May-2007
  • Izdevniecība: Springer-Verlag New York Inc.
  • ISBN-10: 0387461078
  • ISBN-13: 9780387461076
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  • Formāts: Hardback, 308 pages, height x width: 235x155 mm, weight: 653 g, XI, 308 p., 1 Hardback
  • Sērija : Modern Aspects of Electrochemistry 41
  • Izdošanas datums: 03-May-2007
  • Izdevniecība: Springer-Verlag New York Inc.
  • ISBN-10: 0387461078
  • ISBN-13: 9780387461076
Volume 41 of the prominent series Modern Aspects of Electrochemistry covers a range of topics in Electrochemistry and Electrochemical Engineering. The topics include the second chapter on the survey of experimental techniques and devices of solid state electrochemistry begun by Professor Joachim Maier in Volume 39. Chapter two contains a review of synthesis and characterization of nanoporous carbons and their electrochemical applications by Professors Gyoung-Ja Lee and Su-Il Pyun while in the next chapter Professor Joseph D. Fehribach reviews and discusses the use of graphs in the study of chemical reaction network. Professors Keith Scott and Sun Yan-Ping review and discuss mathematical models of three dimensional electrode structures in chapter four.

Volume 41 of the prominent series Modern Aspects of Electrochemistry covers a range of topics in Electrochemistry and Electrochemical Engineering. The topics include the second chapter on the survey of solid state electrochemistry begun by Professor Joachim Maier in Number 38. While the first part dealt with fundamenals of solid state electochemistry, this chapter deals with techniques and devices. Chapter two contains a review of synthesis and characterization of nanoporous carbons and their electrochemical applications by Professors Gyoung-Ja Lee and Su-Il Pyun while in the next chapter Professor Joseph D. Fehribach reviews and discusses the use of graphs in the study of chemical reaction network. Professors Keith Scott and Sun Yan-Ping review and discuss mathematical models of three dimensional electrode structures in chapter four.

Recenzijas

From the reviews:









"The 41st volume in this series covers a range of topics that touch on issues of potential interest to those working in electrochemistry-related fields. Overall, this text contains a diverse collection of topics that would be of varying degrees of interest to the broader electrochemistry community. More likely, the individual chapters would be most valued by specialists working in these areas." (Andrew C. Hillier, Journal of the American Chemical Society, Vol. 130 (2), 2008)



"As the most recent volume of a successful series established 1954 and carefully continued this book provides a timely collection of four review papers covering widely distributed aspects of electrochemistry in representative contributions. The book is a must for all libraries already owning previous volumes, in addition the contributions themselves justify acquisition for specialists entering the respective fields and subjects." (Rudolf Holze, Journal of Solid State Electrochemistry, Vol. 12, 2008)

Solid State Electrochemistry II: Devices and Techniques
Joachim Maier
Introduction
1(5)
Electrochemical Devices and Applications
6(68)
Electrochemical (Composition) Sensors
7(3)
Bulk Conductivity Sensor (Mode 1)
10(1)
Surface Conductivity Sensors (Mode 2)
11(3)
Galvanic Sensors (Mode 3)
14(4)
Extension to Acid-Base Active Gases
18(5)
Electrochemical (Composition) Actors
23(6)
Electrochemical Energy Storage and Conversion Devices
29(1)
Fuel Cells
30(28)
Batteries
58(10)
Other Storage Devices: Supercapacitors and Photobatteries
68(6)
Electrochemical Techniques
74(46)
Determination of Bulk Parameters
76(1)
Determination of Boundary Parameters
77(4)
Electrochemical Polarization---The Effect of Selectively Blocking Electrodes
81(1)
Heuristic Considerations
81(7)
The Steady-State Response: The Evaluation of Partial Conductivities
88(6)
The Instationary Behavior: The Evaluation of the Chemical Diffusion Coefficient
94(3)
Chemically Imposed Gradients
97(1)
Chemical Polarization and Concentration Cell Experiment
97(3)
Oxygen Permeation
100(1)
Zero-Driving Force Method
100(1)
Chemical Relaxation
101(3)
Coulometric Titration
104(2)
Thermodynamic Data from Electrochemical Cells Involving Solid Electrolytes
106(3)
Modifications in the Evaluation of Electrochemical Measurements Due to Internal Defect Reactions
109(3)
Dynamic Interactions
112(2)
Transport in Inhomogeneous, Heterogeneous, and Composite Systems
114(6)
Related Techniques
120(1)
Conclusions
120(19)
Acknowledgment
121(1)
Appendix 1---Terminal Potential Difference
121(1)
Appendix 2---Electrochemical Polarization
122(2)
Appendix 3---Chemical Polarization and Relaxation
124(1)
Appendix 4---Electrolytic Domain Boundaries
125(1)
Appendix 5---Coulometric Titration
126(1)
Appendix 6---Point Electrode Resistance
127(1)
Symbols
127(1)
References
128(11)
Synthesis and Characterization of Nanoporous Carbon and Its Electrochemical Application to Electrode Material for Supercapacitors
Gyoung-Ja Lee
Su-II Pyun
Introduction
139(2)
Preparation of Porous Carbons
141(4)
Activation Method
141(2)
Templating Method
143(2)
Structural Characteristics of Porous Carbons
145(9)
Types of Adsorption Isotherms and Hysteresis Loops
145(5)
Determinations of Surface Area and Pore Size Distribution
150(4)
Fractal Characteristics of Porous Carbons
154(12)
Molecular Probe Method Using Gas Adsorption
155(7)
Image Analysis Method
162(4)
Electrochemical Characteristics of Carbon-Based Porous Electrodes For Supercapacitor: The Uses of AC-Impedance Spectroscopy, Current Transient and Cyclic Voltammetry
166(17)
General Theory of Electrochemical Behavior of Porous Electrodes
166(3)
Effect of Geometric Heterogeneity on Ion Penetration into the Pores during Double-Layer Charging/Discharging
169(6)
Effect of Surface Inhomogeneity on Ion Penetration into the Pores during Double-Layer Charging/Discharging
175(8)
Concluding Remark
183(14)
Acknowledgements
185(1)
Notation
186(4)
References
190(7)
The use of Graphs in the Study of Electrochemical Reaction Networks
Joseph D. Fehribach
Introduction
197(3)
Reaction Species Graphs
200(5)
Kinetic Graphs
201(2)
Bipartite Graphs
203(2)
Reaction Mechanism Graphs
205(6)
MCFC Cathodic Reactions
206(1)
Peroxide Mechanism
206(2)
Superoxide-Peroxide Mechanism
208(1)
HER Reactions
209(2)
Reaction Route Graphs
211(6)
MCFC Cathodic Reactions
212(1)
HER Reactions
213(4)
Discussion: Other Reaction Graphs
217(5)
Acknowledgments
218(1)
References
218(4)
Approximate Analytical Solutions for Models of Three-Dimensional Electrodes by Adomian's Decomposition Method
Keith Scott
Yan-Ping Sun
Introduction
222(1)
Adomian's Decomposition Method (ADM)
223(3)
Example of Applications to Catalytic reactions
226(13)
Model Solution
229(1)
Catalyst Slab
229(3)
Spherical Catalyst Pellet
232(2)
Concentration Profiles and Effectiveness
234(1)
Concentration Profiles
234(1)
Effectiveness
235(4)
Application to the Influence of Mass Transport in Electrocatalysts
239(12)
Internal Diffusion and Film Mass Transport
244(4)
Agglomerate Model of Electrocatalysis
248(3)
Application to Models For Three-Dimensional Electrodes
251(24)
The General Form of Model of Three-Dimension Electrodes
251(1)
Porous Electrode Reactor
252(8)
Packed-Bed Electrode Reactor
260(11)
Simplification of Packed-Bed Electrode with a Low Conversion
271(4)
Examples of Packed-Bed Electrodes applications
275(17)
Electrochemical Reduction of Nitrobenzene in a Packed-Bed Electrode Reactor
275(7)
Direct Electrochemical Oxidation of Propylene in a Sparged Packed-Bed Electrode Reactor
282(5)
Two-Dimensional Model of Packed-Bed Electrodes
287(5)
Conclusions
292(10)
Acknowledgement
293(1)
Symbols
293(1)
ADM's Nomenclature
293(1)
Nomenclatures in this Paper
293(3)
Appendix: ADM Mathematica Codes
296(1)
ADM to Solve One ODE
296(3)
ADM to Solve the Coupled ODE's
299(3)
References
302