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E-grāmata: Multi Frequency EPR Spectroscopy of Conjugated Polymers and Their Nanocomposites

(Russian Academy of Sciences, Moscow, Russia)
  • Formāts: 314 pages
  • Izdošanas datums: 14-Oct-2016
  • Izdevniecība: CRC Press Inc
  • Valoda: eng
  • ISBN-13: 9781498779654
  • Formāts - PDF+DRM
  • Cena: 86,40 €*
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  • Formāts: 314 pages
  • Izdošanas datums: 14-Oct-2016
  • Izdevniecība: CRC Press Inc
  • Valoda: eng
  • ISBN-13: 9781498779654

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Conjugated polymeric materials and their nanocomposites are widely used for the creation of alternative sources of renewable energy, cell phone screens, mobile gadgets, video players and OLED-TV, as well as organic diodes, transistors, sensors, etc. with field-dependent and spin-assisted electronic properties. Multifrequency EPR Spectroscopy methods can help researchers optimize their structural, magnetic and electronic properties for the creation of more efficient molecular devices. This book will acquaint the reader with the basic properties of conjugated polymers, the fundamentals of EPR Spectroscopy, and the information that can be obtained at different wavebands of EPR spectroscopy.

List of Symbols
ix
List of Abbreviations
xv
Preface xvii
Acknowledgments xix
Author xxi
1 Introduction
1(16)
1.1 Properties of Conjugated Polymers
1(3)
1.2 Solitons, Polarons, and Bipolarons in Conjugated Polymers
4(6)
1.3 Resonant Manipulation of Interacting Spins in Polymer Nanocomposites
10(2)
1.4 Multifrequency EPR of Spin Charge Carriers in Conjugated Polymer Systems
12(3)
1.5 Summary
15(2)
2 Theoretical Backgrounds of Paramagnetic Resonance and Spin Transfer in Conjugated Polymers
17(40)
2.1 Magnetic Parameters of Organic Radicals Directly Obtained by EPR Spectroscopy
17(14)
2.2 Electron Relaxation of Spin Packets in Conjugated Polymers
31(3)
2.3 Spin Diffusion in Conjugated Polymers
34(6)
2.4 Molecular Dynamics in Conjugated Polymers
40(8)
2.5 Charge Carrier Transfer Mechanisms in Low-Dimensional Systems
48(9)
3 Instrumentation and Experimental Setup
57(8)
3.1 EPR Techniques
57(4)
3.2 EPR Standards
61(4)
4 Magnetic, Relaxation, and Dynamic Parameters of Charge Carriers in Conjugated Polymers
65(102)
4.1 Polyacetylene
65(18)
4.2 Poly(bis-Alkylthioacetylene)
83(12)
4.3 Poly(p-Phenylene)
95(3)
4.4 Poly pyrrole
98(4)
4.5 Poly(tetrathiafulvalene)
102(15)
4.6 Polyaniline
117(31)
4.7 Polythiophene
148(5)
4.8 Poly(3-Alkylthiophenes)
153(14)
5 Charge Transfer by Spin Carriers in Polymer: Fullerene Nanocomposites
167(50)
5.1 Line Shape and G-Factor
171(19)
5.2 Photoinitiation and Recombination of Charge Carriers in Polymen: Fullerene Nanocomposites
190(10)
5.3 Light-Induced EPR Linewidth
200(5)
5.4 Electron Relaxation and Dynamics of Spin Charge Carriers
205(12)
6 Spin-Assisted Charge Transfer in Polymer: Dopant/Polymen: Fullerene Nanocomposites
217(10)
6.1 Composition of Charge Carriers and Spin Precession Frequency
218(2)
6.2 Handling of Charge Transfer in Multispin Polymer Systems
220(7)
7 Concluding Remarks
227(4)
References 231(40)
Index 271
Victor I. Krinichnyi was employed as a scientific researcher and a senior scientific researcher in the Institute of Problems of Chemical Physics RAS (former the above mentioned Institute of Chemical Physics in Chernogolovka RAS). His SciD (Physics and Mathematics) Thesis (Habilitation) titled "High resolution 2-mm wave band EPR spectroscopy in the study of biological and conducting polymers' was also successfully defended by 1992 in the same Institute where he works today as a leading scientific researcher and heads the High-Frequency EPR Group.