Introduction |
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ix | |
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3 | (4) |
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7 | (6) |
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3 PVT Properties of Gases |
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13 | (22) |
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13 | (3) |
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16 | (5) |
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3.3 The van der Waals Equation |
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21 | (1) |
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3.4 The Redlich--Kwong Equation |
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22 | (1) |
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3.5 Principle of Corresponding States |
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22 | (2) |
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3.6 Molecular Basis of the Principle of Corresponding States |
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24 | (2) |
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26 | (2) |
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3.8 Truncated Virial Equation |
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28 | (7) |
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35 | (16) |
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4.1 Constant-Pressure Processes |
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42 | (3) |
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4.2 Steady Flow Processes |
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45 | (6) |
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5 Thermal Properties of Gases |
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51 | (16) |
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51 | (6) |
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5.2 Processes Involving Ideal Gases |
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57 | (10) |
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6 Second Law of Thermodynamics |
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67 | (18) |
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6.1 Irreversible Processes |
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68 | (2) |
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6.2 Heat Engines and Carnot's Theorem |
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70 | (3) |
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6.3 Thermodynamic Temperature Scale |
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73 | (3) |
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6.4 A New State Property: Entropy |
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76 | (9) |
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7 Thermodynamic Relationships for PVT Systems |
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85 | (16) |
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7.1 Volume Dependence of Internal Energy |
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85 | (2) |
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7.2 Auxiliary Functions and Maxwell Relations |
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87 | (3) |
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7.3 Relationship of Heat Capacities |
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90 | (11) |
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8 Entropy, Irreversibility, Randomness, and Natural Philosophy |
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101 | (6) |
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107 | (8) |
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115 | (12) |
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11 Phase Transition and Thermodynamic Diagrams |
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127 | (26) |
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127 | (6) |
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133 | (7) |
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11.3 Thermodynamic Diagrams |
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140 | (5) |
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145 | (8) |
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12 Work Processes and Cycles |
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153 | (20) |
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154 | (4) |
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12.2 Compression of Gases |
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158 | (15) |
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13 Refrigeration and Heat Pumps |
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173 | (26) |
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Part B Multicomponent Systems |
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199 | (12) |
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14.1 Partial Molar Quantities |
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201 | (3) |
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204 | (7) |
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15 PVT Properties of Gas Mixtures |
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211 | (6) |
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211 | (1) |
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212 | (1) |
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15.3 The Pseudo-critical Method |
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213 | (1) |
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213 | (4) |
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16 Thermodynamic Relationships |
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217 | (8) |
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16.1 Maxwell Relations and Gibbs--Duhem Relation |
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217 | (2) |
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16.2 Gibbs Phase Rule and Phase Equilibria |
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219 | (6) |
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225 | (14) |
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239 | (12) |
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240 | (1) |
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241 | (2) |
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18.3 Corresponding-States Correlation |
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243 | (1) |
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18.4 Other Equations of State |
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243 | (8) |
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251 | (42) |
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19.1 Condition for Equilibrium |
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251 | (2) |
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19.2 Equilibrium Composition |
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253 | (3) |
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19.3 Equilibrium Constant |
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256 | (5) |
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19.4 Independent Reactions |
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261 | (2) |
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263 | (30) |
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293 | (28) |
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294 | (1) |
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295 | (3) |
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20.3 Solubility Coefficients |
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298 | (1) |
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20.4 Activity Coefficients and Osmotic Coefficient |
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299 | (2) |
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20.5 Thermodynamic Consistency |
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301 | (1) |
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302 | (3) |
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305 | (2) |
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20.8 Electrolytic Solutions |
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307 | (14) |
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321 | (42) |
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21.1 Vapor as a Meter for Chemical Potentials in Liquid |
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322 | (4) |
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21.2 Gibbs Function and Ideal Solutions |
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326 | (2) |
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328 | (8) |
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21.4 Van Laar Equation and Regular Solutions |
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336 | (6) |
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342 | (3) |
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345 | (18) |
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363 | (6) |
Index: General |
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369 | (6) |
Index: Chemical Compounds |
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375 | |