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Newman Lectures on Thermodynamics [Hardback]

(University of California, Berkeley, USA), (Lawrence Berkeley National Laboratory, Berkeley, CA, USA)
  • Formāts: Hardback, 378 pages, height x width: 229x152 mm, weight: 762 g, 18 Tables, black and white; 1 Illustrations, color; 107 Illustrations, black and white
  • Izdošanas datums: 02-Jul-2019
  • Izdevniecība: Pan Stanford Publishing Pte Ltd
  • ISBN-10: 981477426X
  • ISBN-13: 9789814774260
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  • Formāts: Hardback, 378 pages, height x width: 229x152 mm, weight: 762 g, 18 Tables, black and white; 1 Illustrations, color; 107 Illustrations, black and white
  • Izdošanas datums: 02-Jul-2019
  • Izdevniecība: Pan Stanford Publishing Pte Ltd
  • ISBN-10: 981477426X
  • ISBN-13: 9789814774260

Prof. Newman is considered one of the great chemical engineers of his time. His reputation derives from his mastery of all phases of the subject matter, his clarity of thought, and his ability to reduce complex problems to their essential core elements. He is a member of the National Academy of Engineering, Washington, DC, USA, and has won numerous national awards including every award offered by the Electrochemical Society, USA. His motto, as known by his colleagues, is "do it right the first time." He has been teaching undergraduate and graduate core subject courses at the University of California, Berkeley (UC Berkeley), USA, since joining the faculty in 1966. His method is to write out, in long form, everything he expects to convey to his class on a subject on any given day. He has maintained and updated his lecture notes from notepad to computer throughout his career. This book is an exact reproduction of those notes.

This book presents concepts needed to define single- and multi-component systems, starting with the Gibbs function. It helps readers derive concepts of entropy and temperature and the development of material properties of pure substances. It acquaints them with applications of thermodynamics, such as cycles, open systems, and phase transitions, and eventually leads them to concepts of multiple-component systems, in particular, chemical equilibria and phase equilibria. It covers topics such as the interconversion of mechanical and thermal energy, processes involving compression of gases, the Carnot and practical refrigeration cycles, the liquefaction of gases, Joule–Kelvin expansion, Amagat’s law, Dalton’s law, the virial equation, Redlich–Kwong and van der Waals equation of state, Gibbs’ phase rule, Gibbs’ mixing rule, fugacity coefficient, and activity coefficient and discusses a multitude of examples of different systems at work. It clearly presents all concepts that are necessary for engineers.

Introduction ix
Part A Pure Substances
1 Thermodynamics
3(4)
2 Concept of Temperature
7(6)
3 PVT Properties of Gases
13(22)
3.1 Ideal Gases
13(3)
3.2 A Real Substance
16(5)
3.3 The van der Waals Equation
21(1)
3.4 The Redlich--Kwong Equation
22(1)
3.5 Principle of Corresponding States
22(2)
3.6 Molecular Basis of the Principle of Corresponding States
24(2)
3.7 The Virial Equation
26(2)
3.8 Truncated Virial Equation
28(7)
4 Conservation of Energy
35(16)
4.1 Constant-Pressure Processes
42(3)
4.2 Steady Flow Processes
45(6)
5 Thermal Properties of Gases
51(16)
5.1 Heat Capacity
51(6)
5.2 Processes Involving Ideal Gases
57(10)
6 Second Law of Thermodynamics
67(18)
6.1 Irreversible Processes
68(2)
6.2 Heat Engines and Carnot's Theorem
70(3)
6.3 Thermodynamic Temperature Scale
73(3)
6.4 A New State Property: Entropy
76(9)
7 Thermodynamic Relationships for PVT Systems
85(16)
7.1 Volume Dependence of Internal Energy
85(2)
7.2 Auxiliary Functions and Maxwell Relations
87(3)
7.3 Relationship of Heat Capacities
90(11)
8 Entropy, Irreversibility, Randomness, and Natural Philosophy
101(6)
9 The Virial Equation
107(8)
10 Surface Systems
115(12)
11 Phase Transition and Thermodynamic Diagrams
127(26)
11.1 Phase Transition
127(6)
11.2 Equilibrium
133(7)
11.3 Thermodynamic Diagrams
140(5)
11.4 Sources of Data
145(8)
12 Work Processes and Cycles
153(20)
12.1 Steam Power Plant
154(4)
12.2 Compression of Gases
158(15)
13 Refrigeration and Heat Pumps
173(26)
Part B Multicomponent Systems
14 Mixtures
199(12)
14.1 Partial Molar Quantities
201(3)
14.2 Mixing Experiments
204(7)
15 PVT Properties of Gas Mixtures
211(6)
15.1 Dalton's Law
211(1)
15.2 Amagat's Law
212(1)
15.3 The Pseudo-critical Method
213(1)
15.4 Virial Equation
213(4)
16 Thermodynamic Relationships
217(8)
16.1 Maxwell Relations and Gibbs--Duhem Relation
217(2)
16.2 Gibbs Phase Rule and Phase Equilibria
219(6)
17 Ideal-Gas Mixtures
225(14)
18 Fugacity Coefficient
239(12)
18.1 The Virial Equation
240(1)
18.2 Amagat's Law
241(2)
18.3 Corresponding-States Correlation
243(1)
18.4 Other Equations of State
243(8)
19 Gas-Phase Reactions
251(42)
19.1 Condition for Equilibrium
251(2)
19.2 Equilibrium Composition
253(3)
19.3 Equilibrium Constant
256(5)
19.4 Independent Reactions
261(2)
19.5 Chemical Equilibria
263(30)
20 Dilute Solutions
293(28)
20.1 Mole Ratios
294(1)
20.2 Chemical Potentials
295(3)
20.3 Solubility Coefficients
298(1)
20.4 Activity Coefficients and Osmotic Coefficient
299(2)
20.5 Thermodynamic Consistency
301(1)
20.6 Pressure Dependence
302(3)
20.7 Mole-Fraction Basis
305(2)
20.8 Electrolytic Solutions
307(14)
21 Liquid Mixtures
321(42)
21.1 Vapor as a Meter for Chemical Potentials in Liquid
322(4)
21.2 Gibbs Function and Ideal Solutions
326(2)
21.3 Margules Equations
328(8)
21.4 Van Laar Equation and Regular Solutions
336(6)
21.5 Wilson Equation
342(3)
21.6 Phase Equilibria
345(18)
22 Surface Systems
363(6)
Index: General 369(6)
Index: Chemical Compounds 375
John Newman is Charles W. Tobias Chair of Electrochemistry (emeritus), Department of Chemical Engineering, UC Berkeley. He was also a senior scientist and principal investigator at the Energy Technologies Area (ETA), Lawrence Berkeley National Laboratory (LBNL), Berkeley, California, USA. His current research focuses on the analysis and design of electrochemical systems, with batteries, fuel cells, turbulence, and renewable energy receiving the most attention.

Vincent Battaglia is a research scientist at LBNL, where he heads the Energy Storage Group of the ETA. He received his PhD in chemical engineering from UC Berkeley with an emphasis in electrochemical engineering. He specializes in battery design, fabrication, and testing, and his current research focuses on the science of electrode formulation as it relates to manufacturing and performance.