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E-grāmata: Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013

, (Ohio State University, USA)
  • Formāts: 1500 pages
  • Izdošanas datums: 05-Dec-2013
  • Izdevniecība: Royal Society of Chemistry
  • Valoda: eng
  • ISBN-13: 9781849733069
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  • Formāts: 1500 pages
  • Izdošanas datums: 05-Dec-2013
  • Izdevniecība: Royal Society of Chemistry
  • Valoda: eng
  • ISBN-13: 9781849733069

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Chemical nomenclature is used to identify a chemical species by means of written or spoken words and enables a common language for communication amongst chemists. Nomenclature for chemical compounds additionally contains an explicit or implied relationship to the structure of the compound, in order that the reader or listener can deduce the structure from the name. This purpose requires a system of principles and rules, the application of which gives rise to a systematic nomenclature. Of course, a wide range of traditional names, semisystematic or trivial, are also in use for a core group of common compounds. Detailing the latest rules and international practice, this new volume can be considered a guide to the essential organic chemical nomenclature, commonly described as the "Blue Book". An invaluable source of information for organic chemists everywhere and the definitive guide for scientists working in academia or industry, for scientific publishers of books, journals and databases, and for organisations requiring internationally approved nomenclature in a legal or regulatory environment.

Detailing the latest rules and international practice, this new volume can be considered a guide to the essential organic chemical nomenclature, commonly described as the "Blue Book".
Preface xxvii
Acknowledgements xxviii
Changes From The 1979 Edition, The 1993 Guide, And Official Publications From 1993 Through 2002 Included In The 2013 Edition Of IUPAC Nomenclature Of Organic Chemistry xxix
Glossary xxxviii
Chapter P-1 General Principles, Rules, And Conventions
P-10 Introduction
1(1)
P-11 Scope Of Nomenclature For Organic Compounds
2(1)
P-12 Preferred, Preselected, And Retained IUPAC Names
3(7)
P-12.1 Preferred IUPAC Names
3(5)
P-12.2 Preselected Names
8(1)
P-12.3 Retained Names
9(1)
P-12.4 Methodology
9(1)
P-13 Operations In Nomenclature Of Organic Compounds
10(15)
P-13.1 The Substitutive Operation
10(1)
P-13.2 The Replacement Operation
10(3)
P-13.3 The Additive Operation
13(4)
P-13.4 The Subtractive Operation
17(2)
P-13.5 The Conjunctive Operation
19(2)
P-13.6 The Multiplicative Operation
21(1)
P-13.7 The Fusion Operation
22(1)
P-13.8 Operations Used Only In The Nomenclature Of Natural Products
23(2)
P-14 General Rules
25(28)
P-14.0 Introduction
25(1)
P-14.1 Bonding Number
25(2)
P-14.2 Multiplicative Prefixes
27(1)
P-14.3 Locants
28(6)
P-14.4 Numbering
34(7)
P-14.5 Alphanumerical Order
41(4)
P-14.6 Nonalphanuerical Order
45(2)
P-14.7 Indicated And 'Added Indicated' Hydrogen
47(1)
P-14.8 Adducts
48(5)
P-15 Types Of Nomenclature
53(51)
P-15.0 Introduction
54(1)
P-15.1 Substitutive Nomenclature
55(10)
P-15.2 Functional Class Nomenclature
65(4)
P-15.3 Multiplicative Nomenclature
69(20)
P-15.4 Skeletal Replacement ('a') Nomenclature
89(5)
P-15.5 Functional Replacement Nomenclature
94(4)
P-15.6 Conjunctive Nomenclature
98(6)
P-16 Name Writing
104(26)
P-16.0 Introduction
104(1)
P-16.1 Spelling
104(1)
P-16.2 Punctuation
105(2)
P-16.3 Multiplicative Prefixes 'Di', Tri', Etc. vs. Bis', 'Tris', Etc.
107(6)
P-16.4 Other Numerical Terms
113(1)
P-16.5 Enclosing Marks
113(8)
P-16.6 Italicization
121(1)
P-16.7 Elision Of Vowels
122(2)
P-16.8 Addition Of Vowels
124(1)
P-16.9 Primes
124(6)
Chapter P-2 Parent Hydrides
P-20 Introduction
130(1)
P-21 Mononuclear And Acyclic Polynuclear Parent Hydrides
131(6)
P-21.1 Mononuclear Parent Hydrides
131(2)
P-21.2 Acyclic Polynuclear Parent Hydrides
133(4)
P-22 Monocyclic Parent Hydrides
137(18)
P-22.1 Monocyclic Hydrocarbons
137(2)
P-22.2 Heteromonocyclic Parent Hydrides
139(16)
P-23 Polyalicyclic Parent Hydrides (Extended Von Baeyer System)
155(14)
P-23.0 Introduction
155(1)
P-23.1 Definitions And Terminology
155(1)
P-23.2 Naming And Numbering Of Von Baeyer Hydrocarbons
156(8)
P-23.3 Heterogeneous Heterocyclic Von Baeyer Parent Hydrides
164(1)
P-23.4 Homogeneous Heterocyclic Von Baeyer Aren't Hydrides
165(1)
P-23.5 Heterogeneous Heterocyclic Von Baeyer Parent Hydrides Composed Of Alternating Heteroatoms
166(2)
P-23.6 Heterocyclic Polyalicyclic Parent Hydrides Having Heteroatoms With Nonstandard Bonding Numbers
168(1)
P-23.7 Retained Names For Von Baeyer Parent Hydrides
169(1)
P-24 Spiro Ring Systems
169(34)
P-24.0 Introduction
169(1)
P-24.1 Definitions
170(1)
P-24.2 Spiro Ring Systems With Only Monocyclic Ring Components
170(8)
P-24.3 Monospiro Ring Systems Containing Two Identical Polycyclic Ring Components
178(4)
P-24.4 Monospiro Ring Systems With Three Identical Polycyclic Ring Components Spirofused Together
182(2)
P-24.5 Monospiro Ring Systems With Different Components, At Least One Of Which Is A Polycyclic Ring System
184(4)
P-24.6 Unbranched Polyspiro Ring Systems With Different Components, One Being A Polycyclic Ring System
188(2)
P-24.7 Branched Polyspiro Ring Systems
190(5)
P-24.8 Spiro Ring Systems Containing Atoms With Nonstandard Bonding Numbers
195(8)
P-25 Fused And Bridged Fused Ring Systems
203(95)
P-25.0 Introduction
204(1)
P-25.1 Names Of Hydrocarbon Parent Ring Components
205(6)
P-25.2 Names Of Heterocyclic Parent Ring Components
211(8)
P-25.3 Constructing Fusion Names
219(44)
P-25.4 Bridged Fused Ring Systems
263(21)
P-25.5 Limitations Of Fusion Nomenclature: Three Components And Peri-Fused Together
284(3)
P-25.6 Fused Ring Systems With Skeletal Atoms With Nonstandard Bonding Numbers
287(2)
P-25.7 Double Bonds, Indicated Hydrogen, And The δ-Convention
289(4)
P-25.8 Parent Components In Decreasing Order Of Seniority (Partial Lists)
293(5)
P-26 Phane Nomenclature
298(24)
P-26.0 Introduction
298(1)
P-26.1 Concepts And Terminology
299(1)
P-26.2 Components Of Phane Parent Names
300(3)
P-26.3 Superatom Locants And Amplificant Attachment Locants
303(1)
P-26.4 Numbering Of Phane Parent Hydrides
304(12)
P-26.5 Skeletal Replacement ('a') Nomenclature In Phane Nomenclature
316(6)
P-26.6 Other Aspects Of Phane Nomenclature
322(1)
P-27 Fullerenes
322(17)
P-27.0 Introduction
322(1)
P-27.1 Definitions
323(1)
P-27.2 Fullerene Names
323(1)
P-27.3 Numbering Of Fullerenes
324(3)
P-27.4 Structurally Modified Fullerenes
327(4)
P-27.5 Replacement Of Skeletal Atoms
331(1)
P-27.6 Addition Of Rings And Ring Systems To Fullerenes
332(6)
P-27.7 Other Aspects Of Fullerene Nomenclature
338(1)
P-28 Ring Assemblies
339(10)
P-28.0 Introduction
339(1)
P-28.1 Definitions
339(1)
P-28.2 Ring Assemblies Of Two Identical Cyclic Systems
340(3)
P-28.3 Unbranched Ring Assemblies Of Three Through Six Identical Cyclic Systems
343(2)
P-28.4 Ring Assemblies Composed Of Identical Cyclic Systems Modified By Skeletal Replacement ('a') Nomenclature
345(2)
P-28.5 Ring Assembles Composed Of More Than Six Identical Cyclic Systems
347(1)
P-28.6 Branched Ring Assemblies Of Identical Cyclic Systems
347(2)
P-28.7 Ring Assemblies Of Non-Identical Cyclic Systems
349(1)
P-29 Prefixes Denoting Substituent Groups Derived From Parent Hydrides
349(23)
P-29.0 Introduction
350(1)
P-29.1 Definitions
350(2)
P-29.2 General Methodology For Naming Substituent Groups Prefixes
352(1)
P-29.3 Systematic Prefixes For Simple Substituents Groups Derived From Saturated Parent Hydrides
353(9)
P-29.4 Compound Substituent Groups
362(2)
P-29.5 Complex Substituent Groups
364(1)
P-29.6 Retained Names For Prefixes Of Simple Substituent Groups Derived From The Parent Hydrides Described In
Chapter P-2
365(7)
Chapter P-3 Characteristic (Functional) And Substituent Groups
P-30 Introduction
372(1)
P-31 Modification Of The Degree Of Hydrogenation Of Parent Hydrides
373(27)
P-31.0 Introduction
373(1)
P-31.1 The Endings 'Ene' Or 'Yne'
373(17)
P-31.2 The Prefixes 'Hydro' And 'Dehydro'
390(10)
P-32 Prefixes For Substituent Groups Derived From Parent Hydrides With A Modified Degree Of Hydrogenation
400(7)
P-32.0 Introduction
400(1)
P-32.1 Substituent Groups Derived From Parent Hydrides With 'Ene' Or 'Yne' Endings
400(3)
P-32.2 Substituent Groups Derived From Parent Hydrides Modified By The Prefix 'Hydro'
403(2)
P-32.3 Retained Names For Substituent Groups Derived From Unsaturated Acyclic Parent Hydrides
405(1)
P-32.4 Retained Names For Substituent Groups Derived From Partially Saturated Polycyclic Parent Hydrides
405(2)
P-33 Suffixes
407(6)
P-33.0 Introduction
407(1)
P-33.1 Definitions
407(1)
P-33.2 Functional Suffixes
408(4)
P-33.3 Cumulative Suffixes
412(1)
P-34 Functional Parent Compounds
413(8)
P-34.0 Introduction
413(1)
P-34.1 Retained Functional Parent Compounds
414(4)
P-34.2 Substituent Groups Related To Functional Parent Compounds
418(3)
P-35 Prefixes Corresponding To Characteristic Groups
421(7)
P-35.0 Introduction
421(1)
P-35.1 General Methodology
422(1)
P-35.2 Simple Prefixes Denoting Characteristic Groups
422(3)
P-35.3 Compound Substituent Prefixes
425(1)
P-35.4 Complex Substituent Prefixes
426(1)
P-35.5 Mixed Substituent Prefixes
427(1)
Chapter P-4 Rules For Name Construction
P-40 Introduction
428(1)
P-41 Seniority Order For Classes
428(3)
P-42 Seniority Order For Acids
431(5)
P-42.1 Class 7a. Acids Expressed By Suffixes (Excludes Carbonic And Polycarbonic Acids)
432(1)
P-42.2 Class 7b. Carbon Acids With No Substitutable Hydrogen Atoms
432(1)
P-42.3 Class 7c. Noncarbon Acids Having Substitutable Hydrogen Atoms On The Central Atom
432(1)
P-42.4 Class 7d. Noncarbon Acids Used To Generate Derivatives Having Substitutable Hydrogen Atoms
433(2)
P-42.5 Class 7e. Other Monobasic 'Oxo' Acids Used As Functional Parents
435(1)
P-43 Seniority Order For Suffixes
436(10)
P-43.0 Introduction
436(1)
P-43.1 General Methodology Of Functional Replacement
436(10)
P-44 Seniority Order For Parent Structures
446(69)
P-44.0 Introduction
447(1)
P-44.1 Seniority Order For Parent Structures
447(6)
P-44.2 Seniority Order Only For Rings And Ring Systems
453(37)
P-44.3 Seniority Of Acyclic Chains (The Principal Chain)
490(3)
P-44.4 Seniority Criteria Applicable To Rings, Ring Systems, Or Acyclic Chains
493(22)
P-45 Selection Of The Preferred IUPAC Name
515(25)
P-45.0 Introduction
515(1)
P-45.1 Multiplication Of Identical Senior Parent Structures
515(2)
P-45.2 Criteria Related To Number And Location Of Substituent Groups
517(11)
P-45.3 Criteria Related Only To Substituents With Nonstandard Bonding Numbers, Other Criteria Being Equal
528(1)
P-45.4 Criteria Related Only To Isotopic Modification, Other Criteria Being Equal
529(2)
P-45.5 Criteria Related To Alphanumerical Order Of Names
531(5)
P-45.6 Criteria Related Only To Configuration
536(4)
P-46 The Principal Chain In Substituent Groups
540(12)
P-46.0 Introduction
540(1)
P-46.1 The Principal Substituent Chain
541(8)
P-46.2 Principal Substituent Chains In Isotopically Labeled Compounds
549(1)
P-46.3 Principal Substituent Chains In Compounds With Stereogenic Centers
550(2)
Chapter P-5 Selecting Preferred IUPAC Names And Constructing Names Of Organic Compounds
P-50 Introduction
552(1)
P-51 Selecting The Preferred Type Of IUPAC Nomenclature
553(18)
P-51.0 Introduction
553(1)
P-51.1 Selecting The Preferred Type Of Nomenclature
553(2)
P-51.2 Functional Class Nomenclature
555(2)
P-51.3 Multiplicative Nomenclature
557(6)
P-51.4 Skeletal Replacement ('a') Nomenclature
563(7)
P-51.5 Conjunctive Nomenclature vs. Substitutive Nomenclature
570(1)
P-52 Selecting Preferred IUPAC Names And Preselected Names For Parent Hydrides
571(25)
P-52.1 Selecting Preselected Names
572(4)
P-52.2 Selecting Preferred IUPAC Names
576(20)
P-53 Selecting Preferred Retained Names Of Parent Hydrides
596(1)
P-54 Selecting The Preferred Method For Modifying The Degree Of Hydrogenation
597(6)
P-54.1 Methods For Modifying The Degree Of Hydrogenation Of Parent Hydrides:
597(1)
P-54.2 Unsaturated Monocyclic Carbocycles
597(1)
P-54.3 Unsaturation In Ring Assemblies Composed Of Mancude And Saturated Rings
598(1)
P-54.4 Names Modified By 'Hydro' Or 'Dehydro' Prefixes
598(5)
P-55 Selecting The Preferred Retained Name For Functional Parent Compounds
603(1)
P-56 Selecting The Preferred Suffix For The Principal Characteristic Group
603(3)
P-56.1 The Suffix 'Peroxol' For -OOH
603(1)
P-56.2 The Suffixes 'SO-Thioperoxol', And Chalogen Analogues
604(1)
P-56.3 The Suffixes 'Amidine' And 'Carboxamidine'
604(1)
P-56.4 The Endings 'Diyl' And 'Ylidene' vs. 'Ylene'
604(2)
P-57 Selecting Prefered And Preselected Prefixes For Substituent Groups
606(8)
P-57.1 Substituent Prefixes Derived From Parent Hydrides
606(6)
P-57.2 Prefixes Derived From Characteristic (Functional) Groups
612(1)
P-57.3 Prefixes Derived From Organic Functional Parent Compounds
612(1)
P-57.4 Construction Of Linear Compound And/or Complex Substituent Prefixes.
612(2)
P-58 Selecting Preferred IUPAC Names
614(14)
P-58.1 Introduction.
614(1)
P-58.2 Indicated Hydrogen, 'Added Indicated Hydrogen', And Non-Detachable Hydro Prefixes
615(12)
P-58.3 Homogeneous Hetero Chains And Functional Groups
627(1)
P-59 Name Construction
628(20)
P-59.0 Introduction
628(1)
P-59.1 General Methodology
628(4)
P-59.2 Examples Illustrating The Methodology
632(16)
Chapter P-6 Applications To Specific Classes Of Compounds
P-60 Introduction
648(1)
P-60.1 Topical Outline
648(1)
P-60.2 Presentation Of Names
648(1)
P-61 Substitutive Nomenclature: Prefix Mode
649(18)
P-61.0 Introduction
649(1)
P-61.1 General Methodology
650(1)
P-61.2 Hydrocarbyl Groups And Corresponding Di- And Polyvalent Groups
651(5)
P-61.3 Halogen Compounds
656(5)
P-61.4 Diazo Compounds
661(1)
P-61.5 Nitro And Nitroso Compounds
662(1)
P-61.6 Heterones
663(1)
P-61.7 Azides
664(1)
P-61.8 Isocyanates
664(1)
P-61.9 Isocyanides
665(1)
P-61.10 Fulminates And Isofulminates
666(1)
P-61.11 Polyfunctional Compounds
666(1)
P-62 Amines And Imines
667(22)
P-62.0 Introduction
667(1)
P-62.1 General Methodology
668(1)
P-62.2 Amines
668(14)
P-62.3 Imines
682(3)
P-62.4 N-Substitution Of Amines And Imines By Heteroatoms
685(1)
P-62.5 Amine Oxides, Imine Oxides, And Chalcogen Analogues
685(2)
P-62.6 Amine And Imine Salts
687(2)
P-63 Hydroxy Compounds, Ethers, Peroxols, Peroxides, And Chalcogen Analogues
689(31)
P-63.0 Introduction
689(1)
P-63.1 Hydroxy Compounds And Chalcogen Analogues
690(9)
P-63.2 Ethers And Chalcogen Analogues
699(8)
P-63.3 Peroxides And Chalcogen Analogues
707(4)
P-63.4 Hydroperoxides (Peroxols) And Chalcogen ** Analogues
711(2)
P-63.5 Cyclic Ethers, Sulfides, Selenides, And Tellurides
713(2)
P-63.6 Sulfoxides And Sulfones
715(1)
P-63.7 Polyfunctional Compounds
716(3)
P-63.8 Salts Of Hydroxy Compounds, Hydroperoxy Compounds And Their Chalcogen Analogues
719(1)
P-64 Ketones, Pseudoketones, Heterones, And Chalcogen Analogues
720(24)
P-64.0 Introduction
720(1)
P-64.1 Definitions
720(2)
P-64.2 Ketones
722(10)
P-64.3 Pseudoketones
732(2)
P-64.4 Heterones
734(2)
P-64.5 Carbonyl Groups As Prefixes
736(3)
P-64.6 Chalcogen Analogues Of Ketones, Pseudoketones, And Heterones
739(2)
P-64.7 Polyfunctional Ketones, Pseudoketones And Heterones
741(2)
P-64.8 Acyloins
743(1)
P-65 Acids, Acyl Halides And Pseudohalides, Salts, Esters, And Anhydrides
744(95)
P-65.0 Introduction
744(1)
P-65.1 Carboxylic Acids And Functional Replacement Analogues
745(32)
P-65.2 Carbonic, Cyanic, And Di- And Polycarbonic Acids
777(11)
P-65.3 Sulfonic Acids And Functional Replacement Analogues
788(7)
P-65.4 Acyl Groups As Substituent Groups
795(1)
P-65.5 Acid Halides And Pseudohalides
796(5)
P-65.6 Salts And Esters
801(25)
P-65.7 Anhydrides And Their Analogues
826(13)
P-66 Amides, Imides, Hydrazides, Nitriles, Aldehydes, Their Chalcogen Analogues And Derivatives
839(76)
P-66.0 Introduction
839(1)
P-66.1 Amides
839(29)
P-66.2 Imides
868(2)
P-66.3 Hydrazides
870(10)
P-66.4 Amidines, Amidrazones, Hydrazidines, And Amidoximes Amide Oximes)
880(19)
P-66.5 Nitriles
899(7)
P-66.6 Aldehydes
906(9)
P-67 Mononuclear And Polynuclear Noncarbon Acids And Their Functional Replacement Analogues As Functional Parents For Naming Organic Compounds
915(49)
P-67.0 Introduction
915(1)
P-67.1 Mononuclear Noncarbon Oxoacids
915(33)
P-67.2 Di- And Polynuclear Noncarbon Oxoacids
948(13)
P-67.3 Substitutive Names And Functional Class Names Of Polyacids
961(3)
P-68 Nomenclature Of Organic Compounds Of The Group 13, 14, 15, 16, And 17 Elements Not Included In Sections P-62 Through P-67
964(71)
P-68.0 Introduction
964(1)
P-68.1 Nomenclature Of Compounds Of Group 13 Elements
965(19)
P-68.2 Nomenclature Of Compounds Of Group 14 Elements
984(8)
P-68.3 Nomenclature Of Compounds Of Group 15 Elements
992(32)
P-68.4 Nomenclature Of Compounds Of Group 16 Elements
1024(9)
P-68.5 Nomenclature Of Compounds Of Group 17 Elements
1033(2)
P-69 Nomenclature Of Organometallic Compounds
1035(13)
P-69.0 Introduction
1035(1)
P-69.1 Organometallic Compounds Of Elements In Groups 13, 14, 15, And 16
1036(1)
P-69.2 Organometallic Compounds Of Elements In Groups 3 Through 12
1036(7)
P-69.3 Organometallic Compounds Of Elements In Groups 1 And 2
1043(1)
P-69.4 Metallacycles
1044(2)
P-69.5 Order Of Seniority Order For Organometallic Compounds
1046(2)
Chapter P-7 Radicals, Ions, And Related Species
P-70 Introduction
1048(3)
P-70.1 General Methodology
1048(1)
P-70.2 Seniority Of Radicals And Ions
1048(1)
P-70.3 Name Formation
1048(2)
P-70.4 General Rules For The Selection Of Preferred Names
1050(1)
P-71 Radicals
1051(14)
P-71.1 General Methodology
1051(1)
P-71.2 Radicals Derived From Parent Hydrides
1051(6)
P-71.3 Radical Centers On Characteristic Groups
1057(5)
P-71.4 Assemblies Of Parent Radicals
1062(1)
P-71.5 Prefixes Denoting Radicals
1063(1)
P-71.6 Order Of Citation And Seniority Of Suffixes 'Yl', 'Ylidene', And 'Ylidyne'
1064(1)
P-71.7 Choice Of Parent Radical
1064(1)
P-72 Anions
1065(17)
P-72.1 General Methodology
1065(1)
P-72.2 Anions Formed By Removal Of Hydrons
1066(8)
P-72.3 Anions Formed By Addition Of Hydride Ions
1074(2)
P-72.4 Skeletal Replacement ('a') Nomenclature
1076(1)
P-72.5 Multiple Anionic Centers
1077(1)
P-72.6 Anionic Centers In Both Parent Compounds And Substituent Groups
1078(2)
P-72.7 Choice Of An Anionic Parent Structure
1080(1)
P-72.8 The Suffixes 'Ide' And 'Uide' And The λ-Convention
1081(1)
P-73 Cations
1082(26)
P-73.0 Introduction
1082(1)
P-73.1 Cationic Compounds With Cationic Centers Derived Formally By Addition Of Hydrons
1082(7)
P-73.2 Cationic Compounds With Cationic Centers Derived Formally By The Removal Of Hydride Ions
1089(6)
P-73.3 The λ-Convention With The Suffix 'Ylium'
1095(3)
P-73.4 Skeletal Replacement ('a') Nomenclature For Cations
1098(2)
P-73.5 Cationic Compounds With Multiple Cationic Centers
1100(4)
P-73.6 Cationic Prefix Names
1104(2)
P-73.7 Choice Of A Parent Structure
1106(1)
P-73.8 The Suffixes 'Ium' vs. 'Ylium' And The λ-Convention
1107(1)
P-74 Zwitterions
1108(13)
P-74.0 Introduction
1108(1)
P-74.1 Zwitterionic Parent Structures Having The Anionic And Cationic Centers On The Same Parent Compound Including Ionic Centers On Characteristic Groups Expressible As Suffixes
1108(3)
P-74.2 Dipolar Compounds
1111(10)
P-75 Radical Ions
1121(6)
P-75.1 Radical Ions Formed By The Addition Or Removal Of Electrons
1122(1)
P-75.2 Radical Ions Derived From Parent Hydrides
1122(3)
P-75.3 Radical Ions On Characteristic Groups
1125(1)
P-75.4 Ionic And Radical Centers In Different Parent Structures
1126(1)
P-76 Delocalized Radicals And Ions
1127(1)
P-76.1 Delocalization In Names Involving One Radical Or Ionic Center In An Otherwise Conjugated Double Bonds Structure Is Denoted By The Appropriate Suffix Without Locants
1127(1)
P-77 Salts
1127(3)
P-77.1 Preferred Names For Salts Of Organic Bases
1127(1)
P-77.2 Salts Derived From Alcohols (Including Phenols), Peroxols, And Their Chalcogen Analogues
1128(1)
P-77.3 Salts Derived From Organic Acids
1129(1)
Chapter P-8 Isotopically Modified Compounds 1130(26)
P-80 Introduction
1130(1)
P-81 Symbols And Definitions
1130(1)
P-81.1 Nuclide Symbols
1130(1)
P-81.2 Atomic Symbols
1130(1)
P-81.3 Names For Hydrogen Atoms And Ions
1131(1)
P-81.4 Isotopically Unmodified Compounds
1131(1)
P-81.5 Isotopically Modified Compounds
1131(1)
P-82 Isotopically Substituted Compounds
1131(13)
P-82.0 Introduction
1132(1)
P-82.1 Structures
1132(1)
P-82.2 Names
1132(5)
P-82.3 Order Of Nuclide Symbols
1137(1)
P-82.4 Stereoisomeric Isotopically Substituted Compounds
1138(2)
P-82.5 Numbering
1140(1)
P-82.6 Locants
1141(3)
P-83 Isotopically Labeled Compounds
1144(11)
P-83.1 Specifically Labeled Compounds
1145(4)
P-83.2 Selectively Labeled Compounds
1149(3)
P-83.3 Nonselectively Labeled Compounds
1152(1)
P-83.4 Isotopically Deficient Compounds
1153(1)
P-83.5 General And Uniform Labeling
1153(2)
P-84 Comparative Examples Of Formulas And Names Of Isotopically Modified Compounds
1155(1)
Chapter 9 Specification Of Configuration And Conformation
P-90 Introduction
1156(1)
P-91 Stereoisomer Graphical Representation And Naming
1156(6)
P-91.1 Stereoisomer Graphical Representation
1157(1)
P-92.2 Stereodescriptors
1157(3)
P-91.3 Naming Of Stereoisomers
1160(2)
P-92 Cip Priority And Sequence Rules
1162(48)
P-92.1 The Cahn-Ingold-Prelog (CIP) System: General Methodology
1162(14)
P-92.2 Sequence Rule (1)
1176(12)
P-92.3 Sequence Rule (2)
1188(1)
P-92.4 Sequence Rule (3)
1189(4)
P-92.5 Sequence Rule (4)
1193(12)
P-92.6 Sequence Rule (5)
1205(5)
P-93 Configuration Specification
1210(76)
P-93.0 Introduction
1210(1)
P-93.1 General Aspects Of Configuration Specification
1210(3)
P-93.2 Tetrahedral Configuration Of Atoms Other Than Carbon
1213(4)
P-93.3 Nontetrahedral Configuration
1217(14)
P-93.4 Configuration Specification Of Acyclic Organic Compounds
1231(9)
P-93.5 Configuration Specification Of Cyclic Organic Compounds
1240(42)
P-93.6 Compounds Composed Of Rings And Chains
1282(4)
P-94 Conformation And Conformational Stereodescriptors
1286(7)
P-94.1 Definition
1286(1)
P-94.2 Torsion Angle
1286(3)
P-94.3 Specific Stereodescriptors
1289(4)
Chapter 10 Parent Structures For Natural Products And Related Compounds
P-100 Introduction
1293(1)
P-101 Nomenclature For Natural Products Based On Parent Hydrides (Alkaloids, Teroids, Terpenes, Carotenes, Corrinoids, Tetrapyrroles, And Similar Compounds)
1294(50)
P-101.1 Biologically Based Trivial Names
1294(1)
P-101.2 Semisystematic Nomenclature For Natural Products (Stereoparent Hydrides)
1295(7)
P-101.3 Skeletal Modifications Of Parent Structures
1302(15)
P-101.4 Replacement Of Skeletal Atoms
1317(3)
P-101.5 Addition Of Rings And Ring Systems
1320(7)
P-101.6 Modification Of The Degree Of Hydrogenation Of Parent Structures
1327(6)
P-101.7 Derivatives Of Parent Structures
1333(8)
P-101.8 Further Aspects Of Configurational Specification
1341(3)
P-102 Carbohydrate Nomenclature
1344(47)
P-102.1 Definitions
1344(2)
P-102.2 Parent Monosaccharides
1346(3)
P-102.3 Configurational Symbolism
1349(6)
P-102.4 Choice Of A Parent Structure
1355(1)
P-102.5 Monosaccharides: Aldoses And Ketoses; Deoxy And Amino Sugars
1356(27)
P-102.6 Monosaccharides And Derivatives As Substituent Groups
1383(5)
P-102.7 Disaccharides And Oligosaccharides
1388(3)
P-103 Amino Acids And Peptides
1391(23)
P-103.0 Introduction
1391(1)
P-103.1 Names, Numbering And Configuration Specification Of Amino Acids
1391(8)
P-103.2 Derivatives Of Amino Acids
1399(9)
P-103.3 Nomenclature Of Peptides
1408(6)
P-104 Cyclitols
1414(6)
P-104.0 Introduction
1414(1)
P-104.1 Definitions
1414(1)
P-104.2 Name Construction
1415(3)
P-104.3 Derivatives Of Cyclitols
1418(2)
P-105 Nucleosides
1420(5)
P-105.0 Introduction
1420(1)
P-105.1 Retained Names Of Nucleosides
1421(1)
P-105.2 Substitution On Nucleosides
1422(3)
P-106 Nucleotides
1425(6)
P-106.0 Introduction
1425(1)
P-106.1 Retained Names
1425(1)
P-106.2 Nucleotide Diphosphates And Triphosphates
1426(1)
P-106.3 Derivatives Of Nucleotides
1427(4)
P-107 Lipids
1431(8)
P-107.0 Introduction
1431(1)
P-107.1 Definitions
1432(1)
P-107.2 Glycerides
1432(1)
P-107.3 Phosphatidic Acids
1433(3)
P-107.4 Glycolipids
1436(3)
References 1439(4)
Appendix 1 Seniority List Of Elements And 'a' Terms Used In Skeletal Replacement ('a') Nomenclature, In Decreasing Order Of Seniority 1443(2)
Appendix 2 Detachable Prefixes Used In Substitutive Nomenclature 1445(70)
Appendix 3 Structures For Alkaloids, Steroids, Terpenoids And Similar Compounds Given In Table 10.1, P-101.2.7,
Chapter 10
1515(28)
Subject Index 1543