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E-grāmata: Photoelectrochemical Solar Conversion Systems: Molecular and Electronic Aspects

  • Formāts: 348 pages
  • Izdošanas datums: 19-Apr-2016
  • Izdevniecība: CRC Press Inc
  • Valoda: eng
  • ISBN-13: 9781439869260
  • Formāts - PDF+DRM
  • Cena: 77,63 €*
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  • Formāts: 348 pages
  • Izdošanas datums: 19-Apr-2016
  • Izdevniecība: CRC Press Inc
  • Valoda: eng
  • ISBN-13: 9781439869260

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Providing new insights into the molecular and electronic processes involved in the conversion of sunlight into chemical products, Photoelectrochemical Solar Conversion Systems: Molecular and Electronic Aspects begins with an historical overview and a survey of recent developments in the electrochemistry of semiconductors and spectroscopic techniques. It then provides a comprehensive introduction to the science of conversion cells, reviews current issues and potential directions, and covers a wide range of materials from organic to inorganic cells.





Employing a tutorial organization with balanced coverage of electrochemistry and solar energy conversion, this book covers:



















The conversion of sunlight into chemical energy and different actual conversion concepts





Electrochemical methods for the construction and characterization of electrolyte-metal-oxide-semiconductor contacts (EMOS) in the nanodimensions, the so-called nano-emitter concept, including the electrochemical formation of metal clusters of catalytic metals and the formation of passivating layers by anodization





The fundamentals of electrocatalysis with emphasis on the hydrogen evolution reaction and the electrochemical CO2 reduction





Classical and quantum mechanical theories of electron transfer reactions in metal-electrolyte interfaces and their relation with surface electronics





The physicochemical characterization of the model system Si-SiOx-metal-electrolyte by means of modern electrochemical, surface, and spectroscopic methods





Improvements of conversion efficiency by means of optical effects, for example, the generation of surface plasmons by nano-dimensioned arrangements of optically active metals
Preface vii
About the Author xi
Chapter 1 Principles and Systems in Light-Induced Energy Conversion
1(52)
1.1 Basic Aspects of Light-Induced Generation of Fuels
1(11)
1.2 Development of Energy Conversion Systems
12(9)
1.3 Advanced Concepts for Sunlight Energy Conversion
21(5)
1.4 Inorganic Concepts
26(7)
1.5 Energy and Electron Transfer Processes
33(20)
References
44(9)
Chapter 2 Nanodimensioned Systems Based on Semiconductor-Oxide-Metal-Electrolyte Contacts
53(90)
2.1 Fundamentals of Electrochemical Phase Formation
53(10)
2.2 Experimental Techniques and Experiment Designs
63(6)
2.3 The Electrodeposition of Selected Systems
69(26)
2.3.1 Electrodeposition of Indium
70(4)
2.3.2 Electrodeposition of Co onto Silicon
74(8)
2.3.3 Electrocrystallization of Noble Metals onto Silicon
82(7)
2.3.4 Electrodeposition onto Niobium Oxide
89(6)
2.4 Anodic Oxide Growth: Mechanisms, Methods, and Properties
95(48)
References
133(10)
Chapter 3 Physics of Electrolyte-Metal-Oxide-Semiconductor (EMOS) Contacts in Nanodimensions
143(40)
3.1 The Electron Transfer in Nanodimensioned Schottky Contacts
143(10)
3.2 Analysis of Complex Systems: The EMOS Interface
153(30)
References
179(4)
Chapter 4 Electrocatalysis on Nanodimensioned EMOS Contacts
183(60)
4.1 Fundamental Aspects of the Metal-Electrolyte Interface
183(14)
4.2 The Electron Transfer at Metal-Electrolyte Interfaces: From Butler-Volmer to Quantum Mechanical Concepts
197(6)
4.3 Reaction Mechanisms in Selected Systems: Hydrogen Evolution and CO2 Reduction
203(27)
4.4 Development of New Electrochemical Catalysts: Future Directions
230(13)
References
235(8)
Chapter 5 Electronics and Chemistry of Electrolyte-Metal-Oxide-Semiconductor Contacts
243(64)
5.1 Methods: Combination of Electrochemical Techniques with Surface-Sensitive Spectroscopy
243(14)
5.2 Chemical and Electronic Properties of Electrochemical Generated Interfaces on Silicon
257(37)
5.3 Modulation of the Interfacial Potential in Nanodimensioned EMOS Contacts
294(13)
References
301(6)
Chapter 6 Optical Effects: Current Approaches and Future Directions
307(24)
References
326(5)
Index 331
Muńoz, Andrés G.