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Introduction and historical background |
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1 | (28) |
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1 | (1) |
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2 | (7) |
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2 | (2) |
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Pseudopolymorphism, solvates, and hydrates |
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4 | (4) |
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Conventions for naming polymorphs |
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8 | (1) |
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Is this material polymorphic? |
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9 | (10) |
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Occurrence of polymorphism |
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9 | (1) |
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Literature sources of polymorphic compounds |
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10 | (5) |
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Polymorphic compounds in the Cambridge Structural Database |
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15 | (2) |
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17 | (1) |
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17 | (1) |
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Polymorphism of elements and inorganic compounds |
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17 | (1) |
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Polymorphism in macromolecular crystals |
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18 | (1) |
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19 | (8) |
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Commercial/industrial importance of polymorphism-some additional comments |
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27 | (2) |
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29 | (37) |
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29 | (1) |
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Thermodynamics of polymorphic molecular crystals |
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29 | (13) |
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29 | (2) |
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Thermodynamic relations in polymorphs |
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31 | (1) |
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Energy vs temperature diagrams-the Gibbs free energy |
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32 | (2) |
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Enantiotropism and monotropism |
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34 | (1) |
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Phase diagrams in terms of pressure and temperature |
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35 | (3) |
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38 | (1) |
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38 | (2) |
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40 | (1) |
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40 | (1) |
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40 | (1) |
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41 | (1) |
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Kinetic factors determining the formation of polymorphic modifications |
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42 | (3) |
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45 | (21) |
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46 | (3) |
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Structural characterization and comparison of polymorphic systems |
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49 | (1) |
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Presentation of polymorphic structures for comparison |
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49 | (17) |
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Controlling the polymorphic form obtained |
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66 | (28) |
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66 | (1) |
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Aggregation and nucleation |
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67 | (5) |
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Thermodynamic vs kinetic crystallization conditions |
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72 | (2) |
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Monotropism, enantiotropism, and crystallization strategy |
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74 | (1) |
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75 | (14) |
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Crystallization methods and conditions |
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76 | (4) |
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Examples of different classes of compounds |
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80 | (6) |
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86 | (3) |
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89 | (3) |
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Control of polymorphic crystallization by design |
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92 | (2) |
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Analytical techniques for studying and characterizing polymorphs |
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94 | (57) |
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94 | (1) |
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Optical/hot stage microscopy |
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94 | (10) |
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104 | (7) |
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111 | (14) |
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125 | (6) |
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131 | (2) |
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Solid state nuclear magnetic resonance (SSNMR) spectroscopy |
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133 | (11) |
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Scanning electron microscopy |
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144 | (2) |
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Atomic force microscopy (AFM) and scanning tunnelling microscopy (STM) |
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146 | (1) |
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147 | (1) |
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New technologies and `hyphenated techniques' |
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147 | (1) |
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Are two samples polymorphs of the same compound? |
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148 | (1) |
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149 | (2) |
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Conformational polymorphism: intra- and intermolecular energetics |
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151 | (37) |
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151 | (1) |
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Molecular shape and energetics |
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152 | (1) |
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Intermolecular interactions and energetics |
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152 | (4) |
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The search for examples of conformational polymorphism |
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156 | (1) |
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Presenting and comparing conformational polymorphs |
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157 | (1) |
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Some examples of conformational polymorphism |
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157 | (7) |
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What are conformational polymorphs good for? |
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164 | (1) |
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Computational studies of the energetics of polymorphic systems |
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165 | (4) |
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Some exemplary studies of conformational polymorphism |
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169 | (13) |
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The computational prediction of polymorphs |
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182 | (6) |
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Polymorphism and structure-property relations |
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188 | (52) |
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188 | (1) |
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189 | (34) |
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189 | (8) |
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Organic magnetic materials |
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197 | (7) |
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Photovoltaicity and photoconductivity |
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204 | (3) |
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Nonlinear optical activity and second harmonic generation |
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207 | (6) |
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Chromoisomerism, photochromism, thermochromism, mechanochromism, etc. |
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213 | (10) |
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Thermal phase changes and the thermosalient effect-`hopping' or `jumping' crystals |
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223 | (1) |
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223 | (11) |
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Infrared and Raman spectroscopy |
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224 | (1) |
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UV/Vis absorption spectroscopy |
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225 | (6) |
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231 | (3) |
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Excited state diffraction studies |
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234 | (1) |
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234 | (3) |
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Thermal reactions and gas-solid reactions |
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237 | (1) |
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238 | (1) |
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239 | (1) |
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Polymorphism of pharmaceuticals |
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240 | (17) |
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240 | (1) |
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Occurrence of polymorphism in pharmaceuticals |
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241 | (2) |
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241 | (1) |
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242 | (1) |
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Importance of polymorphism in pharmaceuticals |
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243 | (6) |
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Dissolution rate and solubility |
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243 | (1) |
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244 | (5) |
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Microscopy and thermomicroscopy of pharmaceuticals |
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249 | (1) |
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Thermal analysis of pharmaceuticals |
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250 | (1) |
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The importance of metastable forms |
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251 | (2) |
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The importance of amorphous forms |
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253 | (2) |
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255 | (2) |
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Polymorphism of dyes and pigments |
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257 | (18) |
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257 | (2) |
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Occurrence of polymorphism among pigments |
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259 | (1) |
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Polymorphism in some specific groups of pigments |
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259 | (12) |
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259 | (4) |
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263 | (1) |
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264 | (6) |
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Some other pigments-old and new |
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270 | (1) |
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271 | (4) |
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Polymorphism of high energy materials |
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275 | (22) |
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275 | (1) |
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The `alphabet' of high energy molecular materials |
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276 | (2) |
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278 | (19) |
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278 | (9) |
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287 | (10) |
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297 | (11) |
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297 | (1) |
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298 | (3) |
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301 | (3) |
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304 | (1) |
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305 | (2) |
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307 | (1) |
References |
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308 | (93) |
Index |
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401 | |