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1 | (10) |
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1 | (1) |
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1.2 Simple Resonance Theory |
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2 | (2) |
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1.3 Absorption of Energy and Spin-Lattice Relaxation |
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4 | (7) |
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11 | (54) |
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2.1 Motion of Isolated Spins-Classical Treatment |
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11 | (2) |
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2.2 Quantum Mechanical Description of Spin in a Static Field |
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13 | (4) |
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2.3 Equations of Motion of the Expectation Value |
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17 | (3) |
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2.4 Effect of Alternating Magnetic Fields |
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20 | (5) |
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2.5 Exponential Operators |
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25 | (4) |
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2.6 Quantum Mechanical Treatment of a Rotating Magnetic Field |
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29 | (4) |
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33 | (2) |
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2.8 Solution of the Bloch Equations for Low H1 |
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35 | (4) |
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39 | (7) |
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2.10 Quantum Mechanical Treatment of the Spin Echo |
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46 | (5) |
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2.11 Relationship Between Transient and Steady-State Response of a System and of the Real and Imaginary Parts of the Susceptibility |
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51 | (8) |
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2.12 Atomic Theory of Absorption and Dispersion |
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59 | (6) |
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3 Magnetic Dipolar Broadening of Rigid Lattices |
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65 | (22) |
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65 | (1) |
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66 | (5) |
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71 | (9) |
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3.4 Example of the Use of Second Moments |
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80 | (7) |
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4 Magnetic Interactions of Nuclei with Electrons |
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87 | (58) |
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87 | (1) |
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4.2 Experimental Facts About Chemical Shifts |
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88 | (1) |
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4.3 Quenching of Orbital Motion |
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89 | (3) |
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4.4 Formal Theory of Chemical Shifts |
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92 | (4) |
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4.5 Computation of Current Density |
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96 | (12) |
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4.6 Electron Spin Interaction |
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108 | (5) |
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113 | (14) |
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4.8 Single Crystal Spectra |
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127 | (4) |
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4.9 Second-Order Spin Effects-Indirect Nuclear Coupling |
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131 | (14) |
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5 Spin-Lattice Relaxation and Motional Narrowing of Resonance Lines |
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145 | (74) |
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145 | (1) |
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5.2 Relaxation of a System Described by a Spin Temperature |
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146 | (5) |
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5.3 Relaxation of Nuclei in a Metal |
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151 | (6) |
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5.4 Density Matrix--General Equations |
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157 | (8) |
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5.5 The Rotating Coordinate Transformation |
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165 | (4) |
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5.6 Spin Echoes Using the Density Matrix |
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169 | (5) |
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5.7 The Response to a δ-Function |
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174 | (5) |
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5.8 The Response to a π/2 Pulse: Fourier Transform NMR |
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179 | (7) |
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5.9 The Density Matrix of a Two-Level System |
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186 | (4) |
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5.10 Density Matrix--An Introductory Example |
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190 | (9) |
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5.11 Bloch-Wangsness-Redfield Theory |
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199 | (7) |
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5.12 Example of Redfield Theory |
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206 | (9) |
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5.13 Effect of Applied Alternating Fields |
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215 | (4) |
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6 Spin Temperature in Magnetism and in Magnetic Resonance |
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219 | (28) |
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219 | (1) |
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6.2 A Prediction from the Bloch Equations |
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220 | (1) |
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6.3 The Concept of Spin Temperature in the Laboratory Frame in the Absence of Alternating Magnetic Fields |
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221 | (2) |
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6.4 Adiabatic and Sudden Changes |
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223 | (8) |
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6.5 Magnetic Resonance and Saturation |
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231 | (3) |
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6.6 Redfield Theory Neglecting Lattice Coupling |
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234 | (5) |
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6.6.1 Adiabatic Demagnetization in the Rotating Frame |
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235 | (2) |
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237 | (2) |
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6.7 The Approach to Equilibrium for Weak H1 |
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239 | (2) |
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6.8 Conditions for Validity of the Redfield Hypothesis |
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241 | (1) |
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242 | (2) |
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6.10 Spin Locking, T1 Q, and Slow Motion |
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244 | (3) |
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247 | (120) |
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7.1 What Is Double Resonance and Why Do It? |
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247 | (1) |
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7.2 Basic Elements of the Overhauser-Pound Family of Double Resonance |
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248 | (2) |
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7.3 Energy Levels and Transitions of a Model System |
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250 | (4) |
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7.4 The Overhauser Effect |
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254 | (3) |
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7.5 The Overhauser Effect in Liquids: The Nuclear Overhauser Effect |
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257 | (7) |
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7.6 Polarization by Forbidden Transitions: The Solid Effect |
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264 | (2) |
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7.7 Electron-Nuclear Double Resonance (ENDOR) |
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266 | (3) |
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7.8 Bloembergen's Three-Level Maser |
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269 | (1) |
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7.9 The Problem of Sensitivity |
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270 | (1) |
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7.10 Cross-Relaxation Double Resonance |
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271 | (4) |
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7.11 The Bloembergen-Sorokin Experiment |
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275 | (2) |
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7.12 Harm's Ingenious Concept |
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277 | (2) |
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7.13 The Quantum Description |
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279 | (4) |
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7.14 The Mixing Cycle and Its Equations |
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283 | (4) |
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287 | (2) |
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7.16 The Effects of Spin-Lattice Relaxation |
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289 | (4) |
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7.17 The Pines-Gibby-Waugh Method of Cross Polarization |
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293 | (2) |
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7.18 Spin-Coherence Double Resonance-Introduction |
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295 | (1) |
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7.19 A Model System-An Elementary Experiment: The S-Flip-Only Echo |
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296 | (7) |
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303 | (8) |
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7.21 Spin Echo Double Resonance |
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311 | (8) |
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7.22 Two-Dimensional FT Spectra--The Basic Concept |
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319 | (5) |
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7.23 Two-Dimensional FT Spectra--Line Shapes |
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324 | (1) |
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7.24 Formal Theoretical Apparatus I--The Time Development of the Density Matrix |
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325 | (6) |
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331 | (13) |
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7.26 Formal Theoretical Apparatus II--The Product Operator Method |
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344 | (6) |
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7.27 The Jeener Shift Correlation (COSY) Experiment |
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350 | (7) |
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7.28 Magnetic Resonance Imaging |
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357 | (10) |
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8 Advanced Concepts in Pulsed Magnetic Resonance |
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367 | (64) |
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367 | (1) |
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8.2 The Carr-Purcell Sequence |
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367 | (2) |
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8.3 The Phase Alternation and Meiboom-Gill Methods |
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369 | (2) |
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8.4 Refocusing Dipolar Coupling |
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371 | (1) |
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371 | (9) |
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8.6 The Jeener-Broekaert Sequence for Creating Dipolar Order |
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380 | (4) |
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8.7 The Magic Angle in the Rotating Frame--The Lee-Goldburg Experiment |
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384 | (4) |
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388 | (4) |
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392 | (14) |
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8.10 The Relation of Spin-Flip Narrowing to Motional Narrowing |
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406 | (3) |
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8.11 The Formal Description of Spin-Rip Narrowing |
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409 | (7) |
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8.12 Observation of the Spin-Flip Narrowing |
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416 | (5) |
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8.13 Real Pulses and Sequences |
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421 | (2) |
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8.13.1 Avoiding a z-Axis Rotation |
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421 | (1) |
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8.13.2 Nonideality of Pulses |
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422 | (1) |
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8.14 Analysis of and More Uses for Pulse Sequence |
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423 | (8) |
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9 Multiple Quantum Coherence |
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431 | (54) |
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431 | (3) |
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9.2 The Feasibility of Generating Multiple Quantum Coherence--Frequency Selective Pumping |
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434 | (10) |
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9.3 Nonselective Excitation |
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444 | (26) |
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9.3.1 The Need for Nonselective Excitation |
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444 | (1) |
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9.3.2 Generating Multiple Quantum Coherence |
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445 | (4) |
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9.3.3 Evolution, Mixing, and Detection of Multiple Quantum Coherence |
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449 | (6) |
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9.3.4 Three or More Spins |
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455 | (8) |
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9.3.5 Selecting the Signal of a Particular Order of Coherence |
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463 | (7) |
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9.4 High Orders of Coherence |
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470 | (15) |
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9.4.1 Generating a Desired Order of Coherence |
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471 | (9) |
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9.4.2 Mixing to Detect High Orders of Coherence |
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480 | (5) |
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10 Electric Quadrupole Effects |
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485 | (18) |
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485 | (1) |
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10.2 Quadrupole Hamiltonian -- Part 1 |
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486 | (3) |
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10.3 Clebsch-Gordan Coefficients, Irreducible Tensor Operators, and the Wigner-Eckart Theorem |
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489 | (5) |
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10.4 Quadrupole Hamiltonian -- Part 2 |
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494 | (3) |
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10.5 Examples at Strong and Weak Magnetic Fields |
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497 | (3) |
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10.6 Computation of Field Gradients |
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500 | (3) |
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11 Electron Spin Resonance |
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503 | (52) |
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503 | (2) |
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11.2 Example of Spin-Orbit Coupling and Crystalline Fields |
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505 | (11) |
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516 | (8) |
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11.4 Electron Spin Echoes |
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524 | (9) |
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533 | (22) |
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555 | (2) |
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557 | (22) |
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579 | (50) |
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A A Theorem About Exponential Operators |
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579 | (1) |
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B Some Further Expressions for the Susceptibility |
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580 | (4) |
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C Derivation of the Correlation Function for a Field That Jumps Randomly Between ± h0 |
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584 | (1) |
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D A Theorem from Perturbation Theory |
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585 | (4) |
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E The High Temperature Approximation |
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589 | (3) |
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F The Effects of Changing the Precession Frequency -- Using NMR to Study Rate Phenomena |
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592 | (5) |
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G Diffusion in an Inhomogeneous Magnetic Field |
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597 | (4) |
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H The Equivalence of Three Quantum Mechanics Problems |
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601 | (4) |
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605 | (11) |
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J Time-Dependent Hamiltonians |
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616 | (7) |
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K Correction Terms in Average Hamiltonian Theory -- The Magnus Expansion |
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623 | (6) |
Selected Bibliography |
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629 | (10) |
References |
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639 | (8) |
Author Index |
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647 | (4) |
Subject Index |
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651 | |