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Principles of Magnetic Resonance Third Edition 1990 [Mīkstie vāki]

  • Formāts: Paperback / softback, 658 pages, height x width: 235x155 mm, weight: 1021 g, XII, 658 p., 1 Paperback / softback
  • Sērija : Springer Series in Solid-State Sciences 1
  • Izdošanas datums: 06-Dec-2010
  • Izdevniecība: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
  • ISBN-10: 3642080693
  • ISBN-13: 9783642080692
  • Mīkstie vāki
  • Cena: 140,62 €*
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  • Formāts: Paperback / softback, 658 pages, height x width: 235x155 mm, weight: 1021 g, XII, 658 p., 1 Paperback / softback
  • Sērija : Springer Series in Solid-State Sciences 1
  • Izdošanas datums: 06-Dec-2010
  • Izdevniecība: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
  • ISBN-10: 3642080693
  • ISBN-13: 9783642080692
The first edition of this book was written in 1961 when I was Morris Loeb Lecturer in Physics at Harvard. In the preface I wrote: "The problem faced by a beginner today is enormous. If he attempts to read a current article, he often finds that the first paragraph refers to an earlier paper on which the whole article is based, and with which the author naturally assumes familiarity. That reference in turn is based on another, so the hapless student finds himself in a seemingly endless retreat. I have felt that graduate students or others beginning research in magnetic resonance needed a book which really went into the details of calculations, yet was aimed at the beginner rather than the expert. " The original goal was to treat only those topics that are essential to an understanding of the literature. Thus the goal was to be selective rather than comprehensive. With the passage of time, important new concepts were becoming so all-pervasive that I felt the need to add them. That led to the second edition, which Dr. Lotsch, Physics Editor of Springer-Verlag, encouraged me to write and which helped launch the Springer Series in Solid-State Sciences. Now, ten years later, that book (and its 1980 revised printing) is no longer available. Meanwhile, workers in magnetic resonance have continued to develop startling new insights.

Recenzijas

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"The clarity and style in which the book is written reveals Slichter`s research expertise and talent as an excellent teacher and expositor." Physics Today

Papildus informācija

Springer Book Archives
1 Elements of Resonance
1(10)
1.1 Introduction
1(1)
1.2 Simple Resonance Theory
2(2)
1.3 Absorption of Energy and Spin-Lattice Relaxation
4(7)
2 Basic Theory
11(54)
2.1 Motion of Isolated Spins-Classical Treatment
11(2)
2.2 Quantum Mechanical Description of Spin in a Static Field
13(4)
2.3 Equations of Motion of the Expectation Value
17(3)
2.4 Effect of Alternating Magnetic Fields
20(5)
2.5 Exponential Operators
25(4)
2.6 Quantum Mechanical Treatment of a Rotating Magnetic Field
29(4)
2.7 Bloch Equations
33(2)
2.8 Solution of the Bloch Equations for Low H1
35(4)
2.9 Spin Echoes
39(7)
2.10 Quantum Mechanical Treatment of the Spin Echo
46(5)
2.11 Relationship Between Transient and Steady-State Response of a System and of the Real and Imaginary Parts of the Susceptibility
51(8)
2.12 Atomic Theory of Absorption and Dispersion
59(6)
3 Magnetic Dipolar Broadening of Rigid Lattices
65(22)
3.1 Introduction
65(1)
3.2 Basic Interaction
66(5)
3.3 Method of Moments
71(9)
3.4 Example of the Use of Second Moments
80(7)
4 Magnetic Interactions of Nuclei with Electrons
87(58)
4.1 Introduction
87(1)
4.2 Experimental Facts About Chemical Shifts
88(1)
4.3 Quenching of Orbital Motion
89(3)
4.4 Formal Theory of Chemical Shifts
92(4)
4.5 Computation of Current Density
96(12)
4.6 Electron Spin Interaction
108(5)
4.7 Knight Shift
113(14)
4.8 Single Crystal Spectra
127(4)
4.9 Second-Order Spin Effects-Indirect Nuclear Coupling
131(14)
5 Spin-Lattice Relaxation and Motional Narrowing of Resonance Lines
145(74)
5.1 Introduction
145(1)
5.2 Relaxation of a System Described by a Spin Temperature
146(5)
5.3 Relaxation of Nuclei in a Metal
151(6)
5.4 Density Matrix--General Equations
157(8)
5.5 The Rotating Coordinate Transformation
165(4)
5.6 Spin Echoes Using the Density Matrix
169(5)
5.7 The Response to a δ-Function
174(5)
5.8 The Response to a π/2 Pulse: Fourier Transform NMR
179(7)
5.9 The Density Matrix of a Two-Level System
186(4)
5.10 Density Matrix--An Introductory Example
190(9)
5.11 Bloch-Wangsness-Redfield Theory
199(7)
5.12 Example of Redfield Theory
206(9)
5.13 Effect of Applied Alternating Fields
215(4)
6 Spin Temperature in Magnetism and in Magnetic Resonance
219(28)
6.1 Introduction
219(1)
6.2 A Prediction from the Bloch Equations
220(1)
6.3 The Concept of Spin Temperature in the Laboratory Frame in the Absence of Alternating Magnetic Fields
221(2)
6.4 Adiabatic and Sudden Changes
223(8)
6.5 Magnetic Resonance and Saturation
231(3)
6.6 Redfield Theory Neglecting Lattice Coupling
234(5)
6.6.1 Adiabatic Demagnetization in the Rotating Frame
235(2)
6.6.2 Sudden Pulsing
237(2)
6.7 The Approach to Equilibrium for Weak H1
239(2)
6.8 Conditions for Validity of the Redfield Hypothesis
241(1)
6.9 Spin-Lattice Effects
242(2)
6.10 Spin Locking, T1 Q, and Slow Motion
244(3)
7 Double Resonance
247(120)
7.1 What Is Double Resonance and Why Do It?
247(1)
7.2 Basic Elements of the Overhauser-Pound Family of Double Resonance
248(2)
7.3 Energy Levels and Transitions of a Model System
250(4)
7.4 The Overhauser Effect
254(3)
7.5 The Overhauser Effect in Liquids: The Nuclear Overhauser Effect
257(7)
7.6 Polarization by Forbidden Transitions: The Solid Effect
264(2)
7.7 Electron-Nuclear Double Resonance (ENDOR)
266(3)
7.8 Bloembergen's Three-Level Maser
269(1)
7.9 The Problem of Sensitivity
270(1)
7.10 Cross-Relaxation Double Resonance
271(4)
7.11 The Bloembergen-Sorokin Experiment
275(2)
7.12 Harm's Ingenious Concept
277(2)
7.13 The Quantum Description
279(4)
7.14 The Mixing Cycle and Its Equations
283(4)
7.15 Energy and Entropy
287(2)
7.16 The Effects of Spin-Lattice Relaxation
289(4)
7.17 The Pines-Gibby-Waugh Method of Cross Polarization
293(2)
7.18 Spin-Coherence Double Resonance-Introduction
295(1)
7.19 A Model System-An Elementary Experiment: The S-Flip-Only Echo
296(7)
7.20 Spin Decoupling
303(8)
7.21 Spin Echo Double Resonance
311(8)
7.22 Two-Dimensional FT Spectra--The Basic Concept
319(5)
7.23 Two-Dimensional FT Spectra--Line Shapes
324(1)
7.24 Formal Theoretical Apparatus I--The Time Development of the Density Matrix
325(6)
7.25 Coherence Transfer
331(13)
7.26 Formal Theoretical Apparatus II--The Product Operator Method
344(6)
7.27 The Jeener Shift Correlation (COSY) Experiment
350(7)
7.28 Magnetic Resonance Imaging
357(10)
8 Advanced Concepts in Pulsed Magnetic Resonance
367(64)
8.1 Introduction
367(1)
8.2 The Carr-Purcell Sequence
367(2)
8.3 The Phase Alternation and Meiboom-Gill Methods
369(2)
8.4 Refocusing Dipolar Coupling
371(1)
8.5 Solid Echoes
371(9)
8.6 The Jeener-Broekaert Sequence for Creating Dipolar Order
380(4)
8.7 The Magic Angle in the Rotating Frame--The Lee-Goldburg Experiment
384(4)
8.8 Magic Echoes
388(4)
8.9 Magic Angle Spinning
392(14)
8.10 The Relation of Spin-Flip Narrowing to Motional Narrowing
406(3)
8.11 The Formal Description of Spin-Rip Narrowing
409(7)
8.12 Observation of the Spin-Flip Narrowing
416(5)
8.13 Real Pulses and Sequences
421(2)
8.13.1 Avoiding a z-Axis Rotation
421(1)
8.13.2 Nonideality of Pulses
422(1)
8.14 Analysis of and More Uses for Pulse Sequence
423(8)
9 Multiple Quantum Coherence
431(54)
9.1 Introduction
431(3)
9.2 The Feasibility of Generating Multiple Quantum Coherence--Frequency Selective Pumping
434(10)
9.3 Nonselective Excitation
444(26)
9.3.1 The Need for Nonselective Excitation
444(1)
9.3.2 Generating Multiple Quantum Coherence
445(4)
9.3.3 Evolution, Mixing, and Detection of Multiple Quantum Coherence
449(6)
9.3.4 Three or More Spins
455(8)
9.3.5 Selecting the Signal of a Particular Order of Coherence
463(7)
9.4 High Orders of Coherence
470(15)
9.4.1 Generating a Desired Order of Coherence
471(9)
9.4.2 Mixing to Detect High Orders of Coherence
480(5)
10 Electric Quadrupole Effects
485(18)
10.1 Introduction
485(1)
10.2 Quadrupole Hamiltonian -- Part 1
486(3)
10.3 Clebsch-Gordan Coefficients, Irreducible Tensor Operators, and the Wigner-Eckart Theorem
489(5)
10.4 Quadrupole Hamiltonian -- Part 2
494(3)
10.5 Examples at Strong and Weak Magnetic Fields
497(3)
10.6 Computation of Field Gradients
500(3)
11 Electron Spin Resonance
503(52)
11.1 Introduction
503(2)
11.2 Example of Spin-Orbit Coupling and Crystalline Fields
505(11)
11.3 Hyperfine Structure
516(8)
11.4 Electron Spin Echoes
524(9)
11.5 Vk Center
533(22)
12 Summary
555(2)
Problems
557(22)
Appendixes
579(50)
A A Theorem About Exponential Operators
579(1)
B Some Further Expressions for the Susceptibility
580(4)
C Derivation of the Correlation Function for a Field That Jumps Randomly Between ± h0
584(1)
D A Theorem from Perturbation Theory
585(4)
E The High Temperature Approximation
589(3)
F The Effects of Changing the Precession Frequency -- Using NMR to Study Rate Phenomena
592(5)
G Diffusion in an Inhomogeneous Magnetic Field
597(4)
H The Equivalence of Three Quantum Mechanics Problems
601(4)
I Powder Patterns
605(11)
J Time-Dependent Hamiltonians
616(7)
K Correction Terms in Average Hamiltonian Theory -- The Magnus Expansion
623(6)
Selected Bibliography 629(10)
References 639(8)
Author Index 647(4)
Subject Index 651