Preface |
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xi | |
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xv | |
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xxiii | |
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List of abbreviations and acronyms |
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xxvii | |
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1 The traditional measurement of ozone concentration in the atmosphere |
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1 | (78) |
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1 | (4) |
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1.1.1 Observations of the total ozone column |
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4 | (1) |
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1.2 Ground-based instrumentation for TOC observations |
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5 | (29) |
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1.2.1 The Dobson ozone spectrophotometer |
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7 | (3) |
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1.2.2 Intercomparison of Dobson spectrophotometers |
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10 | (9) |
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1.2.3 Interference of SO2 and NO2 in Dobson TOC measurements |
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19 | (5) |
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1.2.4 Influence of stray light on Dobson TOC measurements |
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24 | (10) |
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1.3 Brewer Spectrophotometer |
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34 | (3) |
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1.4 Filter ozonometers M-83/124/134 |
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37 | (2) |
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1.5 Secondary ground-based instrumentation for TOC observations |
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39 | (11) |
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1.5.1 System for Analysis of Observation at Zenith (SAOZ) |
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42 | (1) |
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1.5.2 MICROTOPS II (Total Ozone Portable Spectrometer) |
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42 | (1) |
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1.5.3 High-Resolution Visible/Ultraviolet Absorption Spectros-copy |
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43 | (1) |
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1.5.4 Fourier transform spectrometer (FTS) |
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43 | (3) |
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1.5.5 System for the Monitoring of Stratospheric Compounds (SYMOCS) |
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46 | (1) |
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1.5.6 Star Pointing Spectrometer (SPS) |
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46 | (1) |
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1.5.7 MDR-23 (a Russian commercial device) |
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46 | (1) |
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1.5.8 Scanning spectrometer (EVA) |
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47 | (1) |
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1.5.9 Solar IR spectroradiometer |
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47 | (1) |
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1.5.10 Ground-based UV radiometer (GUV) |
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47 | (1) |
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1.5.11 Spectrometer-Ozonometer PION |
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48 | (1) |
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1.5.12 SPectrometer for Atmospheric TRAcers Monitoring (SPATRAM) |
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48 | (2) |
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1.6 Observations of ozone vertical profile (OVP) |
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50 | (11) |
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1.6.1 Primary ground-based instrumentation for OVP observations |
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50 | (1) |
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1.6.2 Dobson Umkchr measurements and inversion |
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51 | (3) |
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1.6.3 Brewer Umkchr measurements |
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54 | (1) |
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1.6.4 Secondary ground-based instrumentation for OVP observations |
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55 | (1) |
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55 | (1) |
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1.6.6 Microwave radiometry |
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56 | (1) |
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1.6.7 Ground-based Millimeter wave Ozone Spectrometer (GROMOS) |
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57 | (1) |
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1.6.8 Stratospheric Sounding by Infrared Heterodyne Spectroscopy (SIRHS) |
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57 | (1) |
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1.6.9 Ground-based microwave radiometers |
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58 | (1) |
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1.6.10 Ground-based infrared solar spectroscopy |
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59 | (1) |
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1.6.11 Stratospheric Ozone Monitoring Radiometer (SOMORA) |
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59 | (2) |
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1.7 Airborne instrumentation for OVP observations |
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61 | (16) |
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1.7.1 Electrochemical ozonesondes |
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61 | (3) |
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1.7.2 Optical ozonesondes |
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64 | (3) |
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1.7.3 Other balloon instrumentation |
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67 | (4) |
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1.7.4 Aircraft instrumentation |
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71 | (6) |
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1.8 Surface ozone measurements |
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77 | (2) |
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1.8.1 Chemiluminescenee method |
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77 | (1) |
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1.8.2 Electrochemical potassium iodide method |
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77 | (1) |
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1.8.3 UV absorption method |
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77 | (2) |
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2 Satellite systems for studies of atmospheric ozone |
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79 | (70) |
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2.1 Satellite remote sounding of TOC |
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82 | (1) |
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2.2 Direct absorption measuring instruments |
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83 | (3) |
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2.2.1 TIROS Operational Vertical Sounder (TOVS); GOES |
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83 | (2) |
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2.2.2 Laser Heterodyne Spectrometer (LHS)/Tunablc Diode LHS (TDLHS) |
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85 | (1) |
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86 | (1) |
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2.3 Indirect absorption measuring instruments |
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86 | (16) |
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2.3.1 Total Ozone Mapping Spectrometer (TOMS) |
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86 | (4) |
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2.3.2 Ozone Monitoring Instrument (OMI) |
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90 | (3) |
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2.3.3 Advanced Earth Observing Satellite (ADEOS I, II) |
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93 | (1) |
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2.3.4 Solar Backscattered Ultraviolet Radiometer (SBUV) |
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93 | (3) |
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2.3.5 Global Ozone Monitoring Experiment (GOME) |
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96 | (2) |
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98 | (1) |
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2.3.7 The Ozone Mapping and Profiler Suite (OMPS) and the NPOESS |
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99 | (2) |
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2.3.8 Ozone Dynamics Ultraviolet Spectrometer (ODUS) |
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101 | (1) |
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2.3.9 Ozone Layer Monitoring Experiment (OLME) |
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101 | (1) |
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2.3.10 Interferometric Monitor for Greenhouse Gases (IMG) |
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101 | (1) |
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2.3.11 Infrared Atmospheric Sounding Interferometer |
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102 | (1) |
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2.4 Observed variability in total ozone column |
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102 | (4) |
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2.4.1 Latitudinal variation of TOC |
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102 | (4) |
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2.4.2 Longitudinal variation of TOC |
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106 | (1) |
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2.5 Satellite instrumentation for OVP observations |
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106 | (24) |
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2.5.1 Direct-absorption measuring instruments |
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107 | (9) |
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2.5.2 Scattering-measuring instruments |
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116 | (2) |
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2.5.3 Emission-measuring instruments |
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118 | (12) |
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2.5.4 Summary of ozone-monitoring satellites |
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130 | (1) |
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2.6 Observed variability in vertical ozone distribution |
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130 | (19) |
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141 | (1) |
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142 | (1) |
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142 | (1) |
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142 | (1) |
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143 | (1) |
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144 | (1) |
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144 | (1) |
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145 | (4) |
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3 Intercomparisons between various atmospheric ozone datasets |
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149 | (106) |
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149 | (3) |
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3.2 Total ozone measurements over Athens: intercomparison between Dobson, TOMS (version 7), SBUV, and other satellite measurements |
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152 | (9) |
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3.3 Geophysical validation of MIPAS-ENVISAT operational ozone data |
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161 | (29) |
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3.3.1 Introduction to MIPAS |
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161 | (2) |
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163 | (1) |
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3.3.3 Comparison of MIPAS data with WMO/GAW ground-based measurements |
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164 | (26) |
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3.4 Comparison of MIPAS data with stratospheric balloon and aircraft measurements |
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190 | (18) |
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190 | (3) |
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193 | (5) |
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198 | (2) |
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3.4.4 MIPAS-STR, SAFIRE-A, and FOZAN on board the M-55 Geophysica aircraft |
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200 | (7) |
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207 | (1) |
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3.5 Comparison with satellite measurements |
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208 | (26) |
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3.5.1 Comparison of MIPAS data with SAGE II O3 profiles |
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211 | (2) |
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3.5.2 Comparison with POAM III O3 profiles |
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213 | (3) |
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3.5.3 Comparison with Odin-SMR O3 profiles |
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216 | (4) |
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3.5.4 Comparison with ACE-FTS O3 profiles |
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220 | (3) |
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3.5.5 Comparison with HALOE O3 profiles |
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223 | (6) |
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3.5.6 Comparison with GOME O3 profiles |
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229 | (2) |
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3.5.7 Comparison with SCIAMACHY and GOMOS |
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231 | (3) |
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3.6 Comparison of MIPAS data with ECMWF assimilated fields |
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234 | (2) |
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3.7 Summary of MIPAS comparisons |
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236 | (8) |
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3.8 Other intercomparisons between various ozone-monitoring systems |
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244 | (11) |
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3.8.1 TOMS, GOME, GOMOS, and SCIAMACHY data |
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245 | (3) |
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248 | (1) |
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249 | (1) |
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250 | (1) |
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250 | (4) |
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3.8.6 Ozonesonde intercomparisons |
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254 | (1) |
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4 The dynamics of atmospheric ozone |
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255 | (84) |
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257 | (16) |
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4.2 Ozone vertical profile variability |
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273 | (14) |
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4.3 General features of ozone global distribution |
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287 | (19) |
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4.3.1 Stratosphere troposphere exchange |
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293 | (5) |
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298 | (8) |
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4.4 The non-linear nature of ozone variability; detrended fluctuation analysis (DFA) |
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306 | (16) |
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4.4.1 Long-memory processes in global ozone and temperature variations |
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307 | (7) |
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4.4.2 Long-term memory dynamics of total ozone content |
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314 | (3) |
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4.4.3 Scaling behavior of the global tropopause |
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317 | (4) |
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4.4.4 Scaling properties of air pollution at the surface; surface ozone (SOZ) |
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321 | (1) |
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4.5 Impacts of the solar eclipse of March 29, 2006 on surface ozone and related air pollutants |
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322 | (5) |
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4.6 Long-term coupling between TOC and tropopause properties |
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327 | (12) |
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4.6.1 Occurrence frequency of tropopause height |
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329 | (4) |
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4.6.2 Association between tropopause properties and TOC |
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333 | (3) |
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4.6.3 The tropopause; summary |
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336 | (3) |
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339 | (40) |
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339 | (1) |
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5.2 The proposition by Molina and Rowland of human releases of CFCs being responsible for ozone depiction |
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340 | (4) |
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5.3 The science from 1974 to 1985 |
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344 | (7) |
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351 | (7) |
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5.5 The role of remote sensing in the lead-up to the Montreal Protocol |
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358 | (1) |
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5.6 The NOZE and AAOE expeditions |
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358 | (5) |
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5.7 Theories of the Ozone Hole |
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363 | (3) |
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5.8 Diplomacy, 1974-1989; formulation and ratification of the Montreal Protocol |
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366 | (2) |
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5.9 Reasons for the success in reaching international agreement in Montreal |
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368 | (4) |
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5.10 Ratification of the Montreal Protocol |
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372 | (7) |
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6 The study of atmospheric ozone since 1987 |
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379 | (106) |
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379 | (1) |
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6.2 The reduction of ozone-destroying chemicals in the atmosphere |
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379 | (9) |
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6.2.1 Ozone depletion potential (ODP) |
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382 | (3) |
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6.2.2 Equivalent Effective Stratospheric Chlorine (EESC) |
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385 | (3) |
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6.3 Ground-based and ozonesonde data on ozone depletion |
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388 | (2) |
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6.4 Piecewise linear trends in ozone depletion |
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390 | (16) |
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6.5 Recovery of the ozone layer; the polar regions |
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406 | (42) |
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6.5.1 Sudden stratospheric warmings |
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415 | (2) |
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6.5.2 Observation of sudden stratospheric warmings detected in deep underground muon data |
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417 | (3) |
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6.5.3 The role of the diffusion of gases in ice or an amorphous binary mixture in the polar stratosphere and the upper troposphere |
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420 | (5) |
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6.5.4 Experimental studies of the Antarctic ozone hole and ozone loss in the Arctic |
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425 | (16) |
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6.5.5 Antarctic ozone hole predictability; use of natural time series |
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441 | (7) |
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6.6 Long-term monitoring of the ozone layer |
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448 | (30) |
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6.6.1 Measurement of TOC and the OVP |
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452 | (2) |
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6.6.2 The use of models to predict ozone concentration |
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454 | (15) |
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6.6.3 Ozonesonde networks |
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469 | (5) |
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6.6.4 Trends in TOC and tropopause properties |
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474 | (4) |
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6.7 Scientific assessment of ozone depletion 2010 |
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478 | (7) |
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7 Atmospheric ozone and climate |
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485 | (74) |
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485 | (7) |
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7.2 Radiative-forcing calculations |
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492 | (25) |
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7.2.1 Estimates of changes in RF from pre-industrial times to the present |
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492 | (5) |
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7.2.2 Detailed studies of changes in RF in recent decades |
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497 | (18) |
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7.2.3 Contribution of the transport sector |
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515 | (2) |
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7.3 Ozone-induced climatic impacts |
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517 | (27) |
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7.3.1 The health impacts of changes in ozone concentration |
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543 | (1) |
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7.4 Conclusions on tropo-stratospheric variability |
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544 | (3) |
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7.4.1 Stratospheric ozone dynamics and its determining factors |
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545 | (1) |
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7.4.2 Tropospheric processes |
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546 | (1) |
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7.5 New climate research aspects deduced from global ozone dynamics research and remote sensing |
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547 | (7) |
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7.5.1 Climate modeling and atmospheric ozone |
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547 | (2) |
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7.5.2 Role of phase transitions in climate system dynamics |
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549 | (1) |
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7.5.3 Nambu dynamics and ozone climate modeling |
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550 | (1) |
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7.5.4 Dissipation-induced instabilities in ozone and climate fields |
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551 | (2) |
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7.5.5 Deterministic, chaotic, or stochastic ozone climate time series |
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553 | (1) |
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7.6 WMO/UNEP Scientific Assessment 2010 |
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554 | (5) |
References and bibliography |
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559 | (94) |
Index |
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653 | |