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E-grāmata: Single Particle Nanocatalysis: Fundamentals and Applications

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  • Formāts: EPUB+DRM
  • Izdošanas datums: 04-Feb-2019
  • Izdevniecība: Blackwell Verlag GmbH
  • Valoda: eng
  • ISBN-13: 9783527809714
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Single Particle Nanocatalysis: Fundamentals and ApplicationsPalielināt
  • Formāts: EPUB+DRM
  • Izdošanas datums: 04-Feb-2019
  • Izdevniecība: Blackwell Verlag GmbH
  • Valoda: eng
  • ISBN-13: 9783527809714
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Introduces the detailed basis and recent development of single molecule/particle nanocatalysis based on single molecule techniques

This unique book introduces and summarizes the recent development of single molecule/particle nanocatalysis to provide both comprehensive coverage of fundamentals for different methods now in widespread use and the extensive applications in different catalytic systems. Chapters are mainly based on different detection methods, including single molecule fluorescence microscopy, surface plasmon resonance spectroscopy, X-ray microscopy, and surface enhanced Raman spectroscopy. The book also includes numerous basic principles of different methods and application examples and features illustrations that help clarify presentations.

Single Particle Nanocatalysis: Fundamentals and Applications starts with the history and development of single molecule techniques for nanocatalysis. It then shows readers how single molecule fluorescence microscopy (SMFM) reveals catalytic kinetics and dynamics of individual nanocatalysts. Next, it examines traditional SMFM-based single molecule nanocatalysis without super-resolution (SR) imaging, before moving on to the topic of SMFM-based SR imaging in single molecule nanocatalysis. Following chapters cover scanning electrochemical microscopy for single particle nanocatalysis; surface plasmon resonance spectroscopy for single particle nanocatalysis/reactions; X-ray-based microscopy of single-particle nanocatalysis; and surface-enhanced Raman spectroscopy for single particle nanocatalysis. The book finishes by introducing some less-practiced techniques for single particle nanocatalysis/electrochemistry.

-Presents a systematical and complete introduction to the subject of single particle nanocatalysis covering all of its fundamentals and applications
-Helps readers fully understand the basis, role, and recent development of single molecule nanocatalysis
-Teaches researchers how to gain new knowledge to successfully conduct their own studies within this rapidly increasing new area of research

Single Particle Nanocatalysis: Fundamentals and Applications is an excellent reference book for experts in this area as well as for general researchers who want to learn how to study nanocatalysis at single molecule/particle level.
Preface xi
1 The History/Development of Single Particle Nanocatalysis
1(8)
1.1 History of Single Particle Nanocatalysis Based on Single Molecule Fluorescence Microscopy
2(1)
1.2 History of Single Particle Nanocatalysis Based on (Localized) Surface Plasmon Resonance
3(1)
1.3 History of Single Particle Nanocatalysis Based on Scanning Electrochemical Microscopy
4(1)
1.4 History of Single Particle Nanocatalysis Based on Vibrational Spectroscopies
5(1)
References
6(3)
2 Single Molecule Nanocatalysis Reveals Catalytic Kinetics and Thermodynamics of Individual Nanocatalysts
9(40)
2.1 Single Molecule Enzymology
9(14)
2.1.1 Single Molecule Michaelis--Menten Kinetics in the Absence of Dynamic Disorder
9(4)
2.1.2 Single Molecule Michaelis--Menten Kinetics with Dynamic Disorder
13(7)
2.1.3 Randomness Parameter
20(1)
2.1.4 Single Molecule Michaelis-Menten Kinetics for Fluorogenic Reaction in the Absence of Dynamic Disorder
21(2)
2.2 Physical Models for Kinetic and Dynamic Analysis of Single Molecule Nanocatalysts
23(8)
2.2.1 Langmuir--Hinshelwood Mechanism for Noncompetitive Heterogeneous Catalysis
23(1)
2.2.1.1 Langmuir--Hinshelwood Mechanism for Product Formation
24(3)
2.2.1.2 Two-Pathway Model for Production Dissociation
27(2)
2.2.1.3 Overall Turnover Rate
29(1)
2.2.2 Langmuir--Hinshelwood Mechanism for Competitive Heterogeneous Catalysis
30(1)
2.3 Comparison Between Michaelis--Menten Mechanism and Noncompetitive Langmuir--Hinshelwood Mechanism
31(1)
2.4 Michaelis--Menten Mechanism Coupled with Multiple Product Dissociation Pathways
32(3)
2.4.1 Product Dissociation Process
32(1)
2.4.2 Product Formation Process
33(2)
2.5 Application of Langmuir--Hinshelwood Mechanism to Oligomeric Enzymes
35(1)
2.6 Applications of Competitive/Noncompetitive Langmuir--Hinshelwood Models in Single Molecule Nanocatalysis
35(9)
2.6.1 Applications of Noncompetitive Langmuir--Hinshelwood Models in Single Molecule Nanocatalysis
35(1)
2.6.1.1 Single Molecule Nanocatalysis on Single Au Nanoparticles
35(3)
2.6.1.2 Single Molecule Photocatalysis on Single TiO2 Nanoparticles
38(3)
2.6.2 Applications of Competitive Langmuir--Hinshelwood Models in Single Molecule Nanocatalysis
41(1)
2.6.2.1 Single Pt Nanocatalyst Behaves Differently in Different Reactions
41(1)
2.6.2.2 Single Molecule Nanocatalysis at Subparticle Level
42(2)
2.7 Single Molecule Nanocatalysis Reveals the Catalytic Thermodynamics of Single Nanocatalysts
44(2)
Abbreviation
46(1)
References
46(3)
3 Combination of Traditional SMFM with Other Techniques for Single Molecule/Particle Nanocatalysis
49(14)
3.1 Introduction of SMFM-Based Single Particle Nanocatalysis Analysis Method
49(1)
3.2 SMFM Combining with Electrochemical Techniques
49(8)
3.3 SMFM Combining with AFM
57(3)
3.4 Conclusion
60(1)
Abbreviations
60(1)
References
60(3)
4 Optical Super-Resolution Imaging in Single Molecule Nanocatalysis
63(44)
4.1 History and Principle of Different Optical Super-Resolution (SR) Techniques
63(5)
4.1.1 History of Optical Super-Resolution (SR) Techniques
63(2)
4.1.2 Principle of Optical Super-Resolution (SR) Imaging
65(1)
4.1.2.1 Super-Resolution Imaging with Spatially Patterned Excitation
65(1)
4.1.2.2 Localization Microscopy: Super-Resolution Imaging Based on Single Molecule Localization
66(2)
4.2 Application of Super-Resolution Imaging in Single Particle Catalysis
68(24)
4.2.1 Layered Double Hydroxide (LDH)
69(1)
4.2.2 Zeolites
69(1)
4.2.2.1 Super-Resolution Imaging on Zeolites
69(5)
4.2.2.2 Depth Profiling with Super-Resolution Imaging on Zeolites
74(2)
4.2.3 Metal Nanoparticles
76(3)
4.2.4 Supported Metal Nanocatalysts
79(1)
4.2.5 Semiconductors as Photo(electro)catalysts
80(2)
4.2.5.1 Active Site/Facet Mapping
82(1)
4.2.5.2 Photogenerated Charge Separation
82(2)
4.2.5.3 Design a Photo(electro)catalyst
84(2)
4.2.6 Electrocatalysts
86(1)
4.2.7 Imaging the Chemical Reactions
87(1)
4.2.7.1 Kinetic Studies of Single Molecule Fluorogenic Reactions
87(2)
4.2.7.2 SR Imaging of the Single Molecule Reactions on Different Surfaces
89(2)
4.2.8 Other Applications of SR Imaging Technique
91(1)
4.3 Summary
92(1)
Abbreviations
92(1)
References
93(14)
5 Scanning Electrochemical Microscopy (SECM) for Single Particle Nanocatalysis
107(38)
5.1 Brief Review of Scanning Electrochemical Microscopy (SECM)
107(2)
5.2 Principles of SECM
109(9)
5.2.1 Preparation of Nanoelectrodes
111(1)
5.2.1.1 Fabrication Method 1: Electron Beam Lithography
111(2)
5.2.1.2 Fabrication Method 2: Glass-Coated Electrode
113(1)
5.2.2 Operation Modes of SECM
113(1)
5.2.2.1 Collection Mode
113(4)
5.2.2.2 Feedback Mode
117(1)
5.3 Preparation of Single Nanoparticle Samples for Electrocatalytic Studies
118(9)
5.3.1 "Jump-to-contact" Method for Preparing Single Nanoparticles Based on Tip-Induced Deposition of Metal
119(1)
5.3.2 Electrochemical Methods of Preparing and Characterizing Single-Metal NPs
120(1)
5.3.2.1 Direct Electrodepositing of Single-Metal NPs on a Macroscopic Substrate
121(2)
5.3.2.2 Mechanical Transfer of the Nanoparticle from the Tip
123(1)
5.3.2.3 Anodization of Tip Material
124(1)
5.3.2.4 Single-Nanoparticle Formation on Ultramicroscopic Substrate
124(1)
5.3.3 Determining Electroactive Radii of the Substrate
125(2)
5.4 Examples of Typical Experimental Data Analysis Process
127(14)
5.4.1 Pt NPs/C UME/Proton Reduction
128(2)
5.4.2 Water Oxidation on IrOx NP
130(3)
5.4.3 Hydrogen Evolution Reaction (HER) at the Pd NP
133(4)
5.4.4 Screening of ORR Catalysts
137(4)
5.5 Summary
141(1)
Abbreviations
141(1)
References
142(3)
6 Surface Plasmon Resonance Spectroscopy for Single Particle Nanocatalysis/Reaction
145(36)
6.1 Bulk, Surface, and Localized Surface (Nanoparticle) Plasmons
145(1)
6.2 SPR on Single Particle Catalysis at Single Particle Level
146(4)
6.2.1 Principle of SPR Sensing
146(3)
6.2.2 Experimental Method of SPR on Single Particle Catalysis
149(1)
6.2.3 Application: Electrocatalysis of Single Pt Nanoparticles Based on SPR
150(1)
6.3 LSPR on Single Particle Catalysis/Reaction at Single Particle Level
150(24)
6.3.1 Principle of LSPR Sensing
150(2)
6.3.1.1 Electron Injection and Spillover
152(1)
6.3.1.2 Plasmon Coupling
153(1)
6.3.1.3 Plasmon Resonance Energy Transfer
153(1)
6.3.2 Experimental Method of LSPR on Single Particle Catalysis
154(1)
6.3.2.1 Dark-field Microscopy
154(1)
6.3.2.2 Experimental Strategies
155(1)
6.3.3 Application of LSPR Spectroscopy to Single Particle Catalysis/Reaction
156(1)
6.3.3.1 Application 1: Direct Observation of the Changes of the Single Nanoparticle Itself
156(3)
6.3.3.2 Application 2: Direct Observation of Surface Catalytic Reactions on Single Gold Nanoparticles by Single Particle LSPR Spectroscopy
159(2)
6.3.3.3 Application 3: Indirect Observation of Catalytic Reactions by Single-Nanoparticle LSPR Spectroscopy
161(4)
6.3.3.4 Application 4: Indirect Observation of Chemical Reactions by Plasmon Resonance Energy Transfer
165(1)
6.3.3.5 Application 5: Observation of Electrochemical/Catalytic Reactions on Single Gold Nanoparticles by Single Particle LSPR Spectroscopy
166(8)
Abbreviations
174(1)
References
175(6)
7 X-ray-Based Microscopy of Single Particle Nanocatalysis
181(26)
7.1 History of X-ray Microscopy
181(5)
7.1.1 History of the Setups for X-ray Absorption Fine Structure (XAFS)
182(3)
7.1.2 Evolution of X-ray Source Based on Synchrotron Light Sources
185(1)
7.2 Apparatus for Micrometer-Resolved XAFS Spectroscopy
186(10)
7.2.1 Soft X-rays and Hard X-rays
187(1)
7.2.2 Microprobes
188(3)
7.2.3 How the X-ray Beam is Shaped?
191(1)
7.2.3.1 X-ray Beam Optimization: Energy Selection
192(2)
7.2.3.2 X-ray Beam Optimization: Harmonic Rejection
194(2)
7.3 Spatially Resolved X-ray Microprobe Methods
196(3)
7.3.1 Full-Field Transmission X-ray Microscopy (TXM)
196(1)
7.3.2 Zernike Phase Contrast X-ray Microscopy
197(1)
7.3.3 Scanning Transmission X-ray Microscopy (STXM)
198(1)
7.3.4 Photoemission Microscopes: PEEM, SPEM, and Nano-ARPES
198(1)
7.3.5 Diffraction Microscopy
199(1)
7.4 Applications of X-ray-Based Microscopes at Single-Nanoparticle Catalysis
199(5)
7.5 Summary
204(1)
Abbreviations
204(1)
References
205(2)
8 Vibrational Spectroscopy for Single Particle and Nanoscale Catalysis
207(48)
8.1 Enhanced Raman Spectroscopy
207(37)
8.1.1 Principles of Enhanced Raman Spectroscopy
208(1)
8.1.1.1 Interaction Between Light and Metal Nanostructure
208(1)
8.1.1.2 Interaction Between Light and Molecules
209(2)
8.1.1.3 Interaction Between Metal Nanostructure and Molecules
211(2)
8.1.1.4 Hot Spots
213(3)
8.1.2 Reactions Related to Enhanced Raman Spectroscopy
216(1)
8.1.2.1 Model Chemical Reactions
216(1)
8.1.2.2 Plasmon-Assisted Catalysis
217(2)
8.1.2.3 Electrochemical Reactions
219(1)
8.1.3 Surface-Enhanced Raman Spectroscopy
220(1)
8.1.3.1 Remote Excitation SERS (Re-SERS)
220(1)
8.1.3.2 Instrumentation for Raman Scattering Detection
221(1)
8.1.3.3 SERS Substrate and Applications
222(6)
8.1.3.4 Application of SERS on Single Particle Catalysis/Electrochemistry
228(4)
8.1.4 Tip-Enhanced Raman Scattering
232(1)
8.1.4.1 Configuration of TERS
233(3)
8.1.4.2 Application of TERS on Electrochemistry and Catalysis at Nanoscale or Single Particle Level
236(8)
8.2 Enhanced Infrared Spectroscopy
244(4)
8.2.1 Principles of SEIRAS
244(3)
8.2.2 Application of SEIRAS on Single Particle Nanocatalysis
247(1)
Abbreviations
248(1)
References
249(6)
9 Other Techniques for Single Particle Nanocatalysis/Electrochemistry
255(28)
9.1 Photoluminescence Spectroscopy for Single Particle Nanocatalysis
255(5)
9.1.1 Photoluminescence of Au Nanoparticle
255(2)
9.1.2 Applications of PL Spectroscopy for Single Particle Catalysis
257(1)
9.1.2.1 Revealing Plasmon-Enhanced Catalysis by Single Particle PL Spectroscopy
257(1)
9.1.2.2 Direct Observation of Chemical Reactions by Single Particle PL Measurement
258(2)
9.2 Nanoelectrodes and Ultra-microelectrodes for Single Particle Electrochemistry
260(13)
9.2.1 Nanoelectrodes for Single Particle Electrocatalysis
261(3)
9.2.2 Ultra-microelectrodes for Single Particle Electrochemistry
264(1)
9.2.2.1 Stochastic Collision of Individual Nanoparticles with UME
264(3)
9.2.2.2 Application of UME on Single-Nanoparticle Electrochemistry
267(6)
9.3 Three-Dimensional Holographic Microscopy for Single Particle Electrochemistry
273(5)
9.3.1 3D-Superlocalization of Nanoparticles by DHM
273(2)
9.3.2 Application of DHM on Single Particle Electrochemistry
275(1)
9.3.2.1 Deciphering the Transport Reaction Process of Single Ag Nanoparticles
276(1)
9.3.2.2 Correlated DHM and UME to Reveal the Chemical Reactivity of Individual Nanoparticles
277(1)
Abbreviations
278(1)
References
278(5)
Index 283
Weilin Xu, PhD, is Professor at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. He focuses on energy process related basic and practical research.

Yuwei Zhang, PhD, is Associate Professor at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Her research is currently on single particle nanocatalysis.

Tao Chen, PhD, obtained his PhD from Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, where he studied the nanocatalysis at single particle level based on single molecule fluorescence spectroscopy.
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