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In Situ Bioremediation of Perchlorate in Groundwater 2009 ed. [Hardback]

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  • Formāts: Hardback, 248 pages, height x width: 276x203 mm, weight: 909 g, XLVI, 248 p., 1 Hardback
  • Sērija : SERDP ESTCP Environmental Remediation Technology
  • Izdošanas datums: 02-Dec-2008
  • Izdevniecība: Springer-Verlag New York Inc.
  • ISBN-10: 0387849203
  • ISBN-13: 9780387849201
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  • Formāts: Hardback, 248 pages, height x width: 276x203 mm, weight: 909 g, XLVI, 248 p., 1 Hardback
  • Sērija : SERDP ESTCP Environmental Remediation Technology
  • Izdošanas datums: 02-Dec-2008
  • Izdevniecība: Springer-Verlag New York Inc.
  • ISBN-10: 0387849203
  • ISBN-13: 9780387849201
This volume presents a critical analysis and timely synthesis of the past decade of intensive research, development, and demonstrations on the in situ bioremediation of perchlorate in groundwater. The intended audiences include the decision makers, practicing engineers and hydrogeologists who will select, design, and operate these remedial systems, as well as researchers seeking to improve the current state-of-the-art. Our hope is that this volume will serve as a useful resource to assist remediation professionals in applying and developing the technology as effectively as possible.  An overview of the current state-of-understanding of perchlorate remediation is followed by a discussion of basic principles of microbial and abiotic processes, and of the engineering and implementation issues underlying the technologies described. Characterization of both anthropogenic and natural sources of perchlorate, including isotopic analysis to distinguish between differing sources, precedes discussions of the advantages, performance, and relative costs of applying a range of remedial technologies. Active, semi-passive, and passive in situ bioremediation are fully described and compared with emphasis on field application. Cost information for each technology, using case studies and analyses of several template sites, covers capital costs, as well as costs for laboratory testing, pilot-scale demonstration, design, system operation, monitoring and maintenance during operations, and demolition and restoration after remediation. In addition, analogous cost data are presented for pump-and-treat systems for each template site to illustrate the potential cost savings associated with the use of alternative approaches. Emerging technologies such as monitored natural attenuation, phytoremediation, and vadose zone bioremediation are described, and field demonstrations are used to illustrate the current stage of maturity and the potential applicability of these approaches for specific situations. Each chapter in this volume has been thoroughly reviewed for technical content by one or more experts in each subject area covered.

Recenzijas

From the reviews:



"In Situ Bioremediation of Perchlorate in Groundwater provides an excellent overview and copious field-based detail regarding the advantages and limitations of perchlorate bioremediation. Overall, I found In Situ Bioremediation of Perchlorate in Groundwater to be very readable, thoughtfully organized, and brimming with highly applicable information and case studies." (Michael D. Taraszki, Environmental & Engineering Geoscience, Vol. XV (4), November, 2009)

Preface vii
About the Editors xi
About the Authors xiii
External Reviewers xix
Acronyms and Abbreviations xxi
Unit Conversion Table xxv
Glossary xxvii
In Situ Bioremediation of Perchlorate in Groundwater: An Overview
1(14)
Introduction
1(1)
How Did Perchlorate Become Such a Problem?
2(5)
Perchlorate Properties and Behavior in the Subsurface
2(1)
Production and Disposal
3(1)
Regulatory History
4(1)
Evolution of Analytical Capabilities
5(1)
Evolution of Toxicological Understanding
6(1)
How Can In Situ Bioremediation Help Solve the Perchlorate Problem?
7(8)
Treatment Technology Overview
7(2)
Why Use In Situ Bioremediation?
9(6)
Development of in Situ Bioremediation Technologies for Perchlorate
15(14)
Introduction
15(1)
Early Discoveries
15(1)
Analytical Methods and Pilot Programs
16(1)
Ubiquitous Occurrence of Perchlorate Degraders
17(1)
Field Demonstrations
18(1)
Bioremediation Strategies
19(2)
Remediation of Perchlorate in Soil---The New Challenge
21(3)
The Challenges Ahead
24(5)
Principles of Perchlorate Treatment
29(26)
Introduction
29(1)
Abiotic Remediation Processes
29(5)
Ion Exchange
29(3)
Abiotic Reduction Technologies
32(2)
Overview of Abiotic Processes
34(1)
Biological Remediation Processes
34(5)
General Characteristics of DPRB
35(1)
Diversity of DPRB
36(1)
Environmental Factors Controlling DPRB Activity
36(2)
Summary
38(1)
Challenges Associated with Microbial Perchlorate Reduction
39(3)
Biofouling and Electron Donor Selection
39(3)
The Tools Available for Predicting and Monitoring Microbial Perchlorate Reduction
42(4)
Most Probable Number Counts
43(1)
Probes to Specific Groups of Perchlorate-Reducing Organisms
44(1)
Biomarkers for All DPRB
44(1)
Immunoprobes Specific for DPRB
45(1)
Use of Stable Isotopes to Identify Perchlorate Source and Monitor Degradation
45(1)
Enrichment, Isolation, and Maintenance of DPRB
46(1)
Direct Isolation
46(1)
Culture Maintenance
47(1)
Conclusions
47(6)
Appendix 3.1 Medium for Freshwater Perchlorate-Reducing Microorganisms
53(2)
Perchlorate Sources, Source Identification and Analytical Methods
55(24)
Introduction
55(1)
Sources of Perchlorate
55(7)
Anthropogenic Sources
56(4)
Natural Sources of Perchlorate
60(2)
Distinguishing Synthetic from Natural Perchlorate Using Stable Isotope Analysis
62(6)
Stable Isotope Analysis
62(1)
Stable Isotope Methods for Perchlorate
63(5)
Analytical Methods for Perchlorate Analysis
68(5)
DoD-Approved Analytical Methods
68(2)
Other Analytical Methods for Perchlorate
70(3)
Site Characterization for Perchlorate Treatment
73(1)
Summary
74(5)
Alternatives for in Situ Bioremediation of Perchlorate
79(12)
Introduction
79(2)
Technology Selection Process
81(4)
In Situ Bioremediation
81(1)
Active Treatment
82(2)
Semi-Passive Treatment
84(1)
Passive Treatment
85(1)
Decision Guidelines
85(3)
Ability to Meet Management Objectives
86(2)
Problematic Site Conditions
88(1)
Summary
88(3)
Active Bioremediation
91(44)
Background and General Approach
91(1)
When to Consider an Active Treatment System
92(1)
Treatment System Configurations
93(2)
Groundwater Extraction and Reinjection (ER)
93(1)
Horizontal Flow Treatment Wells (HFTWs)
94(1)
System Applications
95(5)
Biobarriers
95(3)
Source Area Treatment
98(2)
System Design, Operation and Monitoring
100(13)
Site Assessment Needs
100(1)
Modeling
101(4)
Electron Donor
105(3)
Performance Monitoring
108(3)
Operational Issues
111(2)
Case Study: Aerojet Area 20 Groundwater Extraction - Reinjection System
113(18)
Site Description
113(2)
Site Geology and Hydrogeology
115(2)
Pilot Test Design
117(1)
PTA Installation, Instrumentation and Operation
118(1)
Baseline Geochemical Characterization
119(2)
Hydraulic Characterization (Tracer Testing)
121(2)
System Operation
123(1)
Demonstration Results
124(6)
Pilot Test Conclusions
130(1)
Summary
131(4)
Semi-Passive in Situ Bioremediation
135(20)
Background
135(4)
What is a Semi-Passive Approach?
135(2)
When to Consider a Semi-Passive Approach
137(1)
Advantages and Limitations Relative to Other Approaches
137(1)
Technology Maturity
138(1)
System Design, Operation, and Monitoring
139(5)
Typical System Design
139(2)
Site Assessment Needs
141(1)
Groundwater Modeling
142(1)
Tracer Testing
142(1)
Operation and Maintenance
143(1)
Monitoring
143(1)
Health and Safety
144(1)
Case Study: Semi-Passive Bioremediation of Perchlorate at the Longhorn Army Ammunitions Plant
144(9)
Demonstration Test Procedures
144(3)
Demonstration Test Results
147(5)
Conclusions of Case Study
152(1)
Summary
153(2)
Passive Bioremediation of Perchlorate Using Emulsified Edible Oils
155(22)
Introduction
155(1)
Design of Passive Bioremediation Systems
156(10)
Treatment System Configurations
156(2)
Planning and Design of Passive Bioremediation Systems
158(5)
Site Characterization Requirements
163(2)
Monitoring
165(1)
Case Study
166(5)
Demonstration Design
167(2)
Monitoring
169(1)
Results
169(2)
Tools and Resources
171(1)
Factors Controlling Cost and Performance
171(1)
Summary
172(5)
Permeable Organic Biowalls for Remediation of Perchlorate in Groundwater
177(22)
Introduction
177(2)
Applications to Date
177(1)
Technology Description
178(1)
Site Suitability
179(2)
Land Use and Infrastructure
179(1)
Contaminant Concentration and Distribution
180(1)
Hydrogeology
181(1)
Geochemistry
181(1)
Co-Contaminants
181(1)
Design of Permeable Biowalls
181(4)
Site-Specific Hydrogeology and Contaminant Distribution
182(1)
Dimensions, Configuration and Residence Time
182(1)
Biowall Materials
183(1)
Recharge Options and Alternative Configurations
183(1)
Regulatory Compliance
184(1)
Biowall Installation and Construction
185(2)
Construction Methods
185(1)
Quality Assurance/Quality Control
186(1)
Waste Management Plan
186(1)
Performance Monitoring
187(2)
Biogeochemistry
187(1)
Perchlorate Degradation
188(1)
Sustaining the Reaction Zone
188(1)
Biowall System Costs
189(2)
Installation and Trenching Costs
189(1)
Operations and Monitoring Costs
189(1)
Summary of Life Cycle Costs
190(1)
Case Study: Former NWIRP McGregor, McGregor, Texas
191(6)
Fast Track Cleanup and Innovative Technology Implementation
191(1)
Ex Situ Groundwater Treatment
192(1)
In Situ Groundwater Treatment
192(3)
Natural Attenuation in Groundwater
195(1)
Ex Situ Soil Treatment
195(1)
Operations and Maintenance
196(1)
Summary
197(2)
Cost Analysis of in Situ Perchlorate Bioremediation Technologies
199(20)
Background
199(1)
Costing Methodology
200(2)
Template Site Characteristics and Variations Considered
202(4)
Cost Estimates for Base Case Site Characteristics
206(5)
Impacts of Changes In Site Characteristics on Costs
211(4)
Accelerated Clean Up
211(1)
Reduced and Elevated Concentrations of Perchlorate
211(2)
Lower and Higher Electron Acceptor Concentrations
213(1)
Low and High Groundwater Seepage Velocities
214(1)
Deep Groundwater
214(1)
Thin and Thick Saturated Vertical Intervals
215(1)
Narrow and Wide Plumes
215(1)
Summary
215(4)
Emerging Technologies for Perchlorate Bioremediation
219(26)
Introduction
219(1)
Monitored Natural Attenuation
219(5)
Basis
219(3)
Advantages and Limitations
222(1)
Case Studies
222(2)
Phytoremediation
224(5)
Basis
224(3)
Status
227(1)
Advantages and Limitations
228(1)
Case Studies
228(1)
Vadose Zone Bioremediation
229(16)
Basis
231(2)
Status
233(1)
Advantages and Limitations
234(1)
Case Studies
234(11)
Index 245
H. F. Stroo Dr. Stroo is a Principal Technical Advisor with HydroGeoLogic, Inc. He has a Ph.D. in Soil Science from Cornell University, and over 20 years of experience in the assessment and remediation of contaminated soil and groundwater. He has provided technical support to SERDP/ESTCP in the development and evaluation of innovative remediation technologies for over 10 years, particularly in the advancement of in situ technologies.









C. H. Ward Dr. Ward has had a 41-year career in basic and applied research on chemical transport and fate in environmental media and remediation technology development for cleanup of fuel hydrocarbons and chlorinated compounds. He is a science and environmental technology consultant and advisor to government (EPA, DoD, DOE) and industry. He was the Director of the EPA-sponsored National Center for Ground Water Research for 18 years, the Superfund University Training Institute for 8 years, and the DoD-sponsored Advanced Applied (environmental) Technology Development Facility for 7 years. He is the Founding Chair of the Department of Environmental Science and Engineering at Rice University and has published over 200 scientific and technical papers and journal articles and 28 books and monographs on environmental remediation, remediation technology development, and sustainability. Dr. Ward is a registered professional engineer in the state of Texas and a Board Certified Environmental Engineer by the American Academy of Environmental Engineers