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E-grāmata: Soft Matter Physics [Oxford Scholarship Online E-books]

(Department of Applied Physics, University of Tokyo)
  • Formāts: 272 pages, 124 b/w line illustrations
  • Izdošanas datums: 04-Jul-2013
  • Izdevniecība: Oxford University Press
  • ISBN-13: 9780199652952
Citas grāmatas par šo tēmu:
  • Oxford Scholarship Online E-books
  • Cena pašlaik nav zināma
  • Formāts: 272 pages, 124 b/w line illustrations
  • Izdošanas datums: 04-Jul-2013
  • Izdevniecība: Oxford University Press
  • ISBN-13: 9780199652952
Citas grāmatas par šo tēmu:
Soft matter (polymers, colloids, surfactants and liquid crystals) are an important class of materials in modern technology. They also form the basis of many future technologies, for example in medical and environmental applications. Soft matter shows complex behaviour between fluids and solids, and used to be a synonym of complex materials. Due to the developments of the past two decades, soft condensed matter can now be discussed on the same sound physical basis as solid condensed matter. The purpose of this book is to provide an overview of soft matter for undergraduate and graduate students in physics and materials science.

The book provides an introduction to soft matter (what it is, and what are the characteristics of such materials), and also provides the reader with the physical basis for understanding and discussing such characteristics in more detail. Many basic concepts, which are required in advanced courses of condensed matter physics, such as coarse graining, scaling, phase separation, order-disorder transition, Brownian motion, and fluctuation-dissipation theorem, are explained in detail with various forms of soft matter used as examples.

Link to the Solutions Manual Request Form http://www.oup.co.uk/academic/physics/admin/solutions
1 What is soft matter? 1(7)
1.1 Polymers
1(1)
1.2 Colloids
2(1)
1.3 Surfactants
2(2)
1.4 Liquid crystals
4(1)
1.5 What is common in soft matter?
5(1)
1.6 Summary of this chapter
6(1)
Further reading
7(1)
2 Soft matter solutions 8(20)
2.1 Thermodynamics of solutions
8(6)
2.2 Phase separation
14(2)
2.3 Lattice model
16(4)
2.4 Polymer solutions
20(2)
2.5 Colloidal solutions
22(2)
2.6 Multi-component solutions
24(1)
2.7 Summary of this chapter
25(1)
Further reading
25(1)
Exercises
25(3)
3 Elastic soft matter 28(23)
3.1 Elastic soft matter
28(6)
3.2 Elasticity of a polymer chain
34(4)
3.3 Kuhn's theory for rubber elasticity
38(4)
3.4 Polymer gels
42(6)
3.5 Summary of this chapter
48(1)
Further reading
48(1)
Exercises
48(3)
4 Surfaces and surfactants 51(23)
4.1 Surface tension
51(5)
4.2 Wetting
56(3)
4.3 Surfactants
59(5)
4.4 Inter-surface potential
64(7)
4.5 Summary of this chapter
71(1)
Further reading
71(1)
Exercises
71(3)
5 Liquid crystals 74(19)
5.1 Nematic liquid crystals
74(2)
5.2 Mean field theory for the isotropic-nematic transition
76(4)
5.3 Landau-de Gennes theory
80(4)
5.4 Effect of a spatial gradient on the nematic order
84(5)
5.5 Onsager's theory for the isotropic-nematic transition of rod-like particles
89(1)
5.6 Summary of this chapter
90(1)
Further reading
91(1)
Exercises
91(2)
6 Brownian motion and thermal fluctuations 93(21)
6.1 Random motion of small particles
93(4)
6.2 Brownian motion of a free particle
97(3)
6.3 Brownian motion in a potential field
100(3)
6.4 Brownian motion of particles of general shape
103(2)
6.5 Fluctuation-dissipation theorem
105(5)
6.6 Summary of this chapter
110(1)
Further reading
111(1)
Exercises
111(3)
7 Variational principle in soft matter dynamics 114(23)
7.1 Variational principle for the dynamics of particle-fluid systems
114(6)
7.2 Onsager principle
120(2)
7.3 Diffusion of particles in dilute solutions
122(3)
7.4 Diffusion of particles in concentrated solutions
125(3)
7.5 Rotational Brownian motion of rod-like particles
128(6)
7.6 Summary of this chapter
134(1)
Further reading
135(1)
Exercises
135(2)
8 Diffusion and permeation in soft matter 137(28)
8.1 Spatial correlation in soft matter solutions
137(8)
8.2 Diffusio-mechanical coupling in particle sedimentation
145(3)
8.3 Kinetics of phase separation
148(6)
8.4 Diffusio-mechanical coupling in gels
154(7)
8.5 Summary of this chapter
161(1)
Further reading
162(1)
Exercises
162(3)
9 Flow and deformation of soft matter 165(32)
9.1 Mechanical properties of soft matter
166(5)
9.2 Molecular models
171(4)
9.3 Viscoelasticity of non-entangled polymers
175(6)
9.4 Viscoelasticity of entangled polymers
181(8)
9.5 Rod-like polymers
189(5)
9.6 Summary of this chapter
194(1)
Further reading
195(1)
Exercises
195(2)
10 Ionic soft matter 197(25)
10.1 Dissociation equilibrium
198(3)
10.2 Ionic gels
201(3)
10.3 Ion distribution near interfaces
204(8)
10.4 Electrokinetic phenomena
212(8)
10.5 Summary of this chapter
220(1)
Further reading
221(1)
Exercises
221(1)
Appendix A: Continuum mechanics 222(8)
A.1 Forces acting in a material
222(1)
A.2 Stress tensor
222(2)
A.3 Constitutive equations
224(1)
A.4 Work done to the material
224(2)
A.5 Ideal elastic material
226(2)
A.6 Ideal viscous fluid
228(2)
Appendix B: Restricted free energy 230(6)
B.1 Systems under constraint
230(1)
B.2 Properties of the restricted free energy
231(1)
B.3 Method of constraining force
232(1)
B.4 Example 1: Potential of mean force
233(1)
B.5 Example 2: Landau-de Gennes free energy of liquid crystals
234(2)
Appendix C: Variational calculus 236(3)
C.1 Partial derivatives of functions
236(1)
C.2 Functional derivatives of functionals
237(2)
Appendix D: Reciprocal relation 239(5)
D.1 Hydrodynamic definition of the generalized frictional force
239(1)
D.2 Hydrodynamic proof of the reciprocal relation
240(2)
D.3 Onsager's proof of the reciprocal relation
242(2)
Appendix E: Statistical mechanics for material response and fluctuations 244(8)
E.1 Liouville equation
244(1)
E.2 Time correlation functions
245(1)
E.3 Equilibrium responses
246(2)
E.4 Non-equilibrium responses
248(2)
E.5 Generalized Einstein relation
250(2)
Appendix F: Derivation of the Smoluchowskii equation from the Langevin equation 252(3)
Index 255
Masao Doi graduated from the Department of Applied Physics of University of Tokyo in 1970. In 1976 he received his Doctoral Degree in Engineering at the University of Tokyo and began his academic career as an Assistant Professor of Physics at the Tokyo Metropolitan University. He moved to Nagoya University in 1989 and to Tokyo University in 2004. He retired from Tokyo University in 2012, and is now working as a fellow of Toyota Physical and Chemical Research Institute.

His early research was concerned with the dynamics and rheology of flexible polymers, especially with developing a theoretical description of the role of molecular entanglements for determining the transport properties to flexible polymer solutions and melts. He then worked on various aspects of the rheological properties of soft matter, polymers, liquid crystals, colloidal suspensions and gels. His current research is focused on the surface phenomena of polymers, such as adhesion, friction, and drying.