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E-grāmata: Special Distillation Processes

(School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China), , (College of Environmental and Energy Engine), (College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, China)
  • Formāts: PDF+DRM
  • Izdošanas datums: 21-Aug-2021
  • Izdevniecība: Elsevier Science Publishing Co Inc
  • Valoda: eng
  • ISBN-13: 9780128205112
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  • Formāts: PDF+DRM
  • Izdošanas datums: 21-Aug-2021
  • Izdevniecība: Elsevier Science Publishing Co Inc
  • Valoda: eng
  • ISBN-13: 9780128205112

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Special Distillation Processes, Second Edition focuses on the latest developments in the field, such as separation methods that may prove useful for solving problems encountered during research. Topics include extraction, membrane and adsorption distillation involving the separation principle, process design and experimental techniques. The relationship between processes and techniques are also presented. Comprehensive and easy-to-read, this book provides key information needed to understand processes. It will be a valuable reference source for chemical engineers and students wishing to branch out in chemical engineering.
  • Provides the only comprehensive book available on special distillation processes
  • Contains a thorough introduction to recent developments in the field
  • Presents a valuable reference for students, academics and engineers in chemical engineering
About the authors ix
Preface xi
Chapter 1 Thermodynamic fundamentals
1(64)
Chengna Dai
Zhigang Lei
Gangqiang Yu
Biaohua Chen
1 Predictive molecular thermodynamic models
1(15)
1.1 COSMO-based models
2(2)
1.2 UNIFAC-based models
4(11)
1.3 COMSO-UNIFAC models
15(1)
2 Vapor-liquid phase equilibrium
16(21)
2.1 The equilibrium ratio
17(10)
2.2 Liquid-phase activity coefficient in binary and multicomponent mixtures
27(10)
3 Vapor-liquid-liquid phase equilibrium
37(1)
4 Salt effect
38(6)
5 Nonequilibrium thermodynamic analysis
44(5)
6 Multicomponent mass transfer
49(16)
References
59(6)
Chapter 2 Extractive distillation
65(90)
Zhigang Lei
Chengna Dai
Biaohua Chen
1 Introduction
66(3)
2 Process of extractive distillation
69(13)
2.1 Column sequence
69(6)
2.2 Combination with other separation processes
75(1)
2.3 Tray configuration
76(3)
2.4 Operation policy
79(3)
3 Solvent of extractive distillation
82(19)
3.1 Extractive distillation with solid salt
82(4)
3.2 Extractive distillation with liquid solvent
86(8)
3.3 Extractive distillation with the combination of liquid solvent and solid salt
94(2)
3.4 Extractive distillation with ionic liquid
96(5)
4 Experiment techniques of extractive distillation
101(8)
4.1 Direct method
102(3)
4.2 Gas-liquid chromatography method
105(1)
4.3 Ebulliometric method
106(1)
4.4 Inert gas stripping and gas chromatography method
107(2)
5 CAMD of extractive distillation
109(18)
5.1 CAMD for screening solvents
110(14)
5.2 Other methods for screening solvents
124(3)
6 Theory of extractive distillation
127(10)
6.1 Prausnitz and Anderson theory
128(4)
6.2 Scaled particle theory
132(4)
6.3 Anion effect
136(1)
7 Mathematic models of extractive distillation
137(18)
7.1 EQ stage model
137(8)
7.2 NEQ stage model
145(5)
References
150(5)
Chapter 3 Azeotropic distillation
155(36)
Gangqiang Yu
Chengna Dai
Zhigang Lei
Biaohua Chen
1 Introduction
155(4)
2 Entrainer selection
159(6)
3 Mathematical models
165(20)
3.1 Graphical method
165(10)
3.2 EQ and NEQ stage models
175(7)
3.3 Multiple steady-state analysis
182(3)
4 Industrial applications
185(6)
4.1 Treatment of wastewater
185(1)
4.2 1-Propanol dehydration
186(1)
4.3 Separation of propylene glycol methyl ether/water
187(1)
References
188(3)
Chapter 4 Catalytic distillation
191(50)
Chengna Dai
Zhigang Lei
Biaohua Chen
1 Fixed-bed catalytic distillation
191(12)
1.1 FCD advantages
191(5)
1.2 Hardware structure
196(6)
1.3 Mathematical models
202(1)
2 Suspension catalytic distillation
203(32)
2.1 Tray efficiency and hydrodynamics of SCD
203(10)
2.2 Alkylation of benzene and propylene
213(12)
2.3 Alkylation of benzene and 1-dodecene
225(10)
3 Reactive dividing wall column
235(6)
References
237(4)
Chapter 5 Adsorption distillation
241(20)
Zhigang Lei
Gangqiang Yu
Chengna Dai
Biaohua Chen
1 Fixed-bed adsorption distillation
241(8)
1.1 Introduction
241(1)
1.2 Thermodynamic interpretation
242(1)
1.3 Comparison of FAD and extractive distillation
243(6)
2 Suspension adsorption distillation
249(8)
2.1 Introduction
249(1)
2.2 Thermodynamic interpretation
250(7)
3 New development on adsorption distillation
257(4)
References
259(2)
Chapter 6 Membrane distillation
261(84)
Zhongwei Ding
Zhigang Lei
Chengna Dai
Biaohua Chen
1 Introduction
261(1)
2 Separation principle
262(10)
2.1 MD phenomenon
262(2)
2.2 Definition of MD process
264(1)
2.3 Membrane characteristics
264(2)
2.4 Membrane wetting
266(1)
2.5 The advantages of MD
267(1)
2.6 MD configurations
268(4)
3 Transport process
272(9)
3.1 Heat transfer
272(2)
3.2 Mass transfer
274(2)
3.3 Mechanism of gas transport in porous medium
276(2)
3.4 Characteristics of porous membrane
278(3)
4 Mathematical models
281(28)
4.1 Mathematical model of DCMD
281(3)
4.2 Performance analysis of DCMD
284(12)
4.3 Mathematical model of VMD
296(3)
4.4 Performance analysis of VMD
299(4)
4.5 Mathematical model of AGMD
303(2)
4.6 Performance of AGMD
305(4)
5 Module performance
309(25)
5.1 Performance of flat sheet membrane module
309(11)
5.2 Performance of hollow fiber membrane module
320(14)
6 Industrial applications
334(11)
6.1 Desalination
334(4)
6.2 Concentration of aqueous solution
338(2)
6.3 Separation of volatile components
340(2)
References
342(3)
Chapter 7 Pressure-swing distillation
345(10)
Zhigang Lei
Chengna Dai
Biaohua Chen
1 Introduction
345(3)
1.1 Separation principle
345(2)
1.2 Operation modes
347(1)
2 Design of PSD
348(3)
2.1 Column sequence
348(1)
2.2 Column number
348(3)
3 Comparison among different special distillation processes
351(4)
References
353(2)
Chapter 8 Other distillation techniques
355(22)
Chengna Dai
Zhigang Lei
Biaohua Chen
1 High viscosity material distillation
355(6)
1.1 Introduction
355(1)
1.2 Design of high-efficiency flow-guided sieve tray
356(3)
1.3 Industrial application of high-efficiency flow-guided sieve tray
359(2)
2 Thermally coupled distillation
361(13)
2.1 Introduction
361(4)
2.2 Design and synthesis of TCD
365(6)
2.3 Application of TCD in special distillation processes
371(3)
3 Heat pump and multi-effect distillations
374(1)
4 Molecular distillation
375(2)
References 377(4)
Index 381
Zhigang Lei was born in Hubei province (China) in 1973. He received his B.S. degree in 1995 from Wuhan Institute of Technology, and Ph.D. degree in 2000 from Tsinghua University. Then, he became a postdoctoral researcher in Beijing University of Chemical Technology working with Professor Chengyue Li. In 2003 2005, he worked as a researcher in Research Center of Supercritical Fluid Technology (Tohoku University, Sendai, Japan). In 2005 2006, he got the world-famous Humboldt Fellowship and carried out his research in Chair of Separation Science and Technology (Universität Erlange-Nürnberg, Erlangen, Germany). In 2006, he came back to China. He is now a Professor in State Key Laboratory of Chemical Resource Engineering (BUCT, China). His current research interests include chemical process intensification and predictive molecular thermodynamics. He has contributed to about 140 papers in international journals and one book entitled Special Distillation Processes” published by Elsevier B.V. (2005). Chengna Dai was born in Hebei province (China) in 1984 and received her Ph.D. in 2013 from Beijing University of Chemical Technology (BUCT) under the supervision of Prof. Zhigang Lei. Thereafter she worked in BUCT to 2018, and then she works in Beijing University of Technology as an Associate Professor. Her current research interest is the reaction and separation science with ionic liquids as well as the corresponding predictive molecular thermodynamics. She has contributed to more than 50 papers in international journals. Biaohua Chen was born in Jiangxi province (China) in 1963. He received his Ph.D. degree in 1996 from China University of Petroleum (Beijing). In 2000, he was a visiting scholar at Washington University in St. Louis and the University of Washington. He has received two National Science and Technology Progress Prize (second class), and a few provincial or ministerial level prizes. Now he is a member of the Standing Committee of Beijing Chemical Industry Association and a member of the Editorial Board of the Journal of Petrochemical Universities (China). His main research interests are environmental and green chemistry. He has contributed to more than 150 papers in international journals. Zhongwei Ding is the professor of chemical engineering at Beijing University of Chemical technology. He received B.S. degree from Qingdao Institution of Chemical Technology in 1991, and M.S. and Ph.D. degree from Beijing University of Chemical Technology in 1994 and 2001, respectively. From 1994 to 1998, he worked as a computer programmer of process simulation software. Since 1999, he has conducted research work on membrane science and technology for twenty years, mainly focusing on membrane distillation, microfiltration, membrane contactors, and gas separation by membrane. He has authored and coauthored over 80 research papers and five books.