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Structure and Bonding in Crystalline Materials [Hardback]

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(Carnegie Mellon University, Pennsylvania)
  • Formāts: Hardback, 550 pages, height x width x depth: 254x182x32 mm, weight: 1309 g, Worked examples or Exercises; 175 Tables, unspecified; 4 Halftones, unspecified; 235 Line drawings, unspecified
  • Izdošanas datums: 19-Jul-2001
  • Izdevniecība: Cambridge University Press
  • ISBN-10: 0521663288
  • ISBN-13: 9780521663281
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  • Cena: 132,74 €
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Structure and Bonding in Crystalline MaterialsPalielināt
  • Formāts: Hardback, 550 pages, height x width x depth: 254x182x32 mm, weight: 1309 g, Worked examples or Exercises; 175 Tables, unspecified; 4 Halftones, unspecified; 235 Line drawings, unspecified
  • Izdošanas datums: 19-Jul-2001
  • Izdevniecība: Cambridge University Press
  • ISBN-10: 0521663288
  • ISBN-13: 9780521663281
Citas grāmatas par šo tēmu:
Permanent link: https://www.kriso.lv/db/9780521663281.html
Keywords:
Introducing the established principles of crystollography and bonding, this book focuses on the relationship between the composition, structure, and bonding in crystalline materials. It describes periodic trends, the atomic structure of crysytalline solids, the experimental interrogation of crystalline structure, and the origins and varieties of cohesive forces. Models for predicting phase stability and structure are also discussed. The book is intended for advanced undergraduates or beginning graduate students. Rohrer teaches materials science and engineering at Carnegie Mellon University. Annotation c. Book News, Inc., Portland, OR (booknews.com)

A graduate level textbook for materials scientists that describes the established principles of crystallography and bonding.

How can elements be combined to produce a solid with specified properties? This book acquaints readers with the established principles of crystallography and cohesive forces needed to address the fundamental relationship among composition, structure and bonding. Starting with an introduction to periodic trends, the book discusses crystal structures and the various primary and secondary bonding types, and finishes by describing a number of models for predicting phase stability and structure. Its large number of worked examples, exercises, and detailed descriptions of numerous crystal structures make this an outstanding advanced undergraduate or graduate-level textbook for students of materials science.

Recenzijas

' a remarkably pointed example of how times have changed. The real strengths of the book are its depth of coverage, bridging advanced undergraduate and postgraduate work, and its material-based approach.' Joan Halfpenny, Chemistry of Britain ' an approach to the subject of structure and bonding in crystalline solids can be recommended for everyone concerned with crystalline solids in the broadest sense, as a useful compendium and handbook of long-lasting value.' Peter Kroll, Angewandte Chemie

Papildus informācija

A graduate level textbook for materials scientists that describes the established principles of crystallography and bonding.
Preface ix
Introduction
1(28)
Introduction
1(1)
Periodic trends in atomic properties
2(2)
Bonding generalizations based on periodic trends in the electronegativity
4(8)
Generalizations about crystal structures based on periodicity
12(9)
The limitions of simple models
21(4)
Problems
25(2)
References and sources for further study
27(2)
Basic Structural Concepts
29(59)
Introduction
29(1)
The Bravais lattice
29(12)
The unit cell
41(3)
The crystal structure. A Bravais lattice plus a basis
44(2)
Specifying locations, planes and directions in a crystal
46(4)
The reciprocal lattice
50(6)
Quantitative calculations involving the geometry of the lattice
56(3)
Visual representations of crystal structures
59(10)
Polycrystallography
69(12)
Problems
81(3)
References and sources for further study
84(4)
Symmetry in Crystal Structures
88(47)
Introduction
88(1)
Symmetry operators
88(4)
The 32 distinct crystallographic point groups
92(13)
The 230 space groups
105(16)
The interpretation of conventional crystal structure data
121(7)
Problems
128(5)
References and sources for further study
133(2)
Crystal Structures
135(70)
Introduction
135(1)
Close packed arrangements
135(5)
The interstitial sites
140(3)
Naming crystal structures
143(2)
Classifying crystal structures
145(2)
Important prototype structures
147(30)
Interstitial compounds
177(2)
Laves phases
179(3)
Superlattice structures and complex stacking sequences
182(6)
Extensions of the close packing description to more complex structures
188(2)
Van der Waals solids
190(1)
Noncrystalline solid structures
191(6)
Problems
197(5)
References and sources for further study
202(3)
Diffraction
205(58)
Introduction
205(1)
Bragg's formulation of the diffraction condition
205(1)
The scattering of X-rays from a periodic electron density
206(12)
The relationship between diffracted peak intensities and atomic positions
218(14)
Factors affecting the intensity of diffracted peaks
232(10)
Selected diffraction techniques and their uses
242(9)
Problems
251(8)
Review problems
259(2)
References and sources for further study
261(2)
Secondary Bonding
263(23)
Introduction
263(4)
A physical model for the van der Waals bond
267(11)
Dipolar and hydrogen bonding
278(2)
The use of pair potentials in empirical models
280(2)
Problems
282(2)
References and sources for further study
284(2)
Ionic Bonding
286(40)
Introduction
286(3)
A physical model for the ionic bond
289(13)
Other factors that influence cohesion in ionic systems
302(6)
Predicting the structures of ionic compounds
308(5)
Electronegativity scales
313(4)
The correlation of physical models with the phenomenological trends
317(1)
Pair potential calculations of defect properties in ionic compounds
318(1)
Problems
319(4)
References and sources for further study
323(3)
Metallic Bonding
326(37)
Introduction
326(2)
A physical model for the metallic bond: free electron theory
328(20)
Failures of the free electron theory
348(1)
Electrons in a periodic lattice
348(9)
Correlation of the physical models with the phenomenological trends
357(1)
Empirical potentials for calculating the properties of defects in metals
357(1)
Problems
358(3)
References and sources for further study
361(2)
Covalent Bonding
363(61)
Introduction
363(4)
A physical model for the covalent bond in a molecule
367(9)
A physical model for the covalent bond in a homopolar crystal
376(9)
A physical model for the covalent bond in a polar crystal
385(16)
Bands deriving from d-electrons
401(5)
The distinction between metals and non-metals
406(1)
The distinction between covalent and ionic solids
407(3)
The cohesive energy of a covalently bonded solid
410(2)
Overview of the LCAO model and correlation with phenomenological trends
412(2)
The bandgap
414(1)
Problems
415(5)
References and sources for further study
420(4)
Models for Predicting Phase Stability and Structure
424(53)
Introduction
424(1)
Models for predicting phase stability
425(15)
Factors that determine structure in polar-covalent crystals
440(21)
Structure stability diagrams
461(12)
Problems
473(1)
References and sources for further study
474(3)
Appendix 1A: Crystal and univalent radii 477(3)
Appendix 2A: Computing distances using the metric tensor 480(2)
Appendix 2B: Computing unit cell volumes 482(1)
Appendix 2C: Computing interplanar spacings 483(2)
Appendix 3A: The 230 space groups 485(3)
Appendix 3B: Selected crystal structure data 488(24)
Appendix 5A: Introduction to Fourier series 512(3)
Appendix 5B: Coefficients for atomic scattering factors 515(3)
Appendix 7A: Evaluation of the Madelung constant 518(3)
Appendix 7B: Ionic radii for halides and chalcogenides 521(5)
Appendix 7C: Pauling electronegativities 526(1)
Appendix 9A: Cohesive energies and band gap data 527(2)
Appendix 9B: Atomic orbitals and the electronic structure of the atom 529(4)
Index 533


Gregory S. Rohrer is a Professor of Materials Science and Engineering at Carnegie Mellon University. Prof. Rohrer was born in Lancaster, PA, in 1962. He received his bachelor's degree in Physics from Franklin and Marshall College in 1984 and his Ph.D. in Materials Science and Engineering from the University of Pennsylvania in 1989. At CMU, Prof. Rohrer is the director of the NSF sponsored Materials Research Science and Engineering Center. His research is directed toward understanding how the properties of surfaces and internal interfaces are influenced by their geometric and crystallographic structure, their stoichiometry, and their defect structure. Prof. Rohrer is an associate Editor for the Journal of the American Ceramic Society and his research earned a National Science Foundation Young Investigator Award in 1994.