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Theory of Molecular Rydberg States [Hardback]

(University of Oxford)
  • Formāts: Hardback, 330 pages, height x width x depth: 253x180x20 mm, weight: 810 g, 30 Tables, black and white; 70 Line drawings, unspecified
  • Sērija : Cambridge Molecular Science
  • Izdošanas datums: 11-Aug-2011
  • Izdevniecība: Cambridge University Press
  • ISBN-10: 0521769957
  • ISBN-13: 9780521769952
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  • Hardback
  • Cena: 201,67 €
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  • Formāts: Hardback, 330 pages, height x width x depth: 253x180x20 mm, weight: 810 g, 30 Tables, black and white; 70 Line drawings, unspecified
  • Sērija : Cambridge Molecular Science
  • Izdošanas datums: 11-Aug-2011
  • Izdevniecība: Cambridge University Press
  • ISBN-10: 0521769957
  • ISBN-13: 9780521769952
Citas grāmatas par šo tēmu:
"Molecular Rydberg states have many unusual properties, lending themselves to a diverse range of experimental applications. This book is designed to unravel the mysteries of molecular Rydberg states that lie beyond the scope of accepted spectroscopic theories. It is the first single-authored text to focus on the application of multi-channel quantum defect theory (MQDT) and ab initio theory to this special class of molecular systems, introducing readers to novel theoretical techniques. The scattering techniques of MQDT are examined, along with a unified description of bound states and fragmentation dynamics. Connections with established spectroscopic theory are also described. The book concludes with an account of the spherical tensor and density matrix theories required for the interpretation of multi-photon experiments. While the main text focuses on physical principles and experimental applications, appendices are used to handle advanced mathematical detail. This is a valuable resource for researchers in chemical, atomic and molecular physics"--

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Papildus informācija

The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods.
Preface xi
1 Molecular Rydberg states 1(16)
1.1 The nature of Rydberg states
1(6)
1.2 Organization of the text
7(10)
2 The quantum defect picture 17(28)
2.1 Introduction
17(1)
2.2 Coulomb wavefunctions
18(7)
2.3 Single-channel quantization
25(2)
2.4 Coupled channels
27(18)
3 Ab-initio quantum defects 45(45)
3.1 Traditional quantum chemistry
45(7)
3.2 Constrained ab-initio wavefunctions
52(2)
3.3 The R-matrix matching procedure
54(4)
3.4 The Wigner–Eisbud R-matrix
58(4)
3.5 Variational R-matrix theory
62(12)
3.6 Rydberg–valence interactions
74(4)
3.7 The influence of positive ion dipoles
78(12)
4 Frame transformations and channel interactions 90(35)
4.1 Physical assumptions
91(6)
4.2 Rotational channel interactions
97(8)
4.3 Vibrational channel interactions
105(9)
4.4 Vibronic channel interactions
114(11)
5 Competitive fragmentation 125(32)
5.1 Perturbation model for diatomic species
126(3)
5.2 Diatomic predissociation
129(1)
5.3 Dissociative recombination and related phenomena
130(10)
5.4 R-matrix formulation
140(8)
5.5 Vibronically induced dissociative recombination of H3+
148(9)
6 Photo-excitation 157(34)
6.1 Introduction
157(1)
6.2 n-photon discrete absorption
158(5)
6.3 Spherical tensor representation
163(4)
6.4 Spatial selectivity
167(3)
6.5 Resonant two-photon excitation
170(1)
6.6 Multiphoton band structure
171(6)
6.7 Angular momentum decoupling in high Rydberg states
177(6)
6.8 ZEKE intensities
183(8)
7 Photo-ionization 191(48)
7.1 Boundary conditions and cross-sections
192(3)
7.2 The photo-ionization matrix element
195(4)
7.3 Integrated cross-section
199(3)
7.4 Differential cross-section
202(13)
7.5 Fixed molecule angular distribution
215(4)
7.6 Resonant two-photon ionization
219(7)
7.7 Orientation and alignment
226(6)
7.8 Spin polarization
232(7)
8 Manipulating Rydberg states 239(34)
8.1 Rydberg wavepackets
239(16)
8.2 The Stark effect
255(18)
Appendix A MQDT normalization 273(5)
A.1 Open channels
273(2)
A.2 Closed channels
275(3)
Appendix B Alternative MQDT representations 278(4)
B.1 Standard representation
278(1)
B.2 Sine-cos representation
279(1)
B.3 Mixed representation
280(2)
Appendix C Rotational frame transformations 282(13)
C.1 Hund's cases for diatomic molecules
282(2)
C.2 Parity considerations
284(1)
C.3 Basis functions
285(1)
C.4 Diatomic frame transformations
286(4)
C.5 Asymmetric tops
290(5)
Appendix D Optical transition and photo-ionization amplitudes 295(12)
D.1 Discrete absorption amplitudes
295(2)
D.2 Photo-ionization amplitudes
297(6)
D.3 Dipole radial matrix elements and Cooper minima
303(4)
Appendix E Generalized MQDT representation 307(3)
Appendix F Notation 310(4)
F.1 Angular momenta
310(1)
F.2 Reduced matrix elements
310(2)
F.3 Other special brackets
312(2)
Index 314
Mark Child is a distinguished theoretical chemist and internationally recognised authority on quantum defect theory and its applications to molecular systems. He was Coulson Professor of Theoretical Chemistry at the University of Oxford, a post from which he recently retired.