Preface |
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xi | |
1 Molecular Rydberg states |
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1 | (16) |
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1.1 The nature of Rydberg states |
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1 | (6) |
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1.2 Organization of the text |
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7 | (10) |
2 The quantum defect picture |
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17 | (28) |
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17 | (1) |
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2.2 Coulomb wavefunctions |
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18 | (7) |
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2.3 Single-channel quantization |
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25 | (2) |
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27 | (18) |
3 Ab-initio quantum defects |
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45 | (45) |
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3.1 Traditional quantum chemistry |
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45 | (7) |
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3.2 Constrained ab-initio wavefunctions |
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52 | (2) |
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3.3 The R-matrix matching procedure |
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54 | (4) |
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3.4 The WignerEisbud R-matrix |
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58 | (4) |
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3.5 Variational R-matrix theory |
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62 | (12) |
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3.6 Rydbergvalence interactions |
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74 | (4) |
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3.7 The influence of positive ion dipoles |
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78 | (12) |
4 Frame transformations and channel interactions |
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90 | (35) |
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91 | (6) |
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4.2 Rotational channel interactions |
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97 | (8) |
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4.3 Vibrational channel interactions |
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105 | (9) |
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4.4 Vibronic channel interactions |
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114 | (11) |
5 Competitive fragmentation |
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125 | (32) |
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5.1 Perturbation model for diatomic species |
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126 | (3) |
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5.2 Diatomic predissociation |
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129 | (1) |
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5.3 Dissociative recombination and related phenomena |
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130 | (10) |
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140 | (8) |
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5.5 Vibronically induced dissociative recombination of H3+ |
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148 | (9) |
6 Photo-excitation |
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157 | (34) |
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157 | (1) |
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6.2 n-photon discrete absorption |
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158 | (5) |
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6.3 Spherical tensor representation |
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163 | (4) |
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167 | (3) |
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6.5 Resonant two-photon excitation |
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170 | (1) |
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6.6 Multiphoton band structure |
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171 | (6) |
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6.7 Angular momentum decoupling in high Rydberg states |
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177 | (6) |
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183 | (8) |
7 Photo-ionization |
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191 | (48) |
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7.1 Boundary conditions and cross-sections |
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192 | (3) |
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7.2 The photo-ionization matrix element |
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195 | (4) |
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7.3 Integrated cross-section |
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199 | (3) |
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7.4 Differential cross-section |
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202 | (13) |
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7.5 Fixed molecule angular distribution |
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215 | (4) |
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7.6 Resonant two-photon ionization |
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219 | (7) |
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7.7 Orientation and alignment |
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226 | (6) |
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232 | (7) |
8 Manipulating Rydberg states |
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239 | (34) |
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239 | (16) |
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255 | (18) |
Appendix A MQDT normalization |
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273 | (5) |
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273 | (2) |
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275 | (3) |
Appendix B Alternative MQDT representations |
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278 | (4) |
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B.1 Standard representation |
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278 | (1) |
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B.2 Sine-cos representation |
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279 | (1) |
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280 | (2) |
Appendix C Rotational frame transformations |
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282 | (13) |
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C.1 Hund's cases for diatomic molecules |
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282 | (2) |
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C.2 Parity considerations |
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284 | (1) |
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285 | (1) |
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C.4 Diatomic frame transformations |
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286 | (4) |
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290 | (5) |
Appendix D Optical transition and photo-ionization amplitudes |
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295 | (12) |
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D.1 Discrete absorption amplitudes |
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295 | (2) |
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D.2 Photo-ionization amplitudes |
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297 | (6) |
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D.3 Dipole radial matrix elements and Cooper minima |
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303 | (4) |
Appendix E Generalized MQDT representation |
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307 | (3) |
Appendix F Notation |
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310 | (4) |
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310 | (1) |
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F.2 Reduced matrix elements |
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310 | (2) |
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F.3 Other special brackets |
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312 | (2) |
Index |
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314 | |