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INTRODUCTION | |
The Nature and Control of Waste Disposal Sites | |
The Bioreactor Concept | |
Reactor Configurations of Relevance to Practical Description of a Waste Site | |
The Waste Site as a Biological Reactor | |
PHYSICAL CHARACTERISTICS OF WASTE SITES | |
Waste Site Bioreactor Concepts | |
Porosity of a Waste Site | |
Density and Other Properties of Mixed Soil and Waste Materials | |
Applicability of Conductivity and Permeability Relations for Packed Beds | |
Permeability k of a Mixed Porous Media | |
Permeability (k) Correction for Packed Bed Flow | |
Correction of Packed Column Pressure Drop for Wall Effects | |
Corrections for Pressure Drop Relations for Fluid Flow through a Waste Site | |
Waste Site Particle Properties: Size and Shape | |
References | |
CHARACTERIZATION OF DISPOSED WASTES: PHYSICAL AND CHEMICAL PROPERTIES, AND BIODEGRADATION FACTORS | |
Determination of Physical and Chemical Characteristics of Wastes | |
MSW Composition vs. Landfill Layer Depth or Age: Data for Initialization | |
Individual Wastes and Characteristics | |
Characteristics of Paper Wastes | |
Characteristics of Food Wastes | |
Characteristics of Yard Wastes | |
Characteristics of Plastics Wastes | |
Plastics Deterioration in Landfills | |
Landfill Leachate and Landfill Gas Characteristics | |
WASTE SITE ECOLOGY | |
Influence of the Waste Site Environment on Types of Organisms Present | |
Species Competition for Food at a Waste Site | |
The Range of Organisms at Waste Sites | |
Organisms Found in Compost Piles | |
Trophic Relations and Environmental Factors Determining Organisms at Waste Sites | |
Influence of Site Environmental factors on Organism Types | |
The Waste Site as an Environment for Organisms | |
Definition of Impact of Organisms at Disposed Waste Site | |
Organisms Reported at Landfills, Dumps, and Other Waste Sites: Considerations | |
Waste Site Scavengers | |
Waste Removal Impact of Animals at Disposal Sites | |
Waste Removal by Insects and Soil Mesofauna | |
References | |
MOISTURE AND HEAT FLOWS | |
Moisture as a Control of Processes in the Waste Site | |
Water Film Thickness on Solid Materials under Sorption Regime | |
Method 1 for Liquid Film Thickness Determination | |
Method 2 for Moisture Film Thickness | |
Water Potential vs. Water Activity of Soils and Solid Porous Materials | |
The Issue of Mixed Water Saturation or Varied Water Potential in Wastes | |
Maximum Moisture Sorption by a Material | |
Effect of Waste Moisture Content on Soil Organisms | |
Water Availability to Organisms | |
Hydraulic Conductivity | |
Capillary Effects in Waste Sites | |
Waste Site Moisture Retention Characteristics | |
Full Range Moisture Capillarity | |
Middle Moisture Content Range | |
Moist to Saturation of Wet Moisture Content Section of Curve | |
Moisture Retention Curve in the Dry Range for Landfilled Waste | |
Boundary Conditions | |
Estimation of Constants Full-Range (Wet to Dry) | |
Reliability of Estimated Values | |
Relevance of the Lower Curve Junction to Bioreactor Simulation | |
Development of Moisture Capillarity-Hydraulic | |
Summary of Extended Range Conductivity Relationships | |
Moisture Inflow and Moisture Balance | |
Locations Used for Landfill Cover Moisture Impact Simulations | |
Microorganism Rate vs. Water Content and Water Activity | |
Limitations of Applying Water Potential Concepts | |
Discussion | |
References | |
HEAT GENERATION AND TRANSPORT | |
Introduction | |
The Heat Model | |
Definition of Waste Site System Heat Capacity | |
Heat Content of System: Landfill Gas or Air as Saturating Fluid | |
The Volumetric Heat Generation Term q''' | |
Heat Impact of Moisture Uptake and Flows | |
Evaporation Enhancement Due to Thermal Gradient in Pore Structure | |
Temperature vs. Water Vapor Diffusion, Latent Heat and Density Variation | |
Definitions of Waste Site System Tortuosity | |
Energy Balance at Atmospheric Boundary of Bioractor | |
Effect of Surface Albedo | |
Incoming Longwave Radiation | |
Outgoing Longwave Radiation | |
Latent Heat Flow of a Bioreactor System | |
Temperature Variation with Depth | |
Sensible Heat Flow from the Bioreactor System | |
Development of the Heat Generation Model | |
Solution to the Heat Equation | |
Temperature at the Waste Site Surface | |
Variables of the Heat Generation Model | |
Landfill Thermal Conductivity Km | |
Thermal Conductivity and Diffusivity Values | |
Estimating the Mean Thermal Conductivity of Mixed Waste Materials | |
References | |
THE KINETICS OF DECOMPOSITION OF WASTES | |
Introduction | |
Anaerobic and Aerobic Decomposition Patterns | |
Anaerobic Decomposition | |
The Kinetics of Aerobic Decomposition at a Waste Site | |
Aerobic Hydrolysis Product Generation, Incorporation and Use | |
Diffusivity Coefficients for Liquid and Gas Solutes | |
A Stoichiometric Approach to Decomposition | |
Values of Decompositiom Kinetic Constants | |
References | |
DECOMPOSITION ISSUES | |
Introduction | |
Information from Previous Waste Site Studies | |
Landfill Soils Sampling Studies | |
Landfill Soil Microorganism Studies | |
Mass Transfer Considerations | |
Application of Transport Model to Gas Flux | |
Gas-Liquid Transfers | |
Mass Flux | |
Removal of Chemical in Liquid Film | |
Application of Transport Model to Gas Chemicals Flux | |
Mass Transfer Rate at Interface | |
Biodegradation Rates for Landfill Organic Chemicals | |
Partitioning Between Gas and Liquid | |
Waste Site Settlement | |
References | |
SENSITIVITY ANALYSIS AND CONCLUSIONS | |
Introduction | |
Information in Database for MSW Fractions as Substrate | |
Range of Anaerobic and Hydrolysis Rates | |
Chemical Characterization of Waste Fractions | |
Moisture Sorption Factors for Municipal Waste Materials | |
Moisture Response of Materials to the Environment | |
Testing Approach | |
Other Properties Estimated for the Database | |
Constants for Aerobic and Anaerobic Decomposition | |
Soil Moisture Content | |
Moisture Inflow Effect of Cover | |
Temperature as a Decomposition Factor | |
Biofiltration Effect | |
Settlement Effect | |
Discussion | |
Moisture Input | |
Conclusions | |
Appendix 1: Waste-Properties | |
Appendix 2: Landfill Gas Properties |