Polymer-Driven Wax Crystal Control Using Partially Crystalline Polymeric Materials |
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A. Radulescu, L.J. Fetters, D. Richter |
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1 | |
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6 | |
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1.1 Self-Assembling Copolymers |
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10 | |
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2 Small Angle Neutron Scattering |
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12 | |
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2.1 Small Angle Neutron Scattering Instruments |
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13 | |
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16 | |
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2.3 Small Angle Scattering from Simple Structures |
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19 | |
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2.4 Platelet-Like Aggregates with Internal Structure |
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20 | |
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2.5 Rod-Like Structures with Longitudinal Density Modulation |
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25 | |
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2.6 Scattering from Polymer Brushes - Blob Scattering |
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26 | |
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27 | |
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3 Ethylene/Vinylacetate (EVA) Copolymers |
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28 | |
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4 Crystalline-Amorphous Diblock Copolymers |
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36 | |
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4.1 Aggregates of Crystalline-Amorphous Diblock Copolymers |
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36 | |
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4.2 PE-PEP Self-assembling |
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37 | |
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4.3 Thermodynamics of Platelet Formation |
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46 | |
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4.4 Interaction of PE-PEP Diblocks and Waxes |
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49 | |
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4.5 The Effect of PE-PEP Diblocks on the Yield Stress in Wax-Containing Oils |
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55 | |
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5 Crystalline-Amorphous Poly(ethylene-butene) Copolymers |
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58 | |
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59 | |
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5.2 Self-assembling of Random Crystalline-Amorphous Copolymers (PEB-n) |
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63 | |
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5.3 Cocrystallization of C24 Wax and PEB-11 Random Copolymer |
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75 | |
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5.4 Templating and Cocrystallization of Waxes and PEB-7.5 Random Copolymers |
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83 | |
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93 | |
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96 | |
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98 | |
Layered Double Hydroxide Based Polymer Nanocomposites |
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F.R. Costa, M. Saphiannikova, U. Wagenknecht, G. Heinrich |
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101 | |
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102 | |
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2 Layered Double Hydroxide (LDH) |
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104 | |
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104 | |
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105 | |
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106 | |
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2.4 Characterization Modified LDH |
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108 | |
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2.4.1 X-Ray Diffraction Analysis |
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108 | |
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109 | |
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2.4.3 Morphological Analysis |
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111 | |
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3 Preparation of LDH-Based Polymer Nanocomposites |
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113 | |
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113 | |
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3.1.1 In-Situ LDH Synthesis |
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113 | |
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3.1.2 In-Situ Polymerization |
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114 | |
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3.2 Solution Intercalation |
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118 | |
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3.3 Melt Compounding Method |
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119 | |
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4 Polyethylene/Mg-Al LDH Nanocomposites |
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120 | |
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120 | |
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4.2 Morphological Characterization |
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121 | |
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4.2.1 X-Ray Diffraction Analysis |
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122 | |
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123 | |
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4.3 Melt Rheological Behavior |
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127 | |
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4.3.1 Linear Viscoelastic Behavior |
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128 | |
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4.3.2 Non-linear Viscoelastic Behavior |
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136 | |
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146 | |
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4.5 Flammability Properties |
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150 | |
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4.5.1 Cone Calorimeter Investigation |
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150 | |
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4.5.2 LOI and UL94 Investigation |
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155 | |
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4.5.3 LDH as Flame Retardant Synergist |
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158 | |
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163 | |
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165 | |
Synthesis of Stimuli-Responsive Polymers by Living Polymerization: Poly(N-Isopropylacrylamide) and Poly(Vinyl Ether)s |
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169 | |
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171 | |
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2 Living Polymerization of NIPAM |
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173 | |
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2.1 Development of Living Radical Polymerization and Radical Polymerization of NIPAM |
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173 | |
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2.2 Living Anionic Polymerization of NIPAM |
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175 | |
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3 Synthesis of Various Functionalized NIPAM Polymers |
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176 | |
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3.1 Synthesis of Thermoresponsive Block Copolymers and End-Functionalized Polymers |
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177 | |
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3.2 Synthesis of NIPAM Polymers with Various Shapes |
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180 | |
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3.3 Grafting of NIPAM Segments onto Various Polymers or Inorganic Substrates |
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181 | |
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4 Synthesis of Other Thermoresponsive Polymers |
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182 | |
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4.1 PEO-Related Block Copolymers |
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182 | |
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4.2 Various Thermoresponsive Polymers |
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183 | |
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5 Stimuli-Responsive Poly(Vinyl Ether)s |
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185 | |
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5.1 Thermoresponsive Polymers |
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185 | |
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5.2 Other Stimuli-Responsive Polymers |
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187 | |
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5.3 Self-Association of Stimuli-Responsive Polymers with Controlled Sequences |
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190 | |
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6 New Initiating Systems and Synthetic Methodologies |
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195 | |
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6.1 "Classic" Living Cationic Polymerization with Added Base |
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195 | |
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6.2 Recent Development of Homogeneous Catalysts |
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195 | |
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6.3 Heterogeneous Living Cationic Polymerization with Fe2O3 |
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197 | |
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6.4 Star-Shaped Polymers with Narrow MWDs and Gradient Copolymers |
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197 | |
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200 | |
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200 | |
Author Index Volumes 201-210 |
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209 | |
Subject Index |
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213 | |