Preface |
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xi | |
Acknowledgements |
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xiii | |
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Overview of IC Interconnects |
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1 | (16) |
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Silicon IC BEOL Technology Trends |
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2 | (4) |
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SIA Roadmap Interconnect Projections |
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6 | (1) |
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Low-κ Requirements and Materials |
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7 | (5) |
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8 | (1) |
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Spin-On Glasses and Silsesquioxanes |
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8 | (1) |
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9 | (1) |
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9 | (2) |
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11 | (1) |
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11 | (1) |
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Need for Low-κ CMP Process Understanding |
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12 | (2) |
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14 | (1) |
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14 | (3) |
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Low-κ Interlevel Dielectrics |
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17 | (28) |
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19 | (2) |
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21 | (3) |
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24 | (3) |
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27 | (7) |
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34 | (1) |
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35 | (3) |
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38 | (2) |
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40 | (5) |
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Chemical-Mechanical Planarization (CMP) |
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45 | (26) |
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47 | (3) |
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CMP Processes With Copper Metallization |
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50 | (5) |
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50 | (1) |
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50 | (2) |
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52 | (3) |
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CMP Targeted Results and Challenges |
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55 | (1) |
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55 | (7) |
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62 | (4) |
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Contact Mechanics-Based Models |
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63 | (1) |
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Fluid Mechanics-Based Models |
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64 | (2) |
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Langmuir-Hinshelwood Surface Kinetics in CMP Modeling |
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66 | (5) |
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71 | (1) |
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CMP of BCB and SiLK Polymers |
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71 | (26) |
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Removal Rate in Copper Slurries |
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71 | (3) |
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74 | (4) |
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Surface and Bulk Film Chemistry |
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78 | (7) |
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Angle-Resolved Surface Results |
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78 | (6) |
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84 | (1) |
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Effect of Cure Conditions on BCB and Silk Removal |
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85 | (3) |
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Variation in Cure Conditions |
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86 | (1) |
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Effect of Cure Conditions on Removal Rate |
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86 | (2) |
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Effect of CMP and BCB and Silk Film Hardness |
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88 | (3) |
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Comparison of BCB and Silk CMP with Other Polymer CMP |
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91 | (2) |
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93 | (1) |
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94 | (3) |
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CMP of Organosilicate Glasses |
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97 | (22) |
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Effect of Film Carbon Content |
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97 | (6) |
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Removal Rate in Oxide Slurries |
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98 | (3) |
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Removal Rate in Copper Slurries |
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101 | (2) |
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103 | (3) |
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Surface and Bulk Film Chemistry |
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106 | (4) |
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107 | (2) |
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FTIR Bulk Profiling Results |
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109 | (1) |
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Copper Damascene Patterning with OSG Dielectrics |
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110 | (7) |
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Hardmasks or Dielectric Cap Layers |
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111 | (1) |
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112 | (1) |
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113 | (4) |
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117 | (1) |
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117 | (2) |
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Low-κ CMP Model Based on Surface Kinetics |
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119 | (42) |
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Isolation of the Chemical Effects in Silk CMP |
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120 | (2) |
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CMP with Simplified ``Model'' Silk Slurries |
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122 | (7) |
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Removal Rate Dependence on Slurry Reactant Concentration |
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124 | (3) |
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KH Phthalate Slurry for Copper CMP Applications |
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127 | (1) |
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SiLK Removal Rate Dependence on Velocity |
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128 | (1) |
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Phenomenological Model for CMP Removal |
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129 | (5) |
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Applicability to the CMP of BCB and Silk |
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131 | (2) |
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Applicability to the CMP of Organosilicate Glasses |
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133 | (1) |
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Five Step Removal Model Using Modified Langmuir-Hinshelwood Kinetics for Silk CMP |
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134 | (18) |
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Five Step Surface Mechanism |
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135 | (4) |
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Implementation into 3-D Fluid Mechanics and Mass Transport Models |
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139 | (2) |
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141 | (11) |
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Two Step Removal Model Using Heterogeneous Catalysis for Silk CMP |
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152 | (3) |
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Two Step Surface Mechanism |
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152 | (2) |
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154 | (1) |
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Extendibility of Model to Describe the CMP of Other Materials |
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155 | (3) |
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156 | (1) |
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156 | (2) |
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158 | (3) |
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Copper CMP Model Based Upon Fluid Mechanics and Surface Kinetics |
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161 | (20) |
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163 | (1) |
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164 | (8) |
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Mass Transport of Oxidizer to the Wafer Surface |
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165 | (1) |
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166 | (2) |
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Copper Removal Rate and Effectiveness Factor |
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168 | (2) |
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170 | (1) |
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171 | (1) |
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172 | (4) |
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Copper CMP Experiments with Potassium Dichromate Based Slurry |
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176 | (3) |
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179 | (1) |
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179 | (2) |
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Future Directions in IC Interconnects and Related Low-κ ILD Planarization Issues |
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181 | (46) |
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Planarization of Interconnects with Ultra Low-κ ILDS |
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182 | (3) |
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Alternatives to Conventional CMP |
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182 | (1) |
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Non-CMP Approaches to Planarization |
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183 | (2) |
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Alternatives for the Post-Copper/Ultra Low-κ Interconnect Era |
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185 | (8) |
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185 | (1) |
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Alternative Distribution for Signals and Clocks |
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186 | (2) |
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Non-electrical Distribution of Signals and Clocks |
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188 | (1) |
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Non-Planar Integrated Assemblies-Three Dimensional (3D) Integration |
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189 | (4) |
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3D Wafer-Scale Integration Using Dielectric Bonding Glues and Inter-Wafer Interconnection with Copper Damascene Patterning |
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193 | (6) |
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194 | (3) |
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197 | (2) |
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Comparison with Other Wafer-Scale 3D Integration Technologies |
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199 | (1) |
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199 | (1) |
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200 | (3) |
APPENDICES |
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Appendix A: Experimental Procedures and Techniques |
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203 | (18) |
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Appendix B: XPS Depth-Profile Data |
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221 | (4) |
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Appendix C: CMP Data for Anomalous Silk Removal Behavior |
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225 | (2) |
Index |
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227 | |