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E-grāmata: Corrosion of Ceramic Materials

(Rutgers, The State University of New Jersey, Piscataway, USA)
  • Formāts: 462 pages
  • Sērija : Corrosion Technology
  • Izdošanas datums: 19-Apr-2016
  • Izdevniecība: CRC Press Inc
  • Valoda: eng
  • ISBN-13: 9781439820230
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  • Formāts: 462 pages
  • Sērija : Corrosion Technology
  • Izdošanas datums: 19-Apr-2016
  • Izdevniecība: CRC Press Inc
  • Valoda: eng
  • ISBN-13: 9781439820230
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"This popular book helps readers address corrosion problems and create the most corrosion-resistant systems possible. It examines corrosion by gases, liquids, and solids and presents various models for evaluating corrosion. Now suitable as a graduate-level text, this expanded and completely reorganized third edition incorporates several new chapters along with recent literature and research findings. New chapters cover biological sources of corrosion, bioceramics, building materials, and restoration techniques. This edition also adds more end-of-chapter questions and additional reading lists"--

Reflecting the many changes in the field since the publication of the second edition, Corrosion of Ceramic Materials, Third Edition incorporates more information on bioceramics, including nanomaterials, as well as the weathering of construction materials. Adhering to the original plan of classification by chemistry, this edition reorganizes the topics into four main sections: Fundamentals, Corrosion Analysis, Corrosion of Specific Materials, and Properties and Corrosion.

New to the Third Edition

  • New chapters on corrosion by biological sources
  • New chapter on corrosion of architectural materials
  • Additional material on thermal and environmental barrier coatings
  • Expanded chapter on composites
  • More questions and examples
  • New literature sources in each chapter where appropriate

With an abundance of practical features and new information, this expanded and completely reorganized third edition helps readers address corrosion problems and create the most corrosion-resistant systems possible. Designed as a reference, it could also be used as a text in a graduate or senior undergraduate course.

Recenzijas

"Not only does Dr. McCauley go into excruciating detail about the chemical properties that give ceramics their unique properties, but he also adds historical examples of many of the early experiments in the field to weave a story of the evolution of this field of science. An excellent example is his description of the early ceramic eyes progressing to the present attempts to use ceramics to devise subretinal micro-photodiode arrays that will actually restore sight! Dr. McCauley makes an excellent point when he emphasizes that when designing experiments the researcher must pay close attention to the actual human physiologic environment versus experimental conditions on a substrate." George Weightman, MD

" a comprehensive guide to the fundamental aspects of corrosion in inorganic crystalline and glassy materials. The book is a thorough description of fundamentals, mechanisms, testing, and methods to reduce corrosion for a wide range of engineering applications. This text provides an introductory treatment of corrosion of ceramics that enables both engineering students as well as working professionals to understand and advance their knowledge on the subject. Research scientists and engineers in ceramics, metallurgy and other materials-related industries will find the book particularly valuable for this reason." Richard Haber, Rutgers University

"This is a comprehensive resource for materials engineers who are working in the field of corrosion of ceramic materials, covering both fundamental corrosion mechanisms and the responses of a wide range of specific ceramics. The extensive coverage includes the effects of corrosion in liquid and gaseous media, and even solid-solid corrosion. Bringing together more traditional ceramics, advanced structural and functional ceramics, and bioceramics, this is a thorough overview of the current understanding of the corrosive degradation phenomena that can deleteriously affect these materials. It is certainly a welcome, and timely, addition to the literature on ceramics and provides a thorough extension of the previous edition." Kevin Plucknett, Dalhousie University

" excellent and comprehensive overview of the important mechanisms controlling and contributing to the corrosion of glass and ceramics. Excellent reference source for students, faculty, and practicing engineers an easy read and emphasizes the practical side of why and how glass is corroded under various conditionsby liquids, gases, and in the human body." Delbert E. Day, Missouri University of Science and Technology

"McCauleys 3rd Edition of Corrosion of Ceramic Materials is the best yet, the only comprehensive text on the topic. a giant step new chapters on corrosion of ceramics in biological applications and those of architectural ceramics, the latter including mineralogical ceramics are outstanding starting points for practitioners and researchers in those two rapidly emerging and growing fields. easy to read. I completed it on two transatlantic flights, over and back. Even those familiar with only a few of the features of ceramic corrosion will enjoy it and learn more about ceramic corrosion from reading it. The brief quotes at the beginnings of the chapters are enlightening. In addition to technical statements by many scientists, one is by Yogi Berra which may have originated from McCauleys Missouri roots or his proximity to the New York Yankees. It is always good to see a Yogi Berra fan.

Every materials engineer with an interest in the corrosion of ceramic materials should read this text and have it on his bookshelf as a reference." Richard C. Bradt, Professor of Materials Engineering, Emeritus & Alton N. Scott Professor of Engineering, Emeritus, University of Alabama

Praise for the Previous Edition:"The author's intention to prepare a source book for engineers interested in the corrosion of ceramics has been achieved by bringing together a wealth of information that would otherwise have to be found in textbooks, technical journals and standards. There are useful questions at the end of each chapter to stimulate thoughtful readers to extend their interest in the subject. For a book of its caliber, one would expect it to find its way on to the bookshelves of corrosion engineers concerned with the intelligent selections of ceramics for industrial applications." Materials World, Vol. 13, No. 3, March 2005

"There are few comprehensive information sources available to ceramists working in the field of corrosion and oxidation, being largely limited to conference proceedings and journal articles. Consequently, Corrosion of Ceramic and Composite Materials is a welcome addition to the literature in this important area." JOM, August 2005

Preface to the Third Edition xvii
Preface to the Second Edition xix
Preface to the First Edition xxi
Acknowledgments xxiii
Introduction xxv
Section I Fundamentals
1 Corrosion by Liquids
3(42)
Introduction
3(4)
Crystalline Materials
7(25)
Attack by Aqueous Media
7(1)
Introduction
7(1)
Minerals
8(5)
Architectural Materials
13(8)
Electrochemical Corrosion
21(2)
Attack by Molten Glasses
23(5)
Attack by Molten Metals
28(2)
Attack by Molten Salts
30(2)
Glassy Materials
32(6)
Bioactive Glass
32(2)
Bulk Glasses
34(4)
Fiberglass
38(1)
Additional Recommended Reading
38(1)
Exercises, Questions, and Problems
38(1)
References
39(6)
2 Corrosion by Gas
45(10)
Crystalline Materials
45(5)
Glassy Materials
50(1)
Vacuum
51(1)
Exercises, Questions, and Problems
52(1)
References
52(3)
3 Corrosion by Solid
55(2)
References
56(1)
4 Corrosion by Biological Sources
57(22)
Introduction
57(3)
Human Body Fluids
60(14)
Biogenic Corrosion
60(3)
Ceramic Implants
63(1)
Mineral Dusts
64(6)
Nanoparticles
70(1)
Synthetic Glass Fibers
71(2)
Therapeutic Materials
73(1)
Additional Recommended Reading
74(1)
Exercises, Questions, and Problems
75(1)
References
75(4)
5 Acid/Base Effects
79(4)
Exercises, Questions, and Problems
81(1)
References
81(2)
6 Diffusion
83(6)
Additional Recommended Reading
87(1)
Exercises, Questions, and Problems
87(1)
References
87(2)
7 Kinetics
89(8)
Additional Recommended Reading
95(1)
Exercises, Questions, and Problems
95(1)
References
95(2)
8 Surface Effects
97(10)
Porosity and Surface Area
97(3)
Surface Charge
100(1)
Surface Energy
101(4)
Additional Recommended Reading
105(1)
Exercises, Questions, and Problems
105(1)
References
105(2)
9 Thermodynamics
107(18)
Introduction
107(1)
Mathematical Representation
108(4)
Graphical Representation
112(7)
Additional Recommended Reading
119(1)
Exercises, Questions, and Problems
119(1)
References
119(2)
Summary of Important Concepts Related to the Fundamentals of Corrosion
121(4)
Section II Corrosion Analysis
10 Assessment of Corrosion
125(8)
Introduction
125(1)
Laboratory Test versus Field Trials
125(2)
Sample Selection and Preparation
127(2)
Selection of Test Conditions
129(1)
Data Reduction
130(1)
Exercises, Questions, and Problems
131(1)
References
131(2)
11 Corrosion Test Procedures
133(18)
Introduction
133(6)
ASTM Standards
139(9)
Autoclave Expansion of Portland Cement, C-151
139(1)
Length Change of Hardened Hydraulic-Cement Mortars and Concrete, C-157
140(1)
Resistance of Glass Containers to Chemical Attack, C-225
140(1)
Chemical Resistance of Mortars, Grouts, and Monolithic Surfacings, C-267
140(1)
Acid Resistance of Porcelain Enamels, C-282
140(1)
Resistance of Porcelain Enameled Utensils to Boiling Acid, C-283
141(1)
Disintegration of Refractories in an Atmosphere of Carbon Monoxide, C-288
141(1)
Moisture Expansion of Fired Whiteware Products, C-370
141(1)
Absorption of Chemical-Resistant Mortars, Grouts, and Monolithic Surfacings, C-413
141(1)
Potential Expansion of Portland-Cement Mortars Exposed to Sulfate, C-452
141(1)
Disintegration of Carbon Refractories by Alkali, C-454
142(1)
Hydration Resistance of Basic Brick and Shapes, C-456
142(1)
Hydration of Granular Dead-Burned Refractory Dolomite, C-492
142(1)
Hydration of Magnesite or Periclase Grain, C-544
142(1)
Resistance of Overglaze Decorations to Attack by Detergents, C-556; Withdrawn 1994
142(1)
Permeability of Refractories, C-577
142(1)
Alkali Resistance of Porcelain Enamels, C-614
143(1)
Hydration Resistance of Pitch-Bearing Refractory Brick, C-620
143(1)
Isothermal Corrosion Resistance of Refractories to Molten Glass, C-621
143(1)
Corrosion Resistance of Refractories to Molten Glass Using the Basin Furnace, C-622; Withdrawn in 2000
143(1)
Resistance of Ceramic Tile to Chemical Substances, C-650
143(1)
Alkali Resistance of Ceramic Decorations on Returnable Beverage Glass Containers, C-675
144(1)
Detergent Resistance of Ceramic Decorations on Glass Tableware, C-676
144(1)
Acid Resistance of Ceramic Decorations on Architectural Type Glass, C-724
144(1)
Acid Resistance of Ceramic Decorations on Returnable Beer and Beverage Glass Containers, C-735
144(1)
Lead and Cadmium Extracted from Glazed Ceramic Surfaces, C-738
144(1)
Drip Slag Testing Refractory Brick at High Temperature, C-768
145(1)
Sulfide Resistance of Ceramic Decorations on Glass, C-777
145(1)
Evaluating Oxidation Resistance of Silicon Carbide Refractories at Elevated Temperatures, C-863
145(1)
Lead and Cadmium Release from Porcelain Enamel Surfaces, C-872
145(1)
Rotary Slag Testing of Refractory Materials, C-874
145(1)
Lead and Cadmium Extracted from Glazed Ceramic Tile, C-895
146(1)
Lead and Cadmium Extracted from Lip and Rim Area of Glass Tumblers Externally Decorated with Ceramic Glass Enamels, C-927
146(1)
Alkali Vapor Attack on Refractories for Glass-Furnace Superstructures, C-987
146(1)
Length Change of Hydraulic-Cement Mortars Exposed to a Sulfate Solution, C-1012
146(1)
Lead and Cadmium Extracted from Glazed Ceramic Cookware, C-1034; Withdrawn in 2001
146(1)
Chemical Resistance and Physical Properties of Carbon Brick, C-1106
146(1)
Quantitative Determination of Alkali Resistance of a Ceramic-Glass Enamel, C-1203
147(1)
Static Leaching of Monolithic Waste Forms for Disposal of Radioactive Waste, C-1220
147(1)
Chemical Durability of Nuclear, Hazardous, and Mixed Waste Glasses and Multiphase Glass-Ceramics: The Product Consistency Test (PCT), C-1285
147(1)
Accelerated Leach Test for Diffusive Releases from Solidified Waste and a Computer Program to Model Diffusive, Fractional Leaching from Cylindrical Waste Forms, C-1308
147(1)
Determining the Chemical Resistance of Aggregates for Use in Chemical-Resistant Sulfur Polymer Cement Concrete and Other Chemical-Resistant Polymer Concretes, C-1370
147(1)
Atmospheric Environmental Exposure Testing of Nonmetallic Materials, G-7
147(1)
Performing Accelerated Outdoor Weathering of Nonmetallic Materials Using Concentrated Natural Sunlight, G-90
148(1)
Nonstandard Tests
148(1)
Additional Recommended Reading
149(1)
Exercises, Questions, and Problems
149(1)
References
150(1)
12 Characterization Methods
151(16)
Introduction
151(1)
Chemical Analysis
152(1)
Bulk Analysis
152(1)
Surface Analysis
153(1)
Microstructure and Phase Analysis
153(5)
Visual Observation
153(1)
Optical Microscopy
154(1)
Electrochemical Impedance Spectroscopy
155(1)
Nuclear Magnetic Resonance
156(1)
Scanning Electron Microscopy/Energy Dispersive Spectroscopy
156(1)
Transmission Electron Microscopy
157(1)
X-Ray Diffractometry
157(1)
Physical Property Measurement
158(4)
Gravimetry and Density
158(1)
Mechanical Property Tests
159(1)
Porosity---Surface Area
159(1)
Reaction Rates
160(1)
Thermal Property Measurement
161(1)
Additional Recommended Reading
162(1)
Exercises, Questions, and Problems
162(1)
References
163(4)
Section III Corrosion of Specific Materials
13 Architectural Materials
167(12)
Cement, Concrete, Limestone, and Marble
167(7)
Clay-Based Materials
174(1)
Sandstone
175(1)
Glass
176(1)
Additional Recommended Reading
176(1)
Exercises, Questions, and Problems
177(1)
References
177(2)
14 Biologically Corroded Materials
179(34)
Introduction
179(1)
Inert Materials
180(1)
Alumina and Zirconia
180(1)
Bioactive Implants
181(8)
Bioactive Glasses
181(3)
Bioactive Hydroxyapatite
184(3)
Bioresorbable Materials
187(2)
Dental Materials
189(4)
Mineral Dusts
193(6)
Asbestiform Materials
193(5)
SiC
198(1)
Talc
198(1)
Nanoparticles
199(1)
Synthetic Mineral Fibers
199(2)
Therapeutic Materials
201(2)
Additional Recommended Reading
203(1)
Exercises, Questions, and Problems
204(1)
References
204(9)
15 Specific Crystalline Materials
213(76)
Attack by Liquids
213(27)
Attack by Molten Glasses
213(1)
Alumina-Containing Materials
214(3)
Carbides and Nitrides
217(4)
Zirconia-Containing Materials
221(1)
Attack by Aqueous Solutions
222(1)
Alumina
222(1)
Carbides and Nitrides
223(1)
Silica and Silicates
224(2)
Superconductors
226(1)
Titanates and Titania
226(1)
Transition Metal Oxides
227(1)
Zirconia-Containing Materials
228(1)
Attack by Molten Salts
229(1)
Carbides and Nitrides
229(4)
Oxides
233(3)
Superconductors
236(1)
Attack by Molten Metals
236(4)
Attack by Gases
240(31)
Borides
241(2)
Carbon
243(1)
Nitrides and Carbides
244(1)
Silicon Nitride
244(9)
Other Nitrides
253(2)
Silicon Carbide
255(6)
Other Carbides
261(2)
Oxides
263(1)
Alumina
263(2)
Alumino-Silicates
265(1)
Other Silicates
266(1)
Chrome-Containing Materials
267(1)
Magnesia-Containing Materials
267(1)
SiAlON
268(1)
Titanates
269(1)
Zirconia
269(1)
Silicides
270(1)
Superconductors
271(1)
Attack by Solids
271(2)
Magnesia
271(1)
Metals
272(1)
Silica
272(1)
Superconductors
273(1)
Additional Recommended Reading
273(1)
Exercises, Questions, and Problems
274(1)
References
275(14)
16 Specific Glassy Materials
289(26)
Introduction
289(1)
Borosilicate Glasses
289(5)
Chalcogenide-Halide Glasses
294(1)
Fluoride Glasses
295(1)
Lead-Containing Glasses
296(2)
Nitrogen-Containing Glasses
298(1)
Phosphorus-Containing Glasses
298(2)
Silicate Glasses
300(8)
Additional Recommended Reading
308(1)
Exercises, Questions, and Problems
308(1)
References
308(7)
17 Composite Materials
315(44)
Introduction
315(3)
Reinforcement
318(5)
Fibers
318(2)
Fiber Coatings or Interphases
320(2)
Particulates
322(1)
Other Structures
322(1)
Ceramic Matrix Composites (CMC)
323(18)
Oxide-Matrix Composites
323(1)
Al2O3-Matrix Composites
323(2)
Other Oxide-Matrix Composites
325(5)
Nonoxide-Matrix Composites
330(1)
Carbon-Carbon Composites
330(1)
SiC-Matrix Composites
331(10)
Metal Matrix Composites (MMC)
341(5)
Polymer Matrix Composites (PMC)
346(1)
Additional Recommended Reading
347(1)
Exercises, Questions, and Problems
347(1)
References
348(11)
Section IV Properties and Corrosion
18 Mechanisms
359(12)
Introduction
359(3)
Mechanisms
362(6)
Crystalline Materials
362(1)
Glassy Materials
363(5)
Additional Recommended Reading
368(1)
Exercises, Questions, and Problems
368(1)
References
369(2)
19 Degradation by Specific Environments
371(20)
Degradation by Aqueous Solutions
371(4)
Bioactive Materials
371(1)
Glassy Materials
372(3)
Nitrides
375(1)
Degradation by Molten Metals
375(1)
Degradation by Molten Salts
376(2)
Carbides and Nitrides
376(2)
Zirconia-Containing Materials
378(1)
Degradation by Oxidation
378(5)
Carbides and Nitrides
378(4)
Oxynitrides
382(1)
Degradation by Other Atmospheres
383(1)
Carbides and Nitrides
383(1)
Zirconia-Containing Materials
384(1)
Additional Recommended Reading
384(1)
Exercises, Questions, and Problems
385(1)
References
385(6)
Section V Minimization of Corrosion
20 Methods to Minimize Corrosion
391(14)
Introduction
391(1)
Crystalline Materials---Oxides
392(4)
Property Optimization
392(3)
External Methods of Improvement
395(1)
Crystalline Materials---Nonoxides
396(4)
Property Improvement
396(2)
External Methods of Improvement
398(2)
Glassy Materials
400(1)
Property Optimization
400(1)
External Methods of Improvement
400(1)
Exercises, Questions, and Problems
401(1)
References
401(4)
Epilogue 405(4)
Glossary of Terms 409(4)
Index 413
Ronald A. McCauley is Professor Emeritus in the Department of Materials Science and Engineering at Rutgers University. Dr. McCauley is a member of the American Ceramic Society, the American Society of Testing and Materials, the Mineralogical Society of America, and the National Association of Corrosion Engineers. He is the author and coauthor of numerous professional papers. He earned a Ph.D. from Pennsylvania State University.