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E-grāmata: Improvements in Bio-Based Building Blocks Production Through Process Intensification and Sustainability Concepts

(Professor, Department of Chemical, Engineering of University of Guanajuato, Mexico), , (Professor, Department of Chemical Engineering, University of Guanajuato, Mexico), (Postdoctoral Fellow, Universidad Michoacana de San Nicolįs de Hid)
  • Formāts: PDF+DRM
  • Izdošanas datums: 14-Sep-2021
  • Izdevniecība: Elsevier - Health Sciences Division
  • Valoda: eng
  • ISBN-13: 9780323886321
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Improvements in Bio-Based Building Blocks Production Through Process Intensification and Sustainability ConceptsPalielināt
  • Formāts: PDF+DRM
  • Izdošanas datums: 14-Sep-2021
  • Izdevniecība: Elsevier - Health Sciences Division
  • Valoda: eng
  • ISBN-13: 9780323886321
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Improvements in Bio-Based Building Blocks Production Through Process Intensification and Sustainability Concepts discusses new information on the production and cost of bio-based building blocks. From a technical point-of-view, almost all industrial materials made from fossil resources can be substituted using bio-based counterparts. However, the cost of bio-based production in many cases exceeds the cost of petrochemical production. In addition, new products must be proven to perform at least as good as their petrochemical equivalents, have a lower environmental impact, meet consumer demand for environmentally-friendly products, factor in population growth, and account for limited supplies of non-renewables.

This book outlines the application of process intensification techniques which allow for the generation of clean, efficient and economical processes for bio-based chemical blocks production.

  • Includes synthesis and process design strategies for intensified processes
  • Describes multi-objective optimization applied to the production of bio-based building blocks
  • Presents the controllability of processes where the production of bio-based building blocks is involved
  • Provides examples using aspen and MATLAB
  • Introduces several sustainable indexes to evaluate production processes
  • Presents process intensification techniques to improve performance in productive processes
Author biographies ix
1 Why are bio-based chemical building blocks needed?
1(14)
1.1 Are bio-based chemical building blocks needed?
1(14)
1.1.1 Drop-in bio-based chemicals
5(1)
1.1.2 Novel bio-based chemicals
5(3)
1.1.3 C6 and C6/C5 Sugar
8(1)
1.1.4 Plant-based oil
9(1)
1.1.5 Algae oil
10(1)
1.1.6 Organic solutions
10(1)
1.1.7 Lignin
11(1)
1.1.8 Pyrolysis oil
12(1)
References
13(2)
2 Process intensification and sustainability
15(10)
2.1 Process intensification and sustainability in bioblocks
15(10)
References
23(2)
3 Basic concepts on simulation of (bio)chemical processes
25(8)
3.1 (Bio)chemical processes
25(1)
3.2 Concept of simulation in bioprocesses (chemical)
25(6)
3.2.1 Simulation categories for biochemical processes
26(2)
3.2.2 Process simulation biochemical applications
28(3)
3.3 Concept of modeling and tools in process biochemicals
31(1)
3.4 The role of simulation and process modeling biochemicals
31(1)
3.5 The role of process optimization biochemicals
32(1)
References
32(1)
4 Bioethanol
33(28)
4.1 Bioethanol
33(1)
4.2 Petrochemical route of ethanol production
34(3)
4.2.1 Process, raw material, and kinetics
34(2)
4.2.2 Performance index in the production of ethanol through petrochemical
36(1)
4.2.3 Disadvantages in the production of ethanol through petrochemical
37(1)
4.3 Conventional bioethanol production process
37(9)
4.3.1 Raw material for the production of bioethanol
37(2)
4.3.2 Production of bioethanol from lignocellulosic biomass
39(5)
4.3.3 Advantages and disadvantages of bioethanol production
44(2)
4.4 Problems of the process for obtaining conventional bioethanol
46(1)
4.5 Proposals to intensify the process for obtaining bioethanol
46(12)
4.5.1 Synthesis
47(3)
4.5.2 Design
50(4)
4.5.3 Control
54(4)
4.6 Conclusions
58(3)
References
58(3)
5 Biobutanol
61(34)
5.1 General characteristics, uses, and applications
61(3)
5.2 Production of butanol from fossil sources
64(2)
5.3 Butanol production by the biochemical route
66(6)
5.3.1 Metabolic pathway of acetone-butanol-ethanol fermentation
66(1)
5.3.2 Conventional raw material to produce butanol
67(4)
5.3.3 Isopropanol-butanol-ethanol fermentation
71(1)
5.4 Process intensification applied to butanol production
72(15)
5.4.1 Process intensification in the reactive zone
73(6)
5.4.2 Process intensification in the downstream process
79(8)
5.5 Controllability studies applied to intensified alternatives for biobutanol purification
87(2)
5.6 Conclusions
89(6)
References
89(6)
6 Furfural
95(32)
6.1 Introduction
95(1)
6.2 Uses of furfural
96(2)
6.3 Current furfural markets
98(2)
6.4 Stoichiometric and kinetics models for furfural production
100(2)
6.5 Current technologies for furfural production
102(4)
6.6 New intensified proposes for furfural production
106(15)
6.6.1 Advances in furfural purification
106(4)
6.6.2 Objective functions
110(4)
6.6.3 Optimization results
114(3)
6.6.4 Advances in furfural purification using hybrid extractive distillation schemes
117(4)
6.7 Conclusions
121(6)
References
123(4)
7 Levulinic acid
127(20)
7.1 Introduction
127(2)
7.2 Current uses of levulinic acid
129(1)
7.3 Current levulinic acid markets
130(2)
7.4 Kinetics models for levulinic acid production
132(1)
7.5 Current for levulinic acid production
133(4)
7.6 New intensified proposals for levulinic acid production
137(7)
7.7 Conclusions
144(3)
References
144(3)
8 Ethyl levulinate
147(10)
8.1 Introduction
147(1)
8.2 Current applications and markets of ethyl levulinate
148(1)
8.3 Kinetics models for ethyl levulinate production
149(1)
8.4 Current technologies for ethyl levulinate production
150(2)
8.5 Current advances in ethyl levulinate production
152(3)
8.6 Conclusions
155(2)
References
156(1)
9 2,3-Butanediol
157(24)
9.1 Introduction
157(3)
9.2 Production of 2,3-BD from fossil and renewable sources
160(5)
9.2.1 Microorganisms useful in the production of 2,3-BD
162(3)
9.3 Raw material for 2,3-BD production
165(4)
9.3.1 Nonrenewable raw materials
166(2)
9.3.2 Renewable raw materials
168(1)
9.4 Process intensification (PI) in 2,3-BD production
169(1)
9.5 PI in 2,3-BD recovery
170(5)
9.6 Conclusions
175(6)
References
175(6)
10 Methyl ethyl ketone
181(22)
10.1 Introduction
181(3)
10.2 MEK production
184(11)
10.2.1 MEK production from nonrenewable sources
184(1)
10.2.2 MEK production from renewable sources
185(3)
10.2.3 Production ok methyl ethyl ketone through process intensified schemes
188(7)
10.3 Purification of MEK through intensified process
195(5)
10.4 Conclusion and future insights
200(3)
References
200(3)
11 Lactic acid
203(24)
11.1 Lactic acid
203(3)
11.1.1 Uses of lactic acid
204(1)
11.1.2 Market and demand for lactic acid
205(1)
11.2 Chemical route of lactic acid production
206(2)
11.2.1 Process, raw material, and reactions
206(1)
11.2.2 Performance index in lactic acid production via petrochemical
207(1)
11.2.3 Disadvantages in the production of lactic acid via petrochemical
207(1)
11.3 Conventional process of production of lactic acid via fermentation of biomass
208(4)
11.3.1 Raw material for the production of lactic acid via biomass
209(1)
11.3.2 Lactic acid production via biomass
209(3)
11.3.3 Advantages and disadvantages of lactic acid production via biomass
212(1)
11.3.4 Problems in the production of lactic acid via biomass
212(1)
11.4 Proposals for intensification of the process of obtaining lactic acid via biomass
212(12)
11.4.1 Synthesis and design
213(3)
11.4.2 Optimization
216(8)
11.5 Conclusions
224(3)
References
224(3)
12 Future insights in bio-based chemical building blocks
227(6)
12.1 Future insights in bio-based chemical building blocks
227(6)
References
231(2)
Index 233
Juan Gabriel Segovia-Hernandez is a Professor at Department of Chemical, Engineering of University of Guanajuato (México) has strong expertise in synthesis, design and optimization of (bio) processes. He has contributed to defining systematic methodologies to found, in a complete way, optimum sustainable and green processes for the production of several commodities. He also applied his methodologies to the production of biofuels and Bio-Based Building Blocks. Products of his research are more than 120 papers published in high impact factor indexed journals, 3 books with prestigious international publishers and three patent registers. In addition, he acts as a reviewer for over 25 top journals in chemical engineering, energy, and applied chemistry. For the pioneering work and remarkable achievements in his area of scientific research, he was National President of Mexican Academy of Chemical Engineering (2013-2015). Professor at the Department of Chemical Engineering at the University of Guanajuato (Mexico) since 2017. Through his academic development, he has gained considerable experience in the area of synthesis, design, simulation, control and optimization of chemical processes. Currently published contributions focus on the production of biofuels and base chemicals in the chemical industry. He has currently published more than 25 articles in indexed journals, 6 book chapters from renowned publishers and has registered 2 patents. He acts as a reviewer of indexed journals in the area of energy and chemical engineering. Email: eduardo.sanchez@ugto.mx, tel: +(52)4737320006 ext. 1403 César Ramķrez-Mįrquez is a Postdoctoral Fellow at the Chemical Engineering Department of the Universidad Michoacana de San Nicolįs de Hidalgo, Mexico. He earned his Ph.D. from the University of Guanajuato, Mexico, in 2020. His current research focuses on the production of materials for the solar energy industry and base chemicals in the chemical industry. He has published more than 55 journal papers, six book chapters, presented his work at over fifteen international and regional conferences, and holds four patents. PhD student at University of Guanajuato (Mexico) from 2016 to 2020. Mr. Gabriel has strong expertise in process intensification, control, design, synthesis, and optimization of biorefineries. Currently published contributions focus on the production of bio-blocks for chemical industry such as furfural or ethyl levulinate from lignocellulosic wastes. He has published more than 10 articles high impact factor journals and 2 chapters books. He has presented his work at more than 10 international/regional conferences. In addition, he acts as a reviewer for journals indexed in chemical engineering, biochemicals and energy. Email: g.contreraszarazua@ugto.mx, tel: +(52)4737320006 ext. 1403
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