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E-grāmata: Proton Conductors: Solids, Membranes and Gels - Materials and Devices

Edited by (Centre National de la Recherche Scientifique (CNRS), Paris)
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Proton Conductors: Solids, Membranes and Gels - Materials and DevicesPalielināt
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The present book covers different aspects of proton conduction: the first part describes chemical and physical parameters necessary for fast proton conduction and proposes a classification of different kinds of proton conductors. Comparison is made with other hydrogen containing materials (metals, graphites). The importance of partial water pressure, the role of defects and surface phenomena are discussed. The second part treats the chemistry, structures and electrical properties of typical materials from hydrogen bronzes to polymers via ice, hydroxides, acid sulphates, layer hydrates, clays, gels and porous or fractal media. The third part discusses the methods concerning the proton dynamics from local to macroscopic scale. The fourth part deals with conductivity mechanisms and the last one presents typical applications: electrochemical systems for production or energy storage and microionic devices.

This book gives a comprehensive review of proton conductors, including theory, techniques, the materials themselves and applications.

Papildus informācija

This book gives a comprehensive review of proton conductors, including theory, techniques, the materials themselves and applications.
Preface
Part I. The Hydrogen Bond and Protonic Species:
1. The proton mobility in solids and molten salts
2. Protonic species and their structures
3. Proton conductors: classification and conductivity
4. Defects, non-stoichiometry and phase transitions
5. Structural studies of proton conductors: the technical difficulties
6. Hydrogen in metals
Part II. Materials: Elaboration, Structures and Properties:
7. Structure and characterization of hydrogen insertion compounds of metal oxides
8. High temperature protonic conductors
9. Highly ionic hydroxides
10. Ice
11. Anhydrous materials
12. Hydrogen behaviour in graphite-nitric acid intercalation compound
13. Proton-containing ß
and ß
" alumina structure type compounds
14. Proton conduction in Zeolites
15. Proton containing NASICON phases
B. Layer hydrates
16. Phosphates and phosphonates of tetravalent metals
17. Hydrogen uranyl phosphate (HUP) and related materials
18. From crystalline to amorphous (particle) hydrates
19. Perfluorinated membranes
20. Mixed inorganic-organic polymers
Part III. Proton Dynamics and Charge Transport:
21. Incoherent neutron scattering studies of protons conductors
22. NMR studies of local motions in fast protonic conductors
23. Vibrational spectroscopy of proton conductors
24. Raman spectroscopic studies of proton conductors
25. Frequency dependent conductivity, microwave dielectric relaxation and proton dynamics
26. Measuring the true proton conductivity
27. DC techniques and combination techniques
28. NMR in macroscopic proton mobility in gels and porous media
Part IV. Proton Diffusion Mechanisms:
29. Mobility in hydrogen-containing oxide bronzes
30. Conductivity mechanisms and models in anhydrous protonic conductors
31. Conduction mechanisms in materials with volatile molecules
Part V. Devices:
32. Applications of perfluorinated proton conductors
33. Synthesis principals of polycrystalline H30+ and NH4+ß
/ß
"Al203 and potential application in steam electrolysis/fuel-cells
34. Fuel-cells, steam electrolysis for hydrogen production and hydrogen separation using high temperature protonic conductors
35. Ice-based devices
36. Solid-state gas sensors operating at room temperature
37. All solid-state protonic batteries
38. Applications of proton conductors in electrochromic devices (ECD)
39. Supercapacitors and interfacial charge accumulation devices
Index.


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