Preface |
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ix | |
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1 | (16) |
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1.1 Thermodynamic variables |
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1 | (5) |
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1.2 Microscopic viewpoint |
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6 | (5) |
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11 | (3) |
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14 | (3) |
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Chapter 2 The first and second laws |
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17 | (22) |
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17 | (3) |
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2.2 Energy conservation: the first law |
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20 | (2) |
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2.3 Entropy and the second law |
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22 | (5) |
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2.4 Thermodynamic heat engines |
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27 | (3) |
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30 | (2) |
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2.6 Entropy and probability: a macroscopic example |
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32 | (4) |
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36 | (3) |
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Chapter 3 General applications |
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39 | (26) |
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3.1 Thermodynamic potentials |
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39 | (4) |
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43 | (3) |
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3.3 Properties of ideal gases |
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46 | (4) |
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3.4 Potential temperature |
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50 | (3) |
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3.5 Open systems: enthalpy flux |
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53 | (2) |
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55 | (2) |
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3.7 Turbulent energy fluxes |
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57 | (2) |
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59 | (3) |
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62 | (3) |
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Chapter 4 The atmosphere under gravity |
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65 | (26) |
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65 | (2) |
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67 | (5) |
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72 | (3) |
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75 | (3) |
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4.5 Dry static energy and Bernoulli function |
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78 | (2) |
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80 | (2) |
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4.7 Statistical mechanics |
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82 | (5) |
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87 | (4) |
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Chapter 5 Water in the atmosphere |
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91 | (24) |
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5.1 The Clausius--Clapeyron equation |
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92 | (3) |
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5.2 Calculation of saturated vapour pressure |
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95 | (6) |
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101 | (1) |
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102 | (2) |
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104 | (2) |
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106 | (3) |
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109 | (3) |
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112 | (3) |
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Chapter 6 Vertical structure of the moist atmosphere |
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115 | (18) |
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6.1 Adiabatic lapse rate for moist air |
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115 | (3) |
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118 | (6) |
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6.3 Finite amplitude instabilities |
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124 | (1) |
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6.4 Vertical structure in thermodynamic diagrams |
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125 | (5) |
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6.5 Convective available potential energy |
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130 | (2) |
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132 | (1) |
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133 | (28) |
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7.1 Homogeneous nucleation: the Kelvin effect |
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133 | (5) |
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7.2 Heterogeneous nucleation: the Raoult effect |
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138 | (2) |
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140 | (4) |
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7.4 Charge-enhanced nucleation |
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144 | (4) |
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7.5 Drop growth by diffusion |
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148 | (8) |
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7.6 Drop growth by collision and coalescence |
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156 | (2) |
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158 | (3) |
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Chapter 8 Mixtures and solutions |
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161 | (16) |
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161 | (3) |
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8.2 Ideal gas mixtures and ideal solutions |
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164 | (2) |
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8.3 Raoult's law revisited |
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166 | (2) |
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8.4 Boiling and freezing of solutions |
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168 | (2) |
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8.5 Affinity and chemical equilibrium |
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170 | (4) |
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174 | (3) |
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Chapter 9 Thermal radiation |
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177 | (28) |
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9.1 Thermal radiation and Kirchhoff's law |
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177 | (3) |
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9.2 The Stefan--Boltzmann and Wien displacement laws |
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180 | (2) |
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9.3 Global energy budget and the greenhouse effect |
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182 | (4) |
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9.4 Climate feedbacks and the hydrological cycle |
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186 | (3) |
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9.5 Thermodynamics of a photon gas |
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189 | (4) |
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9.6 Derivation of the Planck law |
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193 | (5) |
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9.7 Energy flux, and the Stefan-Boltzmann integral |
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198 | (4) |
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202 | (3) |
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Chapter 10 Radiative transfer |
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205 | (18) |
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205 | (2) |
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207 | (4) |
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211 | (3) |
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10.4 Radiative-convective equilibrium |
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214 | (6) |
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10.5 Optically thin layers |
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220 | (2) |
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222 | (1) |
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Chapter 11 Non-equilibrium processes |
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223 | (18) |
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11.1 Energetics of motion |
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223 | (5) |
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11.2 Diabatic effects and the second law |
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228 | (4) |
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11.3 Thermodynamics of forced dissipative systems |
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232 | (2) |
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11.4 Climate thermodynamics |
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234 | (6) |
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240 | (1) |
Appendix A Functions of several variables |
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241 | (2) |
Appendix B Thermodynamic diagrams |
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243 | (6) |
Index |
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249 | (8) |
Useful data |
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257 | |